中国环境科学
 
 
中国环境科学  2019, Vol. 39 Issue (12): 5210-5218    DOI:
土壤污染与控制 最新目录| 下期目录| 过刊浏览| 高级检索 |
不同源胡敏酸对磺胺嘧啶紫外光降解的影响及作用机制
申霞1,2, 王彬1,2, 朱静平1, 曾丹1,2, 谌书1,2, 任东3, 黄莎1,2
1. 西南科技大学环境与资源学院, 四川 绵阳 621010;
2. 西南科技大学, 固体废物处理与资源化教育部重点实验室, 四川 绵阳 621010;
3. 西华师范大学环境科学与工程学院, 四川 南充 637009
Influence and mechanism of humic acid from different sources on ultraviolet photodegradation of sulfadiazine
SHEN Xia1,2, WANG Bin1,2, ZHU Jing-ping1, ZENG Dan1,2, CHEN Shu1,2, REN Dong3, HUANG Sha1,2
1. School of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010, China;
2. Key Laboratory of Solid Waste Treatment and Resource Recycle, Ministry of Education, Southwest University of Science and Technology, Mianyang 621010, China;
3. College of Environmental Science and Engineering, China West Normal University, Nanchong 637009, China

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摘要 

研究了紫外光照条件下不同来源的胡敏酸(HA),包括标准品胡敏酸(SPHA)、水稻土胡敏酸(SDHA)、泥炭土胡敏酸(NTHA)和落叶覆盖地胡敏酸(LYHA)对抗生素磺胺嘧啶(SDZ)光降解的影响以及主要活性物种对其光降解效能的贡献.结果表明:SDZ在纯水中及与HA共存条件下,其光降解过程均符合一级动力学模型,且HA对SDZ的光降解具有促进作用,其促进效果从大到小为SPHA > SDHA > NTHA > LYHA.通过羟基自由基(·OH)和单线态氧(1O2)淬灭实验发现,不同来源HA产生·OH和1O2的能力具有一定差异性.同等背景条件下,SPHA产生的·OH量相对较多,其对SDZ光降解的贡献率(26.97%)最大,而LYHA贡献相对较小(9.33%).同时,1O2对SDZ光降解起主导作用,其降解贡献率为41.33%~51.95%.

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申霞
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任东
黄莎
关键词 胡敏酸磺胺嘧啶光解动力学羟基自由基单线态氧    
Abstract

The effects of different humic acids (HA), including standard humic acid (SPHA), Paddy soil humic acid (SDHA), Peat soil humic acid (NTHA) and Deciduous soil humic acid (LYHA), on the photodegradation of sulfadiazine (SDZ), and corresponding contribution of primary reactive species was investigated. The results indicated that the photodegradation process of SDZ in pure water and HA solution was consistent with the first-order photodegradation kinetic model. The photodegradation of SDZ was promoted by HA, in order of promoting effects:SPHA > SDHA > NTHA > LYHA. Based on the quenching experiment of hydroxyl radical (·OH) and singlet oxygen (1O2), the capacity to produce·OH and 1O2 of HA was been influenced by its own source. Under the same conditions, the amount of·OH produced by SPHA was relatively higher, and its contribution rate to SDZ photodegradation was the largest (26.97%), while LYHA contribution was relatively smaller at 9.33%. Meanwhile, 1O2 was found to play the most important role in the photodegradation of SDZ, with the contribution rate ranging from 41.33% to 51.95%.

Key wordshumic acid    sulfadiazine    photodegradation kinetics    hydroxyl radical    singlet oxygen   
收稿日期: 2019-05-24     
PACS: X142  
基金资助:

四川省国际科技创新合作项目(2019YFH0175);国家自然科学基金资助项目(41403081);四川省环境治理与生态保护重大科技专项(2018SZDZX0020);四川省重点研发项目(2017SZ0178)

通讯作者: 王彬,副教授,greenworldwb@swust.edu.cn     E-mail: greenworldwb@swust.edu.cn
作者简介: 申霞(1993-),女,四川蓬溪人,西南科技大学硕士研究生,主要从事土壤有机污染物光降解研究.
引用本文:   
申霞, 王彬, 朱静平, 曾丹, 谌书, 任东, 黄莎. 不同源胡敏酸对磺胺嘧啶紫外光降解的影响及作用机制[J]. 中国环境科学, 2019, 39(12): 5210-5218. SHEN Xia, WANG Bin, ZHU Jing-ping, ZENG Dan, CHEN Shu, REN Dong, HUANG Sha. Influence and mechanism of humic acid from different sources on ultraviolet photodegradation of sulfadiazine. CHINA ENVIRONMENTAL SCIENCECE, 2019, 39(12): 5210-5218.
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