In order to better understand the formation rate and extent of submerged oil under the effect of SPM, this study selected three crude oils as test oils, which were taken from the Bohai southern oilfield (YYH), Liaohe Oilfield (LH) and Middle East (ZD), respectively. The interaction between kaolin and the test crude oils were studied. The results showed that the adsorption kinetics of the three test oils are basically similar, and the rate of sinking oils tends to be stable after exponential growth. The adsorption of the crude oils by kaolin satisfies the Langmuir isotherm, which belongs to monolayer adsorption. The saturated adsorption capacities of YYH, LX and ZD were 914, 1297 and 2083mg/g, respectively. When the concentration of SPM was 500mg/L, the maximum sinking rates of YYH, LX and ZD were 37%, 45% and 59%, respectively. Based on the adsorption mechanism, we discussed the distribution characteristics of dispersed oil droplets at the particle-water interface, and provided a model to calculate the relationship between the sinking rates and the concentration of SPM. This study can provide basic data and scientific basis for the study of numerical models of submerged oil formation and drift diffusion.
Garcia-Pineda O, MacDonald I, Hu C, et al. Detection of floating oil anomalies from the Deepwater Horizon oil spill with synthetic aperture radar[J]. Oceanography, 2013,26(2):124-137.
[2]
National Research Council. Spills of Nonfloating Oils:Risk and Response[M]. Washington, DC, National Academy Press, 1999,75.
[3]
刘正江,李青平,熊德琪,等.渤海半潜和沉底油特性, 漂移预测及回收技术[J]. 中国科技成果, 2015,(19):33-33. Liu Z J, Li Q P, Xiong D Q, et al. Characteristics of semi-submersible and submarine oil in Bohai, drift prediction and recovery technology[J]. China Science and Technology Achievements, 2015,(19):33-33.
[4]
Muschenheim D K, Lee K. Removal of oil from the sea surface through particulate interactions:review and prospectus[J]. Spill Science & Technology Bulletin, 2002,8(1):9-18.
[5]
Bandara U C, Yapa P D, Xie H. Fate and transport of oil in sediment laden marine waters[J]. Journal of Hydro-environment Research, 2011,5(3):145-156.
[6]
Zhao L, Boufadel M C, Geng X, et al. A-DROP:A predictive model for the formation of oil particle aggregates (OPAs)[J]. Marine Pollution Bulletin, 2016,106(1/2):245-259.
[7]
Gao Y, Zhao X, Ju Z, et al. Effects of the suspended sediment concentration and oil type on the formation of sunken and suspended oils in the Bohai Sea[J]. Environmental Science:Processes & Impacts, 2018,20(10):1404-1413.
SY/T 7550-2012原油中蜡胶质沥青质含量的测定[S]. SY/T 7550-2012 Determination of waxy asphaltene content in crude oil[S].
[12]
GB-T 260-77石油产品水分测定法[S]. GB-T 260-77 Determination of Moisture Content of Petroleum Products[S].
[13]
Sun J, Zhao D, Zhao C, et al. Investigation of the kinetics of oil-suspended particulate matter aggregation[J]. Marine Pollution Bulletin, 2013,76(1/2):250-257.
[14]
Sun J, Khelifa A, Zheng X, et al. A laboratory study on the kinetics of the formation of oil-suspended particulate matter aggregates using the NIST-1941b sediment[J]. Marine Pollution Bulletin, 2010,60(10):1701-1707.
[15]
Gong Y, Zhao X, Cai Z, et al. A review of oil, dispersed oil and sediment interactions in the aquatic environment:influence on the fate, transport and remediation of oil spills[J]. Marine Pollution Bulletin, 2014,79(1/2):16-33.
[16]
夏文香,刘金雷,李金成,等.石油污染物在海滩颗粒体系中吸附规律的研究[J]. 海洋通报, 2006,25(5):17-21. Xia W X, Liu J L, Li J C, et al. Study on adsorption law of petroleum pollutants in beach particle system[J]. Haiyang Tongbao, 2006,25(5):17-21.
[17]
Lei C, Huang X, Ma F. The distribution coefficient of oil and curing agent in PP/EPDM TPV[J]. Polymers for Advanced Technologies, 2007,18(12):999-1003.
[18]
Hatje V, Payne T E, Hill D M, et al. Kinetics of trace element uptake and release by particles in estuarine waters:effects of pH, salinity, and particle loading[J]. Environment International, 2003,29(5):619-629.
[19]
李崇明,赵文谦,罗麟.河流泥沙对石油的吸附,解吸规律及影响因素的研究[J]. 中国环境科学, 1997,17(1):23-26. Li C M, Zhao W Q, Luo L. Study on adsorption, desorption and influencing factors of river sediment on petroleum[J]. China Environmental Science, 1997,17(1):23-26.