烟花爆竹燃放对大气污染物及PM<sub>2.5</sub>组分影响

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (1231 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract In order to understand the impact of fireworks burning on the concentration of gaseous pollutants and water-soluble inorganic ions, organic carbon (OC) and elemental carbon (EC) in PM_2.5 in Baoding, the concentration characteristics of atmospheric pollutants and particulate components were analyzed and the contribution of fireworks was evaluated during the Spring Festival. The results showed that the average concentration of PM_2.5, PM₁₀, SO₂, NO_2,and CO during the centralized discharge of fireworks in 2019 increased by 1.3, 1.0, 1.1, 0.4, and 0.02 times, respectively, compared with the non-centralized fire period. After the implementation of the burning ban during the Spring Festival in Baoding City, the average concentration, maximum concentration and duration of high concentration of pollutants on New Year's Eve and the first day all decreased significantly. During the centralized discharge period of fireworks, the contribution of fireworks to the concentration of PM_2.5, PM₁₀ and SO₂ decreased from about 50% (2018 and 2017) to about 30% (2019), of which SO₂ contribution decreased more evidently than that of PM_2.5 and PM₁₀. In addition, the component analysis showed that the proportion of total K⁺, Mg²⁺, and Cl^- concentrations in water-soluble ions accounted for 39.3% and 51.1% respectively, at the reception center site (main urban area) and Zhuozhou site (district-county built-up area) during fire period, the fractions of which were significantly higher than those in non-fire period. The contribution of fireworks to the concentration of K⁺, Mg²⁺, and Cl^-in PM_2.5 was more than 50%, of which the contribution to K⁺ was as high as 89.0%. The contribution of SO₄^2-, K⁺, Mg²⁺, and Cl^-at the Zhuozhou site was 2.2, 2.1, 1.9, and 1.8 times that of the reception center site, respectively. The sulfur oxidation rate (SOR), nitrogen oxidation rate (NOR), OC, and EC concentrations in the discharge period increased to a certain extent compared with the non-discharge period, in which OC and EC increased by 2.5 and 2.1 times, respectively, showing fireworks and firecrackers affect OC more than EC.

Key words： water-soluble inorganic ions OC EC fireworks burning Baoding

Received: 28 December 2019

PACS:

X513

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	Lü Wen-li
	ZHANG Kai
	CAO Qing
	ZHU Shuang
	CHEN Jian-hua
	ZHI Min-kang
	Li Dong

Cite this article:

Lü Wen-li,ZHANG Kai,CAO Qing等. Impacts of fireworks burning on atmospheric pollutants and water-soluble inorganic ions in PM_2.5[J]. CHINA ENVIRONMENTAL SCIENCECE, 2020, 40(8): 3303-3311.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2020/V40/I8/3303

