Nano zero-valent iron (NZVI) was modified by carboxymethylcellulose sodium (CMC) and copper (Cu) was used as composite metal to prepare modified nanoscale Fe/Cu bimetal. A reaction column was used to simulate the reaction process of 2,4-dichlorophenol (2,4-DCP) removal from groundwater by permeable reactive barrier (PRB). The characterization of the modified materials and the results of the sedimentation experiments showed that the modified materials had stronger dispersity. The effects of concentration of pollutant, dosage of materials, copper loading rate, pH and flow rate on degradation of 2,4-DCP were investigated andthe result showed that the reaction process followed the pseudo first-order kinetics, lower pH, lower flow rate and 10% copper loading rate were beneficial to the dechlorination of 2,4-DCP, and too high dosage of materials and excessive initial concentration of 2,4-DCP were not conducive to dechlorination.
潘煜, 孙力平, 陈星宇, 林明意. CMC改性纳米Fe/Cu双金属模拟PRB去除地下水中2,4-二氯苯酚[J]. 中国环境科学, 2019, 39(9): 3789-3796.
PAN Yu, SUN Li-ping, CHEN Xing-yu, LIN Ming-yi. Removal of 2,4-dichlorophenol from groundwater by PRB simulated by CMC modified nanoscale Fe/Cu bimetal. CHINA ENVIRONMENTAL SCIENCECE, 2019, 39(9): 3789-3796.
Bhattacharya S S, Banerjee R. Laccase mediated biodegradation of 2,4-dichlorophenol using response surface methodology[J]. Chemosphere, 2008,73(1):81-85.
[2]
Puyol D, Mohedano A F, Sanz J L, et al. Comparison of UASB and EGSB performance on the anaerobic biodegradation of 2,4-dichlorophenol[J]. Chemosphere, 2009,76(9):1192-1198.
[3]
Vione D, Minero C, Housari F, et al. Photoinduced transformation processes of 2,4-dichlorophenol and 2,6-dichlorophenol on nitrate irradiation[J]. Chemosphere, 2007,69(10):1548-1554.
[4]
Keith L H, Telliard W A. Priority pollutants. I. A perspective view[J]. Environmental Science and Technology, 1979,13(4):416-423.
[5]
Choi J H, Kim Y H, Choi S J. Reductive dechlorination and biodegradation of 2,4,6-trichlorophenol using sequential permeable reactive barriers:Laboratory studies[J]. Chemosphere, 2007,67(8):1551-1557.
[6]
Gillham R W, O'Hannesin S F. Enhanced degradation of halogenated aliphatics by zero-valent iron[J]. Groundwater, 1994,32(6):958-967.
[7]
Laumann S, Mici? V, Hofmann T. Mobility enhancement of nanoscale zero-valent iron in carbonate porous media through co-injection of polyelectrolytes[J]. Water Research, 2014,50(1):70-79.
[8]
Lien H L, Zhang W X. Transformation of chlorinated methanes by nanoscale iron particles[J]. Journal of Environmental Engineering, 1999,125(11):1042-1047.
[9]
Shahwan T, Üzüm, C?, Erog?Lu A E, et al. Synthesis and characterization of bentonite/iron nanoparticles and their application as adsorbent of cobalt ions[J]. Applied Clay Science, 2010,47(3):257-262.
[10]
Zhao X, Liu W, Cai Z, et al. An overview of preparation and applications of stabilized zero-valent iron nanoparticles for soil and groundwater remediation[J]. Water Research, 2016,100:245-266.
[11]
Zhao X, Liu W, Cai Z, et al. An overview of preparation and applications of stabilized zero-valent iron nanoparticles for soil and groundwater remediation[J]. Water Research, 2016,100:245-266.
[12]
张永祥,常杉,李飞,等.稳定型纳米零价铁去除地下水中2,4-二氯苯酚[J]. 环境科学, 2017,38(6):2385-2392. Zhang Y X, Chang S, Li F, et al. Removal of 2,4-dichlorophenol in underground water by stabilized nano zerovalent iron[J]. Environmental Sciences, 2017,38(6):2385-2392.
[13]
Hang J I, Xian H E, Cao X, et al. Removal of chromium(VI) in water by carboxymethyl cellulose stabilized nano zero-valent iron[Z]. Geoscience, 2013,27(6):1484-1488.
[14]
Mallát T, Bodnár Z, Petró J. Reduction by dissolving bimetals[J]. Tetrahedron, 1991,47(3):441-446.
[15]
Yang M X, Sutapa S, Bent E B, et al. Degradation of multiply-chlorinated hydrocarbons on Cu(100)[J]. Langmuir, 1997,13(2):127-137.
[16]
潘煜,孙力平,张婷婷,等.CMC改性的纳米Fe/Cu双金属去除2,4-二氯苯酚的研究[J]. 环境科学学报, 2019,39(4):1174-1182. Pan Y, Sun L P, Zhang T T, et al. Study on removal of 2,4-dichlorophenol by CMC modified nanoscale Fe/Cu bimetal[J]. Acta Scientiae Circumstantiae, 2019,39(4):1174-1182.
[17]
Comba S, Sethi R. Stabilization of highly concentrated suspensions of iron nanoparticles using shear-thinning gels of xanthan gum[J]. Water Research, 2009,43(15):3717-26.
[18]
Feng H, Zhao D. Preparation and characterization of a new class of starch-stabilized bimetallic nanoparticles for degradation of chlorinated hydrocarbons in water[J]. Environmental Science & Technology, 2005,39(9):3314-3320.
[19]
刘园园,高松,邱明英,等.强化的零价铁PRB技术对PCBs污染地下水的修复[J]. 生态环境学报, 2012,21(4):733-736. Liu Y Y, Gao S, Qiu M Y, et al. Enhanced Fe0PRB technology for the remediation of PCBs contaminated groundwater[J]. Ecology and Environment Sciences, 2012,21(4):733-736.
[20]
Yang J, Cao L, Guo R, et al. Permeable reactive barrier of surface hydrophobic granular activated carbon coupled with elemental iron for the removal of 2,4-dichlorophenol in water[J]. Journal of Hazardous Materials, 2010,184(1-3):782-787.
