The composition characteristics of hydrogen and oxygenstable isotopes as an indicator of evaporation in the River Lijiang, China
REN Meng-meng1,2, HUANG Fen1, HU Xiao-nong2, CAO Jian-hua1, ZHANG Peng1,2, LIANG Jian-hong1, ZHANG Jin3
1. Key Laboratory of Karst Dynamics, Ministry of Natural Resources/Guangxi, Institute of Karst Geology, Chinese Academy of Geological Sciences, Guilin 541004, China;
2. School of Water Resources and Environment, China University of Geosciences, Beijing 100083, China;
3. Jinan University, Guangzhou 510632, China
The stable isotope compositon of water (δD and δ18O) were collected in November 2018 and March 2019 along the Lijiang River to estimate their indication of the evaporation. The results showed that:the δD and δ18O values had different composition characteristics among different sampling sietes in the the Lijiang River, the δD and δ18O values of groundwater was smaller than those of surface water, the δD and δ18O values in the wet season were easier to enrich than in the dry season; The variation trend of δ18O value was more obvious than d-excess under the increasing of water temperature. The elevation gradually decreased from the upstream to the downstream, and the slope and intercept of Lijaing River water line also gradually decreased; Underground river water line and Lijiang River water line were closely to local meteoric water line(LMWL), indicating that there was a close hydraulic connection between underground river, Lijiang River and precipitation in the study area. Due to the influence of temperature and humidity, the evaporation proportion of Lijiang River in wet season and dry season were 0.7%~9.1%,2.6%~9.7%, respectively; The evaporation proportion from upstream to downstream gradually increased in the study area, regardless of in wet season or dry season. The evaluated evaporation value based on isotope mass balance model in the study area was 959.40mm, which was less 43.11mm than the multi-year monitoring data, with the relative error of 4.70%; Using stable isotopes (δD and δ18O) is an essential method to study the hydrological cycle in a river basin, thus stable isotope still has a wide application space in hydrological cycle in Lijiang River Basin.
任梦梦, 黄芬, 胡晓农, 曹建华, 张鹏, 梁建宏, 张晋. 漓江流域δD和δ18O对蒸发的指示作用[J]. 中国环境科学, 2020, 40(4): 1637-1648.
REN Meng-meng, HUANG Fen, HU Xiao-nong, CAO Jian-hua, ZHANG Peng, LIANG Jian-hong, ZHANG Jin. The composition characteristics of hydrogen and oxygenstable isotopes as an indicator of evaporation in the River Lijiang, China. CHINA ENVIRONMENTAL SCIENCECE, 2020, 40(4): 1637-1648.
Posmentier E S, Feng X H, Zhao M X. Seasonal variations of precipitation δ18O in eastern Asia[J]. Journal of Geo-physical Research, 2004,109(D23).
[2]
Yurtever Y. Worldwide survey of stable isotopes in precipitation[R]. Report of the isotope hydrology section, vienna:international atomic energy agency, 1975:1-40.
[3]
董小芳,邓黄月,张峦,等.上海降水中氢氧同位素特征及与ENSO的关系[J]. 环境科学, 2017,38(5):1817-1827. Dong X F, Deng H Y, Zhang L, et al. Characteristics of stable isotope in precipitation and its relationship with ENSO in Shanghai[J]. Environmental Science, 2017,38(5):1817-1827.
[4]
李广,章新平,张立峰,等.长沙地区不同水体稳定同位素特征及其水循环指示意义[J]. 环境科学, 2015,36(6):2094-2101. Li G, Zhang X P, Zhang L F, et al. Stable isotope characteristics in different water bodies in Changsha and implications for the water cycle[J]. Environmental Science, 2015,36(6):2094-2101.
[5]
Dutton A, Wilkinson B H, Welker J M, et al. Spatial distribution and seasonal variation in δ18O of modern precipitation and river water across the conterminous USA[J]. Hydrological Processes, 2005, 19(20):4121-4146.
[6]
胡海英,包为民,瞿思敏,等.稳定性氢氧同位素在水体蒸发中的研究进展[J]. 水文, 2007,27(3):2-5. Hu H Y, Bao W M, Qu SM et al. Fractionation mechanism of stable hydrogen and oxygen isotope in water body evaporating[J]. Hydrology, 2007,27(3):2-5.