[1]	Ravindra K, Mor S, Kaushik C, et al. Short-term variation in air quality associated with firework events:A case study[J]. Journal of Environmental Monitoring, 2003,5(2):260-264.
[2]	Wang Y, Zhuang G, Xu C, et al. The air pollution caused by the burning of fireworks during the lantern festival in Beijing[J]. Atmospheric Environment, 2007,41(2):417-431.
[3]	Vecchi R, Vera B, Diana C, et al. The impact of fireworks on airborne particles[J]. Atmospheric Environment, 2008,42(6):1121-1132.
[4]	Wu K, Duan M, Liu H, et al. Characterizing the composition and evolution of firework-related components in air aerosols during the Spring Festival[J]. Environmental Geochemistry and Health, 2018,40(6):2761-2771.
[5]	Chen Y, Ho K F, Ho S S, et al. Gaseous and particulate polycyclic aromatic hydrocarbons (PAHs) emissions from commercial restaurants in Hong Kong[J]. Journal of Environmental Monitoring Jem, 2007,9(12):1402-1409.
[6]	John H O, Joel E B. Aerosol size distributions of elemental and organic carbon in urban and over-water atmospheres[J]. Atmospheric Environment, 2000,34(10):1509-1517.
[7]	Pope C, Richard T B, Michael J T, et al. Lung cancer, cardiopulmonary mortality, and long-term Exposure to fine particulate air pollution[J]. Jama, 2002,287(9):1132-1141.
[8]	Huang H, Jiang Y, Xu X, et al. In vitro bioaccessibility and health risk assessment of heavy metals in atmospheric particulate matters from three different functional areas of Shanghai, China[J]. Science of the Total Environment, 2017,610-611:646-554.
[9]	Jiang Q, Sun Y L, Wang Z, et al. Aerosol composition and sources during the Chinese Spring Festival:fireworks, secondary aerosol, and holiday effects[J]. Atmospheric Chemistry and Physics, 2015,15(11):6023-6034.
[10]	杨志文,吴琳,元洁,等.2015年春节期间天津烟花爆竹燃放对空气质量的影响[J].中国环境科学, 2017,37(1):69-75. Yang Z W, Wu L, Yuan J, et al. Effect of fireworks on the air quality during the Spring Festival of 2015 in Tianjin City[J]. China Environmental Science, 2017,37(1):69-75.
[11]	Tian Y Z, Wang J, Peng X, et al. Estimation of the direct and indirect impacts of fireworks on the physicochemical characteristics of atmospheric fine and coarse particles[J]. Atmospheric Chemistry and Physics Discuss, 2014,14(18):11075-11101.
[12]	Zhang M, Wang X M, Chen J M, et al. Physical characterization of aerosol particles during the Chinese New Year's firework events[J]. Atmospheric Environment, 2010,44(39):5191-5198.
[13]	周变红,王格慧,张承中,等.春节期间西安市南郊细颗粒物中水溶性离子的污染特征[J].环境化学, 2013,32(3):498-504. Zhou B H, Wang G H, Zhang C Z, et al. Pollutions characteristics of water-souble ions of fine particle during spring festival over Xi'an southern[J]. Environmental Chemistry, 2013,32(3):498-504.
[14]	王红磊,朱彬,沈利娟,等.春节期间南京气溶胶质量浓度和化学组成特征[J].中国环境科学, 2014,34(1):30-39. Wang H L, Zhu B, Shen L J, et al. The mass concentration and chemical compositions of the atmospheric aerosol during the Spring Festival in Nanjing[J]. China Environmental Science, 2014,34(1):30-39.
[15]	Shi Y, Zhang N, Gao J, et al. Effect of fireworks display on perchlorate in air aerosols during the Spring Festival[J]. Atmospheric Environment, 2011,45(6):1323-1327.
[16]	赵伟,范绍佳,谢文彰,等.烟花燃放对珠三角地区春节期间空气质量的影响[J].环境科学, 2015,36(12):4358-4365. Zhao W, Fan S J, Xie W Z, et al. Influence of burning fireworks on air quality during the Spring Festival in the Pearl River Delta[J]. Environmental Science, 2015,36(12):4358-4365.
[17]	Godri K J, Green D C, Fuller G W, et al. Particulate oxidative burden associated with firework activity[J]. Environmental Science & Technology, 2010,44(21):8295-8301.
[18]	Yang L, Gao X, Wang X, et al. Impacts of firecracker burning on aerosol chemical characteristics and human health risk levels during the Chinese New Year Celebration in Jinan, China[J]. Science of the Total Environment, 2014,476-477:57-64.
[19]	Tsai H H, Li-Hsing C, Yuan C S, et al. Influences of fireworks on chemical characteristics of atmospheric fine and coarse particles during Taiwan's Lantern Festival[J]. Atmospheric Environment, 2012, 62:256-264.
[20]	Estrellan C R, Fukuya I. Toxic emissions from open burning[J]. Chemosphere, 2010,80(3):193-207.
[21]	Jiang Q, Sun Y L, Wang Z, et al. Aerosol composition and sources during the Chinese Spring Festival:fireworks, secondary aerosol, and holiday effects[J]. Atmospheric Chemistry and Physics, 2015,15(11):6023-6034.
