Comprehensive assessment of the technological, environmental, and economic effects of pilot-scale oil refining by pyrolysis of waste tires
HUANG Hai-yan1, LI Zi-feng1, XU Liu-jie1, WANG Chao2, GAO Ning-bo3, SONG Qing-bin1
1. Faculty of Innovation Engineering, National Observation and Research Station of Coastal Ecological Environments in Macao, Macau University of Science and Technology, Macao 999078, China; 2. School of Materials and Energy, Guangdong University of Technology, Guangzhou 510090, China; 3. School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an 710049, China
Abstract:With the rapid development of the automobile industry, the problem of waste tires has been attracting more and more attentions. How to achieve effective recycling and safe disposal of waste tires has become a hot issue in current industrial practice. This study aimed to comprehensively evaluate the product characteristics, environmental pollution, and economic benefits of a pilot-scale refinery process, based on the basis of the pyrolysis characteristics of waste tires. It is found that when the pyrolysis temperature ranges was 300℃~350℃, it will result in fewer gaseous pollutants (such as carbon dioxide, sulfur dioxide and nitrogen oxides). Under different pyrolysis temperatures, the heavy fuel oil products at the temperature range of 250℃~350℃ was consistent with the expected results, with lower asphaltene content (4.45%~5.68%) and higher olefin content (18.27%~25.18%). The optimum production temperature conditions were explored to be 350℃, which resulted in an annual profit of CNY 1,981,800 and a payback period of 34 months. This work focus on the evaluation and optimization of the pilot-scale process of low-temperature pyrolysis oil refining waste tiresfrom the perspecitves of technology, environment, and economy, and can provide technical support and application practice for the recycling of waste tires in future.
黄海延, 李子锋, 徐刘杰, 王超, 高宁博, 宋庆彬. 废旧轮胎裂解炼油中试技术、环境及经济评估[J]. 中国环境科学, 2024, 44(5): 2916-2922.
HUANG Hai-yan, LI Zi-feng, XU Liu-jie, WANG Chao, GAO Ning-bo, SONG Qing-bin. Comprehensive assessment of the technological, environmental, and economic effects of pilot-scale oil refining by pyrolysis of waste tires. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(5): 2916-2922.
[1] Policella M, Wang Z, Burra Kiran G, et al. Characteristics of syngas from pyrolysis and CO2-assisted gasification of waste tires[J]. Applied Energy, 2019,254:113678. [2] 刘俊,陈云嫩,聂锦霞.废轮胎热解炭黑制备活性炭及处理染料废水[J].中国环境科学, 2018,38(10):3795-3800. Liu J, Chen Y N, Nie J X. Preparation of activated carbon from waste tire pyrolysis carbon black and its treatment of dyeing wastewater[J]. China Environmental Science, 2018,38(10):3795-3800. [3] Oboirien B O, North B C. A review of waste tyre gasification[J]. Journal of Environmental Chemical Engineering, 2017,5(5):5169-5178. [4] 鲁锋.废旧轮胎热解相关实验研究[D].天津:南开大学, 2010. Lu F. The Related Experimental Study on the Pyrolysis of Waste Tires[D]. TianJin:Nankai University, 2010. [5] Amari T, Themelis N J, Wernick I K. Resource recovery from used rubber tires[J]. Resources Policy, 1999,25(3):179-188. [6] 张志霄.废轮胎回转窑热解特性及应用研究[D].浙江:浙江大学, 2005. Zhang Z X.Investigation of waste ire pyrolysis in rotary kiln and the application project[D]. ZheJiang:Zhejiang University, 2005. [7] Kar Y. Catalytic pyrolysis of car tire waste using expanded perlite[J]. Waste Management, 2011,31(8):1772-1782. [8] Hao J, Feng W, Qiao Y, et al. Thermal cracking behaviors andproducts distribution of oil sand bitumen by TG-FTIR and Py-GC/TOF-MS[J]. Energy Conversion and Management, 2017,151:227-239. [9] Kyari M, Cunliffe A, Williams PT. Characterization of oils, gases, and char in relation to the pyrolysis of different brands of scrap automotive tires[J]. Energy&Fuels, 2005,19(3):1165-1173. [10] Seidelt S, Müller-Hagedorn M, Bockhorn H. Description of tire pyrolysis by thermal degradation behaviour of main components[J]. Journal of Analytical and Applied Pyrolysis, 2006,75(1):11-18. [11] Kaminsky W, Mennerich D. Pyrolysis of Synthetic Tire Rubber in a Fluidized-Bed Reactor to Yield 1,3Butadi-ene,Styrene and Carbon Black[J]. Journal of Analytical and Applied Pyrolysis, 2001,58-59:803-811. [12] Yu Q, Brage C, Chen G, et al. The fate of fuel-nitrogen during gasification of biomass in a pressurised fluidised bed gasifier[J]. Fuel, 2007,86(4):611-618. [13] 代权晨,薛志亮,周永刚,等.废轮胎热解气燃烧NOx和SO2生成及控制研究[J/OL].化工进展, doi:10.16085/j.issn.1000-6613.2023-2027. Dai Q C, Xue Z L, Zhou Y G, et al. Research on the generation and control of NOx and SO2 during the combustion of pyrolysis gas from waste tires[J/OL]. Chemical Industry and Engineering Progress, doi:10.16085/j.issn.1000-6613.2023-2027. [14] Wei L, Yang T, Zhang N, et al. Nitrogen transformation during sewage sludge pyrolysis[J]. Energy&Fuels, 2015,29:5088-5094.