Abstract:Bi2WO6 nanosheets with exposed (001) facets were synthesized via a hydrothermal process, and then Pt nanoparticles were loaded on the surface of the as-synthesized Bi2WO6 through photo-reduction method. The photocatalytic performance of the as-prepared photocatalysts was probed by the photocatalytic oxidation of benzyl alcohol and decomposition of rhodamine B (RhB). In terms of the oxidation of benzyl alcohol, the conversion rate over Pt loaded Bi2WO6 samples could attain 20.7%, which was about twice that of Bi2WO6 without Pt loading. Additionally, the mineralization rate of RhB over the Pt loaded samples (~81.1%) was remarkably higher than that of the photocatalysts without Pt loading (~55.8%) after 40min irradiation. These results collectively demonstrated the superior degradation and mineralization ability of the Pt loaded Bi2WO6 nanosheets under irradiation. The boosting photocatalytic activity of the Pt loaded photocatalysts could be attributed to the synergistic effect of Pt loading and the exposure of high energy facets. The loading of Pt nanoparticles, as a cocatalyst, increases the active sites on the surface of the photocatalysts and thereby promotes the separation and migration efficiency of photo-induced electron-hole pairs on the facets.
Roy S C, Varghese O K, Paulose M, et al. Toward solar fuels:photocatalytic conversion of carbon dioxide to Hydrocarbons[J]. ACS Nano, 2010,4(3):1259-1278.
[2]
苏海英,王盈霏,王枫亮,等.g-C3N4/TiO2复合材料光催化降解布洛芬的机制[J]. 中国环境科学, 2017,37(1):195-202. Su H Y, Wang Y F, Wang F L, et al. Preparation of g-C3N4/TiO2 composites and the mechanism research of the photocatalysis degradation of ibuprofen[J]. China Environmental Science, 2017, 37(1):195-202.
[3]
柴晴雯,吕艳,张周,等.Cu2O@ZnO复合光催化剂对难生物降解有机物的光降解[J]. 中国环境科学, 2019,39(7):2822-2830. Chai Q W, Lü Y, Zhang Z, et al. Photodegradation of refractory organics by Cu2O@ZnO composite photocatalyst[J]. China Environmental Science, 2019,39(7):2822-2830.
[4]
Chen C, Ma W, Zhao J. Semiconductor-mediated photodegradation of pollutants under visible-light irradiation[J]. Chemical Society Review, 2010,39(11):4206-4219.
[5]
Wang C C, Li J R, Lv X L, et al. Photocatalytic organic pollutants degradation in metal-organic frameworks[J]. Energy Environmental Science. 2014,7(9):2831-2867.
[6]
Zhou Y, Tian Z, Zhao Z, et al. High-Yield synthesis of ultrathin and uniform Bi2WO6 square nanoplates benefitting from photocatalytic reduction of CO2 into renewable hydrocarbon fuel under visible light[J]. ACS Applied Materials & Interfaces, 2011,3(9):3594-3601.
[7]
Cheng H F, Huang B B, Lu J B, et al. Synergistic effect of crystal and electronic structures on the visible-light-driven photocatalytic performances of Bi2O3 polymorphs[J]. Physical Chemistry Chemical Physics, 2010,12(47):15468-15475.
[8]
杨佳,牛晓君,陈伟仡,等.BiOBr@Bi2MO6 复合光催化剂制备及其对RhB和BPA降解[J]. 中国环境科学, 2017,37(6):2130-2138. Yang J, Niu X J, Chen W Y, et al. Synthesis of BiOBr@Bi2MoO6 photocatalyst with excellent visible light photocatalytic removal of RhB and BPA[J]. China Environmental Science, 2017,37(6):2130-2138.
[9]
Zhang L, Wang W Z, Sun S M, et al. Hybrid Bi2SiO5 mesoporous microspheres with light response for environment decontamination[J]. Applied Catalysis B:Environmental, 2010,100(1):97-101.
[10]
Mann A K P, Skrabalak S E. Synthesis of single-crystalline nanoplates by spray pyrolysis:a metathesis route to Bi2WO6[J]. Chemistry of Materials, 2011,23(4):1017-1022.
[11]
Sun Q, Jia X R, Wang X F, et al. Facile synthesis of porous Bi2WO6 nanosheets with high photocatalytic performance[J]. Dalton Transactions. 2015,44(32):14532-14539.
[12]
Tamar S, Nicolas C, Corinne C, et al. Bi2O3, BiVO4, and Bi2WO6:Impact of surface properties on photocatalytic activity under visible light[J]. Journal of Physical Chemistry C, 2011,115(13):5657-5666.
[13]
He W, Sun Y, Jiang G, et al. Activation of amorphous Bi2WO6 with synchronous Bi metal and Bi2O3 coupling:photocatalysis mechanism and reaction pathway[J]. Applied Catalysis B:Environmental, 2018, 232:340-347.
[14]
Zhang L W, Wang Y J, Cheng H Y, et al. Synthesis of porous Bi2WO6 thin films as efficient visible-light-active photocatalysts[J]. Advanced Materials, 2010,21(12):1286-1290.
[15]
Zhang F J, Xie F Z, Liu J, et al. Rapid sonochemical synthesis of irregularnanolaminar-like Bi2WO6 as efficient visible-light-active photocatalysts[J]. Ultrasonics Sonochemistry, 2013,20(1):209-215.
