Abstract：VOCs samples from workshops and outlets were collected from four types of typical industrial coating industries in Hebei Province, 102 VOCs species were detected and analyzed, and the VOCs emission characteristics of workshops and outlets in four industries were obtained. The results showed that VOCs emission concentrations vary greatly among different industries due to the influence of type of coating, usage amount and other factors. Aromatics and oxygenated VOCs were the main components in furniture manufacturing, vehicle manufacturing and special equipment manufacturing industries, accounting for 14.7%~88.3% and 10.1%~64.7%, respectively. The proportion of halo-hydrocarbons in metal products industry was 59.2%~86.9%. The end-of-pipe treatment had the greatest effect on aromatics, and the proportions of toluene, ethylbenzene, xylene, trimethylbenzene, butyl acetate and 2-butanone at the outlets were significantly lower than that in the workshops. The contributions of aromatics to ozone formation potential (OFP) and secondary organic aerosol formation potential (SOAP) were the highest, and the end-of-pipe treatment had a significant reduction effect on OFP, SOAP and source reactivity (SR). The differences in the SR of various sources were obvious, and it is suggested to strengthen the control of industries with high SR value.
Xu J, Tie X, Gao W, et al. Measurement and model analyses of the ozone variation during 2006to 2015and its response to emission change in megacity Shanghai, China[J]. Atmospheric Chemistry and Physics, 2019,19(14):9017-9035.
[2]
Li Q, Su G, Li C, et al. An investigation into the role of VOCs in SOA and ozone production in Beijing, China[J]. Science of The Total Environment, 2020,720:137536.
[3]
Wei W, Cheng S, Li G, et al. Characteristics of volatile organic compounds (VOCs) emitted from a petroleum refinery in Beijing, China[J]. Atmospheric Environment, 2014,89:358-366.
[4]
程水源,李文忠,魏巍,等.炼油厂分季节VOCs组成及其臭氧生成潜势分析[J]. 北京工业大学学报, 2013,39(3):438-444. Cheng S Y, Li W Z, Wei W, et al. Refinery VOCs seasonal composition and analysis of ozone formation potential[J]. Journal of Beijing University of Technology, 2013,39(3):438-444,465.
[5]
李国昊,魏巍,程水源,等.炼焦过程VOCs排放特征及臭氧生成潜势[J]. 北京工业大学学报, 2014,40(1):91-99. Li G H, Wei W, Chen S Y, et al. Emission characterization and ozone formation potential of VOCs during the coking process[J]. Journal of Beijing University of Technology, 2014,40(1):91-99.
[6]
郭凤艳,刘芯雨,程晓娟,等.天津临港某石化企业VOCs排放特征研究[J]. 中国环境科学, 2017,37(6):2072-2079. Guo F Y, Liu X Y, Cheng X J, et al. Study on VOCs emission characteristic of a petrochemical enterprise in Tianjin Lingang. China Environmental Science, 2017,37(6):2072-2079.
[7]
刘政,徐晨曦,陈军辉,等.典型钢铁企业挥发性有机物排放量测算及组分特征[J]. 中国环境科学, 2020,40(10):4292-4303. Liu Z, Xu C X, Chen J H, et al. Emission estimation and component characteristics of volatile organic compounds in typical iron and steel enterprise. China Environmental Science, 2020,40(10):4292-4303.
[8]
中华人民共和国生态环境部. 关于印发《重点行业挥发性有机物综合治理方案》的通知[EB/OL]. https://www.mee.gov.cn/xxgk2018/xxgk/xxgk03/201907/t20190703_708395.html, 2019-06-26. Ministry of Ecology and Environment of the People's Republic of China. Notice on printing and distributing the comprehensive treatment plan for volatile organic compounds in key industries[EB/OL]. https://www.mee.gov.cn/xxgk2018/xxgk/xxgk03/201907/t20190703_708395.html, 2019-06-26.
