碳基吸附剂原位吸附底泥重金属离子研究进展

姜枫; 冯显露; 王鹏飞; 姜霞

PDF(431 KB)

中国环境科学 ›› 2022, Vol. 42 ›› Issue (10) : 4790-4797.

环境生态

碳基吸附剂原位吸附底泥重金属离子研究进展

姜枫¹, 冯显露², 王鹏飞¹, 姜霞¹

作者信息 +

Research progress on in-situ adsorption of heavy metal ions in sediments with carbon-based adsorbents

JIANG Feng¹, FENG Xian-lu², WANG Peng-fei¹, JIANG Xia¹

Author information +

文章历史 +

摘要

本文综述了碳基吸附剂去除湖泊底泥中重金属离子的研究进展，具体介绍了生物炭基吸附剂、碳纳米管基吸附剂以及氧化石墨烯基吸附剂在修复湖泊重金属污染底泥中的应用，分析了影响重金属污染底泥修复的影响因素.结果表明，生物炭基吸附剂，碳纳米管基吸附剂，氧化石墨烯基吸附剂以及改性碳基吸附剂均能够有效修复底泥重金属，抑制重金属的生物有效性，同时上覆水pH值、氧化还原电位、有机质和水体扰动会影响重金属修复效果.最后针对碳基吸附剂在修复底泥重金属方面的局限性，展望了未来碳基吸附剂修复湖泊重金属污染底泥的发展方向.

Abstract

In this paper, the research progress of carbon-based adsorbents in the removal of heavy metal ions from lake sediments was reviewed, and the applications of biochar-based adsorbents, carbon nanotubes-based adsorbents and graphene oxide-based adsorbents in the remediation of heavy metal-contaminated sediments in lakes were introduced in detail. The influencing factors were analyzed and the research prospect of carbon-based adsorbents for the remediation of heavy metal-contaminated sediments in lakes was put forward. It was indicated that biochar-based adsorbents, carbon nanotubes-based adsorbents, graphene oxide-based adsorbents and modified carbon-based adsorbents could effectively remove heavy metals in sediments and inhibit the bioavailability of heavy metals. Meanwhile, the performance of heavy metal removal was affected by pH value of overlying water, redox potential, organic matters and physical disturbance. Finally, considering limitation of carbon-based absorbents on remediating heavy metals in sediments, the future direction was prospected.

导出引用

姜枫, 冯显露, 王鹏飞, 姜霞. 碳基吸附剂原位吸附底泥重金属离子研究进展[J]. 中国环境科学. 2022, 42(10): 4790-4797

JIANG Feng, FENG Xian-lu, WANG Peng-fei, JIANG Xia. Research progress on in-situ adsorption of heavy metal ions in sediments with carbon-based adsorbents[J]. China Environmental Science. 2022, 42(10): 4790-4797