[7]
Kim K, Lee X H. Isotopic enrichment of liquid water during evaporation from water surfaces[J]. J Hydrol, 2011,399:364-375.
[8]
Clark I D, Fritz P. Environmental Isotopes in Hydrogeology[M]. New York:Lewis Publishers, 1997.
[9]
Wang L H, Dong Y H, Xie Y Q, et al. Distinct groundwater recharge sources and geochemical evolution of two adjacent subbasins in the lower Shule River Basin, northwest China[J]. Hydrogeol J, 2016, 24(8):1967-1979.
[10]
Cui B L, Li X Y. Characteristics of stable isotope and hydrochemistry of the groundwater around Qinghai Lake, NE Qinghai-Tibet Plateau[J]. China Environmental Earth Sciences, 2014,71:1159-1167.
[11]
冯芳,李忠勤,金爽,等.天山乌鲁木齐河流域山区降水δ18和δD特征及水汽来源分析[J]. 水科学进展, 2013,24(5):634-641. Feng F, Li Z Q, Jin S, et al. Characteristics of the δ18O and δD in precipitation and its water vapor sources in the upper Urumqi River basin, Eastern Tianshan[J]. Advances in Water Science, 2013, 24(5):634-641.
[12]
吴锦奎,杨淇越,丁永建,等.黑河流域大气降水稳定同位素变化及模拟[J]. 环境科学, 2011,32(7):1857-1866. Wu J K, Yang Q Y, Ding Y J, et al. Variations and simulation of stable isotopes in precipitation in the Heihe River basin[J]. Environmental Science, 2011,32(7):1857-1866.
[13]
杨淇越,吴锦奎,丁永建,等.锡林河流域地表水和浅层地下水的稳定同位素研究[J]. 冰川冻土, 2009,31(5):850-856. Yang Q Y, Wu J K, Ding Y J, et al. A study of isotope hydrology in shallow groundwater and stream water in the Xilin River Basin[J]. Journal of Glaciology and Geocryology, 2009,31(5):850-856.
[14]
李永格,李总省,冯起,等.托来河流域不同海拔降水稳定同位素的环境意义[J]. 环境科学, 2018,6:2661-2672. Li Y G, Li Z X, Feng Q, et al. Environmental significance of the stable isotopes in precipitation at different altitudes in the Tuolai River Basin[J]. Environmental Science, 2018,6:2661-2672.
[15]
Ma J Z, Zhang P, Zhu G F, et al. The composition and distribution of chemicals and isotopes in precipitation in the Shiyang River system, northwestern China[J]. Journal of Hydrology, 2012,436-437:92-101.
[16]
宋献方,李发东,于静洁,等.基于氢氧同位素与水化学的潮白河流域地下水水循环特征[J]. 地理研究, 2007,26(1):11-21. Song X F, Li F D, Yu J J, et al. Characteristics of groundwater cycle using deuterium, oxygen-18and hydrochemistry in Chaobai River Basin[J]. Geographical Research, 2007,26(1):11-21.
[17]
于静洁,宋献方,刘相超,等.基于δD和δ18O及水化学的永定河流域地下水循环特征解析[J]. 自然资源学报, 2007,22(3):415-423. Yu J Q, Song X F, Liu X C, et al. A Study of groundwater cycle in Yongding River Basin by using δD, δ18O and hydrochemical data[J]. Journal of Natural Resources, 2007,22(3):415-423.
[18]
徐宁涛,黄丹.漓江流域上游水质评价与生态需水量研究[J]. 黑龙江水利科技, 2016,44(6):20-24. Xu N T, Huang D. Study on water quality assessment and ecological water demand in the upper reaches of the Lijiang River Basin[J]. Heilongjiang Hrdralulic Science and Technology, 2016,44(6):20-24.
[19]
苗迎,章程,肖琼,等.漓江段地表水体旱季硝酸盐动态变化特征及其来源[J]. 环境科学, 2018,39(4):1589-1597. Miao Y, Zhang C, Xiao Q, et al. Dynamic variations and sources of nitrate during dry season in the Lijiang River[J]. Environmental Science, 2018,39(4):1589-1597.