[9]
刘锐源,钟美芳,赵晓雅,等.2011~2019年中国工业源挥发性有机物排放特征[J]. 环境科学, 2021,42(11):5169-5179. Liu R Y, Zhong M F, Zhao X Y, et al. Characteristics of industrial volatile organic compounds (VOCs) emission in China from 2011 to 2019[J]. Environmental Science, 2021,42(11):5169-5179.
[10]
Yuan B, Shao M, Lu S, et al. Source profiles of volatile organic compounds associated with solvent use in Beijing, China[J]. Atmospheric Environment, 2010,44(15):1919-1926.
[11]
高宗江.典型工业涂装行业VOCs排放特征研究[D]. 广州:华南理工大学, 2015. Gao C J. Source characteristics of VOCs emissions from typical industrial painting sources[D]. Guangzhou:South China University of Technology, 2015.
[12]
张嘉妮,曾春玲,刘锐源,等.家具企业挥发性有机物排放特征及其环境影响[J]. 环境科学, 2019,40(12):5240-5249. Zhang J N, Zeng C L, Liu R Y, et al. Volatile organic compound emission characteristics of furniture manufacturing enterprises and the influence on the atmospheric environment[J]. Environmental Science, 2019,40(12):5241-5249.
[13]
王家德,金旦军,顾震宇,等.金属表面涂装行业VOCs排放特征及排放系数[J]. 中国环境科学, 2020,40(5):1940-1945. Wang J D, Jin D J, Gu Z Y, et al. The VOCs emission characteristics of metal surface coating industry and its emission factors[J]. China Environmental Science, 2020,40(5):1940-1945.
[14]
周燕芳,陈梦霞,丁佳锋,等.彩钢行业VOCs排放特征及O3和SOA生成潜势[J]. 中国环境科学, 2019,39(4):1365-1370. Zhou Y F, Chen M X, Ding J F, et al. VOCs emission characteristics of color steel industry and formation potential of ozone and secondary organic aerosol[J]. China Environmental Science, 2019,39(4):1365-1370.
[15]
冯旸,刘锐源,刘雷璐,等.广州典型印刷企业VOCs排放特征及环境影响和健康风险评价[J]. 中国环境科学, 2020,40(9):3791-3800. Feng Y, Liu R Y, Liu L L, et al. VOCs emission characteristics, environmental impact and health risk assessment of typical printing enterprises in Guangzhou[J]. China Environmental Science, 2020, 40(9):3791-3800.
[16]
蒋宝,孙成一,白画画,等.油烟净化器对餐饮VOCs排放和光化学特征的影响[J]. 中国环境科学, 2021,41(5):2040-2047. Jiang B, Sun C Y, Bai H H, et al. Influence of fume purifier on VOCs emission characteristics and photochemical reaction of catering. China Environmental Science, 2020,40(9):3791-3800.
[17]
HJ732-2014固定污染源废气挥发性有机物的采样气袋法[S]. HJ732-2014 Waste gas from fixed pollution source Sampling of volatile organic compounds Air bag method[S].
[18]
Carter W P L. Development of the SAPRC-07chemical mechanism[J]. Atmospheric Environment, 2010,44(40):5324-5335.
[19]
Zhang Z, Wang H, Chen D, et al. Emission characteristics of volatile organic compounds and their secondary organic aerosol formation potentials from a petroleum refinery in Pearl River Delta, China[J]. Science of The Total Environment, 2017,584-585:1162-1174.
[20]
DB11/1226-2015工业涂装工序大气污染物排放标准[S]. DB11/1226-2015 Emission standard of air pollutants for industrial coating process[S].
[21]
邵弈欣.典型行业挥发性有机物排放特征及减排潜力研究[D]. 杭州:浙江大学, 2019. Shao Y X. Study on emission characteristics and emission reduction potential of volatile organic compounds from typical industries.[D]. Hangzhou:Zhejiang University, 2019.