中图分类号： X524

参考文献

[1] Li D, Yu R, Chen J, et al.Ecological risk of heavy metals in lake sediments of China:A national-scale integrated analysis[J].Journal of Cleaner Production, 2022,334:130206.
[2] 张雅然,车霏霏,付正辉,等.青海湖沉积物重金属分布及其潜在生态风险分析[J].环境科学, 2022,43(6):1-14.Zhang Y R, Che F F, Fu Z H, et al.Distribution and potential ecological risk assessment of heavy metals in sediments of Lake Qinghai[J].Environmental Science, 2022,43(6):1-14.
[3] 陈春霄,姜霞,战玉柱,等.太湖表层沉积物中重金属形态分布及其潜在生态风险分析[J].中国环境科学, 2011,31(11):1842-1848.Chen C X, Jiang X, Zhan Y Z, et al.Speciation distribution and potential ecological risk assessment of heavy metals in sediments of Taihu lake[J].China Environmental Science, 2011,31(11):1842-1848.
[4] 丁之勇,蒲佳,吉力力.中国主要湖泊表层沉积物重金属污染特征与评价分析[J].环境工程, 2017,35(6):136-141.Ding Z Y, Pu J, Ji L L.Heavy metal contamination characteristics and its assessment in surface sediments of major lake in China[J].Environmental Engineering, 2017,35(6):136-141.
[5] Wang L, Wang Y, Ma F, et al.Mechanisms and reutilization of modified biochar used for removal of heavy metals from wastewater:a review[J].Science of the Total Environment, 2019,668:1298-1309.
[6] Xu X, Cao X, Zhao L.Comparison of rice husk-and dairy manure-derived biochars for simultaneously removing heavy metals from aqueous solutions:role of mineral components in biochars[J].Chemosphere, 2013,92(8):955-961.
[7] 黄艳虹,高凡,郭伟,等.基于梯度扩散薄膜技术(DGT)的氨基生物炭覆盖沉积物水界面铜,铅释放研究[J].湖泊科学, 2020,32(1):58-69.Huang Y H, Gao F, Guo W, et al.Release of copper and lead from the sediment-water interface under in-situ coverage of amino biochar via diffusive gradients in thin-films (DGT)[J].Journal of Lake Sciences, 2020,32(1):58-69.
[8] Gibbs R J.Transport phases of transition metals in the Amazon and Yukon Rivers[J].Geological Society of America Bulletin, 1977,88(6):829-843.
[9] 庄文.沉积环境重金属地球化学特征及生态风险综述[J].环境科学与技术, 2015,38(7):196-204.Zhuang W.Review on geochemical characteristic and the ecological risk of heavy metals in the sedimentary environment[J].Environmental Science & Technology, 2015,38(7):196-204.
[10] 方小红,彭渤,宋照亮,等.洞庭湖"四水"入湖河床沉积物重金属污染特征[J].地球化学, 2019,48(4):378-394.Fang X H, Peng B, Song Z L, et al.Heavy metal contamination in bed sediment from the four inlets of Xiangjiang, Zijiang, Yuanjiang, and Lishui river to Dongting Lake, China[J].Geochimica, 2019,48(4):378-394.
[11] 李仁英,杨浩,王丽,等.滇池沉积物中重金属的形态分布特征[J].土壤, 2008,40(2):264-268.Li R Y, Yang H, Wang L, et al.Form distribution of heavy metals in sediment of Dianchi Lake, Yunnan provice[J].Soils, 2008,40(2):264-268.
[12] Zhuang W, Gao X.Integrated assessment of heavy metal pollution in the surface sediments of the Laizhou Bay and the coastal waters of the Zhangzi Island, China:comparison among typical marine sediment quality indices[J].PLoS One, 2014,9(4):e94145.
[13] 李国新.污染沉积物原位和异位修复方法概述[J].安徽农学通报, 2019,19(25):114-116.Li G X.Overview of in-situ ectopic remediation methods for contaminated sediments[J].Anhui Agricultural Science Bulletin, 2019, 19(25):114-116.
[14] 刘群群.滨海河流沉积物的典型重金属质量基准确定及Cd污染原位修复研究[D].烟台:中国科学院烟台海岸带研究所, 2021.Liu Q Q.Determination of environmental quality guidelines for typical heavy metals and in-situ remediation of Cd pollution in coastal river sediments[D].Yantai:Yantai Institute of Coastal Zone Research, Chinese Academy of Science, 2021.
[15] Duan C, Ma T, Wang J, et al.Removal of heavy metals from aqueous solution using carbon-based adsorbents:A review[J].Journal of Water Process Engineering, 2020,37:101339.
[16] Thakur A K, Singh R, Pullela R T, et al.Green adsorbents for the removal of heavy metals from Wastewater:A review[J].Materials Today:Proceedings, 2021,6,45:30478-30487.
[17] 陈颢明,胡亦舒,李真.溶磷微生物改性生物炭吸附重金属的机理研究[J].中国环境科学, 2021,41(2):684-692.Chen H M, Hu Y S, Li Z.Adsorption mechanism of heavy metals by phosphate-solubilizing microorganism modified biochar.[J].China Environmental Science, 2021,41(2):684-692.