[20]
韩耀全,周解,吴祥庆.漓江的自然地理与水质调查[J]. 广西水产科技, 2007,2:8-16. Han Y Q, Zhou J, Wu, X Q. Natural geography and water quality survey of Lijiang River.[J]. 2007, Fisheries Science & Technology of Guangxi, 2007,2:8-16.
[21]
申豪勇,姜光辉,郭芳,等.漓江桂林市区段三氮分布特征及影响因素分析.中国岩溶, 2015,34(4):369-374. Shen H Y, Jiang G H, Guo F, et a1. Distribution characteristics and influence factors of the ammonia, nitrite and nitrate in the Lijiang River, Guilin city[J]. Carsologica Sinica, 2015,34(4):369-374.
[22]
林鹏,陈余道,夏源.漓江流域不同土地利用类型下水体污染类型与成因[J]. 桂林理工大学学报, 2016,36(3):539-544. Lin P, Chen Y D, Xia Y. Types and causes of water pollution under different land use types in Lijiang River Basin[J]. Journal of Guilin University of Technology, 2016,36(3):539-544.
[23]
代俊峰,杨艺,方荣杰,等.漓江流域上游水质分析和污染物定量分割[J]. 中国农村水利水电, 2017,(4):67-71. Dai J F, Yang Y, Fang R J, et al. Water quality analysis and segmentation of the pollution loads in different spatial scales of the upstream of Lijiang River[J]. China Rural Water and Hydropower, 2017,(4):67-71.
[24]
苏文静,卢远,蔡德所.基于GIS的漓江流域水文特征空间分析[J]. 广西师范大学学报:自然科学版, 2012,30(4):166-171. Cai W J, Lu Y, Cai D S. Spatial analysis hydrological characteristics for Lijiang River Basin based on GIS[J]. J Guangxi Norm Univ(Nat Sci Ed), 2012,30(4):166-171.
[25]
茹锦文.漓江流域整治的综合研究[M]. 广西:广西师范大学出版社, 1986:7-9. Ru J W. A comprehensive study on the regulation of the Lijiang basin[M]. Guangxi:Guangxi Normal University Press, 1986:7-9.
[26]
肖仁美.区域水文地质报告—桂林幅[M]. 广西:广西壮族自治区地质矿产局, 1983:42-47. Xiao R M. Regional hydrogeology report-Guilin[M]. Guangxi:Guangxi zhuang autonomous region bureau of geology and mineral resources, 1983,42-47.
[27]
吴夏,朱晓燕,张美良,等.大气降水中稳定同位素组成的高分辨率记录—以桂林地区为例[J]. 长江流域资源与环境, 2013,22(2):182-188. Wu X, Zhu X Y, Zhang M L, et al. High-resolution stable isotope record of atmospheric precipitation in Guilin[J]. Resources and Environment in the Yangtza Basin, 2013,22(2):182-188.
[28]
武亚遵,万军伟,林云.湖北宜昌西陵峡地区大气降雨氢氧同位素特征分析[J]. 地质科技情报, 2011,30(3):93-97. Wu Y Z, Wan J W, Lin Y. Characteristics of hydrogen and oxygen isotopes for precipitation in Xiling gorge region of Yichang, Hubei province[J]. Geological Science and Technology Information, 2011, 30(3):93-97.
[29]
赵家成,魏宝国,肖尚斌.湖北宜昌地区大气降水中稳定同位素特征[J]. 热带地理, 2009,(6):526-531. Zhao J C, Wei B G, Xiao S B. Stable isotopic characteristics of atmospheric precipitation from Yichang, Hubei[J]. Tropical Geography, 2009,(6):526-531.
[30]
钱会,窦妍,李西健,等.都思兔河氢氧稳定同位素沿流程的变化及其对河水蒸发的指示[J]. 水文地质工程地质, 2007,(1):107-112. Qian H, Dou Y, Li X J, et al. Changes of δ18O and δD along Dousitu River and its indication of river water evaporation[J]. Hydrogeology and Engineering Geology, 2007,(1):107-112.
[31]
Craig H. Isotopic variations in meteoric water[J]. Science, 1961, 133:1702-1703.
