碳化硼促进<i>Psendomonas stutzeri</i> A1501电催化固氮产氨及机制

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Abstract Pseudomonas stutzeri (P. stutzeri) A1501was used as a model nitrogen-fixing strain and boron carbide (B₄C) was selected as a typical electron transfer carrier to construct an electrocatalytic nitrogen reduction system. The effect of B₄C addition on the ammonia production under different conditions was explored. The results showed that B₄C significantly enhanced the ammonia production of the electrocatalytic nitrogen reduction system mediated by P. stutzeri A1501. With the dosage of 0.4g/L, the addition of B₄C (B₄C₉₀₀) prepared at 900℃ calcination temperature improved the ammonia yield by 117%. This was because the abundant activation sites on the surface of B₄C₉₀₀ promote N₂ adsorption and activation. In addition, the electrochemical and spectroscopic spectrograms showed that the addition of B₄C₉₀₀ not only triggered P. stutzeri A1501 to secrete more redox active substances, but also drove the construction of highly active cathode biofilms, thereby enhancing the long-distance transfer and utilization of electrode electrons.

Key words： Psendomonas stutzeri A1501 B₄C electrocatalysis biological nitrogen fixation

Received: 20 October 2020

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X172

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	DONG Guo-wen
	CHEN Piao
	REN Guo-ping
	WANG Chao
	JIN Shu-guang
	YE Jie
	ZHOU Shun-gui

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DONG Guo-wen,CHEN Piao,REN Guo-ping等. Boron carbide promotes the ammonia production by electrocatalytic nitrogen fixation with Psendomonas Stutzeri A1501[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(5): 2449-2458.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I5/2449

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