[18] Saleh T A.Nanocomposite of carbon nanotubes/silica nanoparticles and their use for adsorption of Pb (II):from surface properties to sorption mechanism[J].Desalination and Water Treatment, 2016, 57(23):10730-10744.
[19] Liu T, Gao B, Fang J, et al.Biochar-supported carbon nanotube and graphene oxide nanocomposites for Pb (II) and Cd (II) removal[J].Rsc.Advances, 2016,6(29):24314-24319.
[20] 吴先亮,黄先飞,张珍明.Fe₃O₄/GO对水溶液中Cd(II)去除的影响因素[J].中国环境科学, 2019,39(6):2411-2421.Wu X L, Huang X F, Zhang Z M.Influencing factors of Cd(Ⅱ) removal from aqueous solution by Fe₃O₄/GO[J].China Environmental Science, 2019,39(6):2411-2421.
[21] Hua M, Zhang S, Pan B, et al.Heavy metal removal from water/wastewater by nanosized metal oxides:a review[J].Journal of Hazardous Materials, 2012,211:317-331.
[22] Inyang M I, Gao B, Yao Y, et al.A review of biochar as a low-cost adsorbent for aqueous heavy metal removal[J].Critical Reviews in Environmental Science and Technology, 2016,46(4):406-433.
[23] Zhang W, Tan X, Gu Y, et al.Rice waste biochars produced at different pyrolysis temperatures for arsenic and cadmium abatement and detoxification in sediment[J].Chemosphere, 2020,250:126268.
[24] Sohi S P.Carbon storage with benefits[J].Science, 2012,338(6110):1034-1035.
[25] Zhang C, Shan B, Zhu Y, et al.Remediation effectiveness of Phyllostachys pubescens biochar in reducing the bioavailability and bioaccumulation of metals in sediments[J].Environmental Pollution, 2018,242:1768-1776.
[26] Tan X, Liu Y, Zeng G, et al.Application of biochar for the removal of pollutants from aqueous solutions[J].Chemosphere, 2015,125:70-85.
[27] Yang X, Wan Y, Zheng Y, et al.Surface functional groups of carbon-based adsorbents and their roles in the removal of heavy metals from aqueous solutions:a critical review[J].Chemical Engineering Journal, 2019,366:608-621.
[28] Tao Q, Li B, Li Q, et al.Simultaneous remediation of sediments contaminated with sulfamethoxazole and cadmium using magnesium-modified biochar derived from Thalia dealbata[J].Science of the Total Environment, 2019,659:1448-1456.
[29] Liu S J, Liu Y G, Tan X F, et al.The effect of several activated biochars on Cd immobilization and microbial community composition during in-situ remediation of heavy metal contaminated sediment[J].Chemosphere, 2018,208:655-664.
[30] Todaro F, Barjoveanu G, De Gisi S, et al.Sustainability assessment of reactive capping alternatives for the remediation of contaminated marine sediments[J].Journal of Cleaner Production, 2021,286:124946.
[31] Tan X F, Liu Y G, Gu Y L, et al.Biochar-based nano-composites for the decontamination of wastewater:a review[J].Bioresource Technology, 2016,212:318-333.
[32] Li J, Chen C, Zhang S, et al.Critical evaluation of adsorption-desorption hysteresis of heavy metal ions from carbon nanotubes:influence of wall number and surface functionalization[J].Chemistry An Asian Journal, 2014,9(4):1144-1151.
[33] Chen H, Li J, Shao D, et al.Poly (acrylic acid) grafted multiwall carbon nanotubes by plasma techniques for Co (II) removal from aqueous solution[J].Chemical Engineering Journal, 2012,210:475-481.
[34] Tang W W, Zeng G M, Gong J L, et al.Simultaneous adsorption of atrazine and Cu (II) from wastewater by magnetic multi-walled carbon nanotube[J].Chemical Engineering Journal, 2012,211:470-478.
[35] Alijani H, Shariatinia Z.Effective aqueous arsenic removal using zero valent iron doped MWCNT synthesized by in situ CVD method using natural α-Fe₂O₃ as a precursor[J].Chemosphere, 2017,171:502-511.
[36] Liang J, Feng J, Xingzhong L, et al.Facile synthesis of alumina-decorated multi-walled carbon nanotubes for simultaneous adsorption of cadmium ion and trichloroethylene[J].Chemical Engineering Journal, 2015,273:101-110.
[37] Sun W, Jiang B, Wang F, et al.Effect of carbon nanotubes on Cd (II) adsorption by sediments[J].Chemical Engineering Journal, 2015,264:645-653.