[22]	Yu X, Shi C, Ma J, et al. Aerosol optical properties during firework, biomass burning and dust episodes in Beijing[J]. Atmospheric Environment, 2013,81(4):475-484.
[23]	Zhang J, Yang L, Chen J, et al. Influence of fireworks displays on the chemical characteristics of PM2.5 in rural and suburban areas in Central and East China[J]. Science of the Total Environment, 2017, 578(1):476-484.
[24]	郑悦,程方,张凯,等.保定市大气污染特征和潜在输送源分析[J].环境科学研究, 2020,33(2):260-270. Zheng Y, Cheng F, Zhang K, et al. Characteristics and potential transport source identification of atmospheric pollution in Baoding city[J]. Research of Environmental Sciences, 2020,33(2):260-270.
[25]	胡丙鑫,段菁春,刘世杰,等.2018年春节期间京津冀及周边地区烟花禁放效果评估[J].环境科学研究, 2019,32(2):203-211. Hu B X, Duan J C, Liu S J, et al. Evaluation of the effect of fireworks prohibition in the Beijing-Tianjin-Hebei and surrounding areas during the Spring Festival of 2018[J]. Research of Environmental Sciences, 2019,32(2):203-211.
[26]	Cao J J, Lee S C, Chow J C, et al. Spatial and seasonal distributions of carbonaceous aerosols over China[J]. Journal of Geophysical Research Atmospheres, 2007,112(D22):22-11.
[27]	张溪.北京市不同污染等级大气颗粒物及其水溶性离子的粒径分布特征及成因分析[D].山东:山东建筑大学, 2018. Zhang X. Size distribution characteristics and cause analysis of atmospheric particles and its water soluble ions of different pollution levels in urban Beijing[D]. Shandong:Shandong Jianzhu University, 2018.
[28]	陈威,邢延峰,孟庆庆,等.春节期间烟花爆竹燃放对哈尔滨市区空气质量的影响[J].中国环境监测, 2018,34(5):59-65. Chen W, Xing Y F, Meng Q Q, et al. Influence of burning fireworks on air quality during the Spring Festival in Harbin City[J]. Environmental Monitoring in China, 2018,34(5):59-65.
[29]	王哲,王自发,郑海涛.一种评估烟花爆竹燃放对大气PM2.5影响的新方法[J].中国环境监测, 2014,30(3):31-36. Wang Z, Wang Z F, Zheng H T. A new method to estimate the impacts of fireworks on airborne PM2.5[J]. Environmental Monitoring in China, 2014,30(3):31-36.
[30]	刘慧萍,张凯,柴发合,等.烟花爆竹燃放对北京大气污染物和水溶性无机离子的影响[J].环境科学研究, 2017,30(6):844-853. Liu H P, Zhang K, Chai F H, et al. Effects of fireworks on gaseous pollutants and water-soluble inorganic ions in the atmosphere[J]. Research of Environmental Sciences, 2017,30(6):844-853.
[31]	Kong S F, Li L, Li X X, et al. The impacts of firework burning at the Chinese Spring Festival on air quality:Insights of tracers, source evolution and aging processes[J]. Atmospheric Chemistry and Physics, 2015,15(4):2167-2184.
[32]	Guo S, Hu M, Zamora M L, et al. Elucidating severe urban haze formation in China[J]. Proceedings of the National Academy of Sciences, 2014,111(49):17373-17378.
[33]	Andreae M, Andreae T, Annegarn H, et al. Airborne studies of aerosol emissions from savanna fires in southern Africa:2. Aerosol chemical composition. Journal of Geophysical Research[J]. 1998,103(32):119-128.
[34]	Duan F, Liu X, Yu T, et al. Identification and estimate of biomass burning contribution to the urban aerosol organic carbon concentrations in Beijing[J]. Atmospheric Environment, 2004,38(9):1275-1282.
[35]	Perry, Kevin D. Effects of outdoor pyrotechnic displays on the regional air quality of western Washington State[J]. Air Repair, 1999, 49(2):146-155.
[36]	Shen Z, Cao J, Arimoto R, et al. Ionic composition of TSP and PM2.5 during dust storms and air pollution episodes at Xi'an, China[J]. Atmospheric Environment, 2009,43(18):2911-2918.
[37]	贺克斌.大气颗粒物与区域复合污染[M].北京:科学出版社, 2011. He K B. Atmospheric particulates combined with regional pollution[M]. Beijing:Science Press, 2011.
[38]	Chen J, Wu H, Wang X, et al. Heterogeneous uptake and oxidation of SO2 on iron oxides[J]. The Journal of Physical Chemistry C, 2007, 111(16):6077-6085.
[39]	Wang G, Zhang R, Gomez M E, et al. Persistent sulfate formation from London Fog to Chinese haze[J]. Proceedings of the National Academy of Sciences of the United States of America, 2016,V113(48):13630-13635.
[40]	Watson J G, Chow J C, Houck J E. PM2.5 chemical source profiles for vehicle exhaust, vegetative burning, geological material, and coal burning in Northwestern Colorado during 1995[J]. Chemosphere, 2001,43(8):1141-1151.
[41]	邹强,姚玉刚.春节烟花爆竹燃放期间苏州市区PM2.5组分特征分析[J].中国环境监测, 2014,26(4):100-107. Zou Q, Yao Y G. The analysis of characteristics of PM2.5 components during set-off fireworks period of Spring Festival in Suzhou City[J]. Environmental Monitoring in China, 2014,26(4):100-107.