选择性催化氧化H<sub>2</sub>S的富氮碳催化剂研究进展

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摘要近年来,能高效净化H₂S并回收硫资源的选择性催化氧化技术(H₂S-SCO)受到了广泛关注.开发高性能、高选择性及低成本的催化剂是H₂S-SCO技术的研究重点,其中富氮碳基催化剂(RNCC)具有高活性、无金属、易制备、低成本且易再生等优点,被认为是一类极具潜力的H₂S-SCO催化剂.本文介绍了金属基催化剂的发展,总结和归纳RNCC的制备方法、催化活性和物化性质,系统地讨论RNCC的构-效关系及影响RNCC性能的关键因素,并总结了RNCC的H₂S-SCO反应机理.最后指出RNCC目前存在机遇和挑战,并展望了未来的发展方向.

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	杨金涛
	杨学金
	宁平
	王访
	宋晓双
	贾丽娟
	冯嘉予

关键词 ：富氮碳基催化剂, H₂S, 选择性催化氧化

Abstract：In recent years, selective catalytic oxidation (H₂S-SCO) technology, which can efficiently purify H₂S and recover sulfur resources, has received much attention. Research on the development of high-performance, high-selective, and low-cost catalysts is the focus of H₂S-SCO technology, among which the nitrogen-rich carbon-based catalysts (RNCCs), which have the advantages of high activity, metal-free, easy-to-prepare, low cost, and easy to be regenerated, are considered as a class of highly promising catalysts for H₂S-SCO. In this article, the development of metal-based catalysts is introduced, the preparation method, catalytic activity, and physical-chemical properties of RNCC are summarized and generalized, the structure-efficacy relationship of RNCC and the key factors affecting the performance of RNCC are systematically discussed, and the H₂S-SCO reaction mechanism of RNCC is concluded. Finally, the current opportunities and challenges of RNCC are also pointed out, and the future development direction is envisioned.

Key words： nitrogen-rich carbon catalyst H₂S selective catalytic oxidation

收稿日期: 2023-09-22

PACS:

X512

基金资助:国家自然科学基金资助项目(51968075)

通讯作者: 贾丽娟,教授,LeegyerKM@163.com;冯嘉予,讲师,FJY_DX3906@163.com E-mail: LeegyerKM@163.com;FJY_DX3906@163.com

引用本文:

杨金涛, 杨学金, 宁平, 王访, 宋晓双, 贾丽娟, 冯嘉予. 选择性催化氧化H₂S的富氮碳催化剂研究进展[J]. 中国环境科学, 2024, 44(4): 1981-1994. YANG Jin-tao, YANG Xue-jin, NING Ping, WANG Fang, SONG Xiao-shuang, JIA Li-juan, FENG Jia-yu. Advances in nitrogen-rich carbon catalysts for selective catalytic oxidation of H₂S. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(4): 1981-1994.

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