[22]
雒瑞,张巍,张培勇,等.德州市典型溶剂使用行业VOCs排放特征及末端治理技术研究[J]. 涂料工业, 2020,50(9):67-75. Luo R, Zhang W, Zhang P Y, et al. Study on emission characteristics and end-control measurements for VOCs from typical solvent-usage industries in Dezhou City[J]. Paint & Coatings Industry, 2020, 50(9):67-75.
[23]
Wang H, Qiao Y, Chen C, et al. Source profiles and chemical reactivity of volatile organic compounds from solvent use in Shanghai, China[J]. Aerosol and Air Quality Research, 2014,14(1):301-310.
[24]
Zheng J, Yu Y, Mo Z, et al. Industrial sector-based volatile organic compound (VOC) source profiles measured in manufacturing facilities in the Pearl River Delta, China[J]. Science of The Total Environment, 2013,456-457:127-136.
[25]
李婷婷,梁小明,卢清,等.泡沫塑料鞋制造区VOCs污染特征及臭氧生成潜势[J]. 中国环境科学, 2020,40(8):3260-3267. Li T T, Liang X M, Lu Q, et al. Pollution characteristics and ozone formation potential of VOCs in the plastic foam shoe manufacturing center[J]. China Environmental Science, 2020,40(8):3260-3267.
[26]
马怡然,高松,王巧敏,等.合成树脂行业挥发性有机物排放成分谱及影响[J]. 中国环境科学, 2020,40(8):3268-3274. Ma Y R, Gao S, Wang Q M, et al. Source profiles and impact of volatile organic compounds in the synthetic resin industry[J]. China Environmental Science, 2020,40(8):3268-3274.
[27]
王瑞文,张春林,丁航,等.电子制造业塑料件生产过程的挥发性有机物排放特征分析[J]. 环境科学学报, 2019,39(1):4-12. Wang R W, Zhang C L, Ding H, et al. Emission characteristics of volatile organic compounds (VOCs) from the production processes of plastic parts in electronic manufacturing industry[J]. Acta Scientiae Circumstantiae, 2019,39(1):6-14.
[28]
刘文文,方莉,郭秀锐,等.京津冀地区典型印刷企业VOCs排放特征及臭氧生成潜势分析[J]. 环境科学, 2019,40(9):3942-3948. Liu W W, Fang L, Guo X R, et al. Emission characteristics and ozone formation potential of VOCs in printing enterprises in Beijing-Tianjin-Hebei[J]. Environmental Science, 2019,40(9):3942-3948.
[29]
景盛翱,王红丽,朱海林,等.典型工业源VOCs治理现状及排放组成特征[J]. 环境科学, 2018,39(7):3090-3095. Jing S H, Wang H L, Zhu H L, et al. Treatment status and emission characteristics of volatile organic compounds from typical industrial sources[J]. Environmental Science, 2018,39(9):3090-3095.
[30]
包亦姝,王斌,邓也,等.成都市典型有机溶剂使用行业VOCs组成成分谱及臭氧生成潜势研究[J]. 环境科学学报, 2020,40(1):76-82. Bao Y S, Wang B, Deng Y, et al. Source profiles and ozone formation potential of VOCs emitted from typical industries using organic solvents in Chengdu[J]. Acta Scientiae Circumstantiae, 2020,40(1):76-82.
[31]
Han S, Zhao Q, Zhang R, et al. Emission characteristic and environmental impact of process-based VOCs from prebaked anode manufacturing industry in Zhengzhou, China[J]. Atmospheric Pollution Research, 2020,11(1):67-77.
[32]
陈鹏,张月,张梁,等.汽车维修行业挥发性有机物排放特征及大气化学反应活性[J]. 环境科学, 2021,42(8):3604-3614. Cheng P, Zhang Y, Zhang L, et al. Emission characteristics and atmospheric chemical reactivity of volatile organic compounds (VOCs) in automobile repair industry[J]. Environmental Science, 2021, 42(8):3604-3614.
