Nanoscale PBA-Fe1Mn2 activated peroxymonosulfate for degradation of Azo organic
ZHANG Ting1, ZENG Jing2, YE Xiao-zhen2, LAN Yan-yan2, WANG Yong-quan2, HONG Jun-ming1
1. Fujian Province Engineering Research Center of Industrial Wastewater Biochemical Treatment, College of Chemical Engineering, Huaqiao University, Xiamen 361021, China; 2. Xiamen Tobacco Industrial Company Limited, Xiamen 361021, China
Abstract：The nano-scale Fe-Mn bimetallic catalyst of Prussian blue analogue PBA-Fe1Mn2, was prepared by a two-step oil bath-hydrothermal method. The large contactable area and many active sites of the nanoscale catalyst was utilized to activate peroxymonosulfate (PMS) for reactive black 5 (RBK5) degradation. Serious catalyst were characterized by X-ray powder diffractometry (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR), indicating that the synthesized catalyst PBA-Fe1Mn2 had structure of Prussian blue cubes. The synergistic effect of FeMn bimetal with the active site on the cubic structure effectively enhanced the degradation efficiency of RBK5. Under the optimal conditions of initial pH=7, catalyst dosage of 0.2g/L and PMS concentration of 2mmol/L, the decolorization efficiency of 10mg/L RBK5 could reach 100% within 60min. The free radical quenching experiments and EPR showed that HO• and SO4-• in this system were involved in the degradation of RBK5 and the hydroxyl radicals on the catalyst surface were the main acting groups. XPS reflected the changes of FeMn valence states, proved the synergistic interaction between bimetals, and identified the promotion of activity via FeMn valence cyclizing process. Finally, the degradation mechanism was analyzed according to XPS and 3D-EEM, which indicated that RBK5 was degraded in the system.
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