[38] Song B, Zeng G, Gong J, et al.Effect of multi-walled carbon nanotubes on phytotoxicity of sediments contaminated by phenanthrene and cadmium[J].Chemosphere, 2017,172:449-458.
[39] Xu P, Chen M, Zeng G, et al.Effects of multi-walled carbon nanotubes on metal transformation and natural organic matters in riverine sediment[J].Journal of Hazardous Materials, 2019,374:459-468.
[40] Somera B F, Corazza M Z, Yabe M J S, et al.3-Mercaptopropyltrimethoxysilane-modified multi-walled carbon nanotubes as a new functional adsorbent for flow injection extraction of Pb (II) from water and sediment samples[J].Water, Air, & Soil Pollution, 2012,223(9):6069-6081.
[41] Gong X, Huang D, Liu Y, et al.Nanoscale zerovalent iron, carbon nanotubes and biochar facilitated the phytoremediation of cadmium contaminated sediments by changing cadmium fractions, sediments properties and bacterial community structure[J].Ecotoxicology and Environmental Safety, 2021,208:111510.
[42] 蔺志朋,宋蕾,韩宝红,等.氧化石墨烯对沉积物中重金属Cu的稳定固化研究[J].生态环境学报, 2019,6(28):1201-1207.Lin Z P, Song L, Han B H, et al.Study on stable curing of heavy metal Cu in sediments by graphene oxide[J].Ecology and Environmental Sciences, 2019,6(28):1201-1207.
[43] Cao Y, Li X.Adsorption of graphene for the removal of inorganic pollutants in water purification:a review[J].Adsorption, 2014,20(5):713-727.
[44] Gu D, Fein J B.Adsorption of metals onto graphene oxide:Surface complexation modeling and linear free energy relationships[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2015,481:319-327.
[45] Zhang N, Qiu H, Si Y, et al.Fabrication of highly porous biodegradable monoliths strengthened by graphene oxide and their adsorption of metal ions[J].Carbon, 2011,49(3):827-837.
[46] Jiao C, Xiong J, Tao J, et al.Sodium alginate/graphene oxide aerogel with enhanced strength-toughness and its heavy metal adsorption study[J].International Journal of Biological Macromolecules, 2016,83:133-141.
[47] Zhang Y, Liu Y, Wang X, et al.Porous graphene oxide/carboxymethyl cellulose monoliths, with high metal ion adsorption[J].Carbohydrate Polymers, 2014,101:392-400.
[48] Yin X, Jiang Y, Tan Y, et al.Co-transport of graphene oxide and heavy metal ions in surface-modified porous media[J].Chemosphere, 2019, 218:1-13.
[49] Xiong T, Yuan X, Wang H, et al.Implication of graphene oxide in Cd-contaminated soil:a case study of bacterial communities[J].Journal of Environmental Management, 2018,205:99-106.
[50] Lin Z, Song L, Han B, et al.Effect of modified graphene oxide on Cu and phosphorus in eutrophic river sediments[J].Water Science and Technology, 2020,82(4):787-798.
[51] Abbas A, Al-Amer A M, Laoui T, et al.Heavy metal removal from aqueous solution by advanced carbon nanotubes:critical review of adsorption applications[J].Separation and Purification Technology, 2016,157:141-161.
[52] Bassyouni M, Mansi A, Elgabry A, et al.Utilization of carbon nanotubes in removal of heavy metals from wastewater:A review of the CNTs' potential and current challenges[J].Applied Physics A, 2020,126(1):1-33.
[53] 王明铭,丁爱中,郑蕾,等.沉积物金属迁移-转化的影响因素及其规律[J].环境工程, 2016,34(11):150-154.Wang M M, Ding A Z, Zheng L, et al.The influencing factors and rules of migration and transformation of metal in sediment:A review[J].Environmental Engineering, 2016,34(11):150-154.
[54] Peng J F, Song Y H, Yuan P, et al.The remediation of heavy metals contaminated sediment[J].Journal of Hazardous Materials, 2009, 161(2/3):633-640.
[55] 杜晓丽,尹子杰,陈梦瑶,等.径流溶解性有机物对生物滞留解质去除Cu²⁺和Pb²⁺的影响[J].中国环境科学, 2021,41(9):4142-4148.Du X L, Yin Z J, Chen M Y, et al.Effect of dissolved organic matter in runoff on the removal of Cu²⁺ and Pb²⁺ by bioretention medium[J].China Environmental Science, 2021,41(9):4142-4148.
[56] 何怡,门斌,杨晓芳,等.生物扰动对沉积物中重金属迁移转化影响的研究进展[J].生态毒理学报, 2016,11(6):25-36.He Y, Men B, Yang X F, et al.Bioturbation effect on the migration and transformation of heavy metals in sediment:A review[J].Asian Journal of Ecotoxicology, 2016,11(6):25-36.