[16]
Zhao B, Wang M, Lin L, et al. Synthesis of parallel squared nanosheet-assembled Bi2WO6 microstructures under alkalescent hydrothermal treatment[J]. Ceramics International, 2014,40(4):5831-5835.
[17]
Zhang C, Zhu Y. Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts[J]. Chemistry of Materials, 2005,17(13):3537-3545.
[18]
Liu L, Lin S, Hu J, et al. Plasmon-enhanced photocatalytic properties of nano Ag@AgBr on single-crystalline octahedral Cu2O (111) microcrystals composite photocatalyst[J]. Applied Surface Science, 2015,330(3):94-103.
[19]
Liang Y, Lin S, Liu L, et al. Oil-in-water self-assembled Ag@AgCl QDs sensitized Bi2WO6:enhanced photocatalytic degradation under visible light irradiation[J]. Applied Catalysis B-Environmental, 2015,164:192-203.
[20]
Liu L, Ding L, Liu Y, et al. A stable Ag3PO4@PANI core@shell hybrid:enrichment photocatalytic degradation with π-π conjugation[J]. Applied Catalysis B-Environmental, 2017,201:92-104.
[21]
Liu L, Qi Y, Lu J, et al. A stable Ag3PO4@g-C3N4 hybrid core@shell composite with enhanced visible light photocatalytic degradation[J]. Applied Catalysis B-Environmental, 2016,183:133-141.
[22]
Tan C, Zhu G, Hojamberdiev M, et al. Co3O4nanoparticles-loaded BiOCl nanoplates with the dominant {001} facets:efficient photodegradation of organic dyes under visible light[J]. Applied Catalysis B-Environmental, 2014,152(1):425-436.
[23]
Lin H, Ding L, Pei Z, et al. Au deposited BiOCl with different facets:on determination of the facet-induced transfer preference of charge carriers and the different plasmonic activity[J]. Applied Catalysis B-Environmental, 2014,160(1):98-105.
[24]
Li R, Zhang F, Wang D, et al. Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO4[J]. Nature communications, 2013,4(2):1432.
[25]
Zhang P, Ran Y, Tan J, et al. Photodeposition of Pt on the Bi2WO6 nanosheets under irradiation of 365nm and 450nm LED lights[J]. Chemical Physics Letters, 2020,739:137019.
[26]
Qamar M, Elsayed R B, Alhooshani K R, et al. Highly efficient and selectiveoxidation of aromatic alcohols photocatalyzed by nanoporous hierarchical Pt/Bi2WO6 in organic solvent-free environment[J]. ACS Applied Materials Interfaces, 2015,7(2):1257-1269.
[27]
Ryu J H, Bang S Y, Kim W S, et al. Microstructure and optical properties of nanocrystalline CaWO4 thin films deposited by pulsed laser ablation in room temperature[J]. Journal of Alloys and Compounds, 2007,441(1):146-151.
[28]
Li X, Huang R, Hu Y, et al. A templated method to Bi2WO6 hollow microspheres and their conversion to double-shell Bi2O3/Bi2WO6 hollow microspheres with improved photocatalytic performance[J]. Inorganic Chemistry, 2012,51(11):6245-6250.
[29]
Sun Z X, Li X F, Guo S, et al. One-step synthesis of Cl-doped Pt(IV)/Bi2WO6 with advanced visible-light photocatalytic activity for toluene degradation in air[J] Journal of Colloid and Interface Science, 2013,412(24):31-38.
[30]
Liang S J, Xia Y Z, Zhu S Y, et al. Au and Pt co-loaded g-C3N4 nanosheets for enhanced photocatalytic hydrogen production under visible light irradiation[J]. Applied Surface Science, 2015,358:304-312.
[31]
Wang W K, Chen J J, Li W W, et al. Synthesis of Pt-loaded self-interspersed anatase TiO2 with a large fraction of (001) facets for efficient photocatalytic nitrobenzene degradation[J]. ACS Applied Materials & Interfaces, 2015,7(36):20349-20359.
[32]
Hao Q Q, Wang Z Q, Wang T J, et al. Role of Pt loading in the photocatalytic chemistry of methanol on rutile TiO2(110)[J]. ACS Catalysis, 2019,9(1):289-294.
[33]
Xu Y G, Xu H, Wang L, et al. The CNT modified white C3N4 composite photocatalyst with enhanced visible-lightresponse photoactivity[J]. Dalton Transactions, 2013,42(21):7604-7613.
[34]
Fu H B, Zhang S C, Xu T G, et al. Photocatalytic degradation of RhB by fluorinated Bi2WO6 and distributions of the intermediate products[J]. Environmental Science & Technology, 2008,42(6):2085-2091.
[35]
Zhang W, Zhang Y, Yang K, et al. Photocatalytic performance of SiO2/CNOs/TiO2 to accelerate the degradation of Rhodamine B under visible light[J]. Nanomaterials (Basel, Switzerland), 2019,9(12):1671-1687.
[36]
Zhuang J, Dai W, Tian Q, et al. Photocatalytic degradation of RhB over TiO2 bilayer films:effect of defects and their location[J]. Langmuir, 2010,26(12):9686-9694.