[32]
卫克勤,林瑞芬.论季风气候对我国雨水同位素组成的影响[J]. 地球化学, 1994,23(1):32-41. Wei K Q, Lin R F. Theinfluence ofthe monsoon climate on theisotopiccompositionof precipitation in China[J]. Geochimica, 1994,23(1):32-41.
[33]
谷洪彪,迟宝明,王贺,等.柳江盆地地表水与地下水转化关系的氢氧稳定同位素和水化学证据[J]. 地球科学进展, 2017,32(8):789-799. Gu D B, Chi B M, Wang H, et al. Relationship between surface water and groundwater in the liujiang basin—hydrochemical constrains[J]. Advance in Earth Sciences, 2017,32(8):789-799.
[34]
张阿龙,高瑞忠,刘廷熙,等.高原内陆河流域气候水文突变与生态演变规律—以内蒙古锡林河和巴拉格尔河流域为例[J]. 中国环境科学, 2019,39(12):5254-5263. Zhang A L, Gao R Z, Liu T X, et al. Identification on hydrometeorology mutation characteristics and ecological evolution pattern of the plateau inland river basin-taken Xilin river and Balager river of Inner Mongolia for instance[J]. China Environmental Science, 2019,39(12):5254-5263.
[35]
Dansgaard W. Stable isotopes in precipitation[J]. Tellus, 1964, 16(4):436-468.
[36]
Gat J R. Oxygen and hydrogen isotopes in the hydrologiccycle[J]. Annual Review of Earth and Planetary Sciences, 1996,24:225-262.
[37]
Majoube M.Oxygen-18 and deuterium fractionation between water and steam[J]. J Chim Phys PCB, 1971,68(10):1423-1436.
[38]
Gonfiantini R. Environmental isotope in lake studies[J]. Terrestrial Environment, 1986,2:132-168.
[39]
高宏斌,李畅游,孙标,等.呼伦湖流域氢氧稳定同位素特征及其对水体蒸发的指示作用[J]. 湖泊科学, 2018,30(1):211-219. Gao H B, Li C Y, Sun B, et al. Characteristics of hydrogen and oxygen stable isotopes in Lake Hulun Basin its indicative function in evaporation[J]. Journal of Lake Sciences, 2018,30(1):211-219.
[40]
肖微,付靖茹,王伟,等.用稳定同位素方法估算大型浅水湖泊蒸发量—以太湖为例[J]. 湖泊科学, 2017,29(4):1009-1017. Xiao W, Fu J R, Wang W, et al. Estimating evaporation over a large and shallow lake using stable isotopic method:A case study of Lake Taihu[J]. Journal of Lake Sciences, 2017,29(4):1009-1017.
[41]
Saxena R K. Oxygen-18fractionation in nature and estimation of groundwater recharge[Dissertation]. PhD thesis, Uppsala Universitet, Report Series A No 40, Uppsala, Sweden, 1987:16-32.
[42]
H Jacob, C Sonntag C. An 8-year record of the seasonal-variation of2H and 18O in atmospheric water vapor and precipitation at Heidelberg, Germany[J]. Tellus B, 1991,43B(3):291-300.
[43]
许景旋,代俊峰.漓江流域上游径流变化分析[J]. 人民长江, 2018,49(10):41-46. Xu J X, Dai J F. Variation characteristics of runoff in upper reaches of Lijiang River Basin[J]. Yangtze River, 2018,49(10):41-46.
[44]
代俊峰,容方雨,杜君,等.广西蒸发皿蒸发量时空变化研究[J]. 中国农村水利水电, 2013,1:11-14. Dai J F, Rong F Y, Du J, et al. Study on Temporal and spatial variability of pan evaporation in Guangxi province[J]. China Rural Water and Hydropower, 2013,1:11-14.
[45]
张态成,彭期伟,范惠娟.阳朔站20m2蒸发池蒸发试验成果分析及广西地区蒸发折算系数研究[J]. 水文, 1995,4:28-34. Zhang T C, Peng Q W, Fan H J. Analysis of evaporation test results of 20m2 evaporation tank in Yangshuo station and study on evaporation conversion coefficient in Guangxi province. Hydrology, 1995,4:28-34.