1. School of Hydraulic Engineering, Changsha University of Science and Technology, Changsha 410114, China;
2. Key Laboratory of Water-Sediment Sciences and Water Disaster prevention of Hunan Province, Changsha 410114, China;
3. Key Laboratory of Dongting Lake Aquatic Eco-Environmental Control and Restoration of Hunan Province, Changsha 410114, China
Based on the 1258 shallow groundwater samples of Dongting Lake region, the spatial distribution of Eh was analyzed by geostatistical method, and the redox zoning of groundwater system in the lake region was carried out by using the concentration spatial data of redox sensitive indexes. The results show that, controlled by geological structure, stratigraphic lithology, swamp wetland and paddy field, spatial distribution of Eh in Dongting Lake region shows a decreasing trend from hilly areas to the hinterland of the lake, which reflects a fact that, groundwater environment gradually changes from relative oxidation to relative reduction. Groundwater system in Dongting Lake area can be divided into three redox zones, which arestable and reductive zone, manganese (IV) reductive zone and iron (III) reductive zone. In general, the three zones reflect the spatial distribution of Eh well, although the zones and Eh are not in synchronizationin some regions for Mn enrichment in aquifer media.
李景保,钟一苇,周永强,等.三峡水库运行对洞庭湖北部地区水资源开发利用的影响[J]. 自然资源学报, 2013,28(9):1583-1593. Li J B, Zhong Y W, Zhou Y Q, et al. Impacts of the operation of Three Gorges Reservoir on the development and utilization of water resources of Northern Dongting Lake Area[J]. Journal of Natural Resources, 2013,28(9):1583-1593.
[2]
柏道远,李长安,王先辉,等.第四纪洞庭盆地构造性质及动力机制探讨[J]. 大地构造与成矿学, 2010,34(3):317-330. Bai Y D, Li C A, Wang X H, et al. Quaternary tectonic characteristics and dynamic mechanismsof the Dongting Basin[J]. Geotectonica et Metallogenia, 2010,34(3):317-330.
[3]
Christensen T H, Bjerg P L, Banwart S A, et al. Characterization of redox conditions in groundwater contaminant plumes[J]. Journal of Contaminant Hydrology, 2000,45(3/4):165-241.
[4]
向交,徐丽萍,李和平,等.氧化还原电位的研究及应用[J]. 地球与环境, 2014,(3):165-171. Xiang J, Xu L P, Li H P, et al. Research on and Application of Oxidation-reduction Potential[J]. Earth and Environment, 2014,(3):165-171.
[5]
钱会,马致远.水文地球化学[M]. 北京:地质出版社, 2005:62-64. Qian H, Ma Z Y, hydrogeochemistry[M]. Beijing:Geological Publishing House, 2005:62-64.
[6]
Massmann G, Greskowiak J, UDünnbier, et al. The impact of variable temperatures on the redox conditions and the behaviour of pharmaceutical residues during artificial recharge[J]. Journal of Hydrology, 2006,328(1/2):0-156.
[7]
苏东,苏小四,张丽华,等.沈阳黄家傍河水源地河水入渗过程中氧化还原分带规律[J]. 中国环境科学, 2016,36(7):2043-2050. Su D, Su X S, Zhang L H, et al. Redox zonation in the process of river water infiltration in the Huangjia riverside well field, Shenyang City[J]. China Environment Science, 2016,36(7):2043-2050.
[8]
齐红艳,范德江,徐琳,等.长江口及邻近海域表层沉积物pH、Eh分布及制约因素[J]. 沉积学报, 2008,026(5):820-827. Qi H Y, Fan D J, Xu L, et al. The states of pH, Eh in surface sediments of the Yangtze River Estuaryand its adjacent areas and their controlling factor[J]. Acta SedimentologicaSinica, 2008,026(5):820-827.
[9]
杨钙仁,童成立,肖和艾,等.水分控制下的湿地沉积物氧化还原电位及其对有机碳矿化的影响[J]. 环境科学, 2009,30(8):2381-2386. Yang K R, Tong C L, Xiao H A, et al. Effects of water content on redox potential and carbon mineralization of wetland sediments[J]. Environmental Science, 2009,30(8):2381-2386.
[10]
续勇波.热带亚热带土壤氮素反硝化及其环境效应[M]. 北京:科学出版社, 2014:31-36. Xu Y B. Nitrogen denitrification in tropical and subtropical soils and its environmental effects[M]. Beijing:Science Press, 2014:31-36.
[11]
国家环境保护总局.地下水环境监测技术规范(HJ/T 164-2004)[S]. 北京:中国标准出版社, 2004:9-32. State Environmental Protection Administration of China. Technical specifications for environmental monitoring of groundwater (HJ/T 164-2004)[S]. Beijing:China Standards Press, 2004:9-32.
[12]
湖南省地质矿产局水文二队.湖南省洞庭湖区综合工程地质报告[R]. 长沙:湖南省国土资源信息中心, 1985:31-32. No.2Hydrogeological and Engineering Geological Team, Hunan Bureau of Geology and mineral resources. Comprehensive engineering geological report of Dongting Lake area, Hunan Province[R]. Changsha:Hunan Data center of land and resource, 1985:31-32.
[13]
邓正苗,谢永宏,陈心胜,等.洞庭湖流域湿地生态修复技术与模式[J]. 农业现代化研究, 2018,39(6):994-1008. Deng Z M, Xie Y H, Chen X S, et al. Wetland ecological restoration techniques and models in Dongting Lake basin[J]. Research of Agricultural Modernization, 2018,39(6):994-1008.
[14]
张猛,曾永年.基于多时相Landsat数据融合的洞庭湖区水稻面积提取[J]. 农业工程学报, 2015,31(13):178-185. Zhang M, Zeng Y N. Mapping paddy fields of Dongting Lake area by fusing Landsat and MoDIS data[J]. Transactions of the Chinese Society of Agricultural Engineering, 2015,31(13):178-185.
[15]
吴家梅,纪雄辉,霍莲杰,等.稻田土壤还原性物质特征及与甲烷排放的关联性分析[J]. 农业现代化研究, 2014,35(5):644-648. Wu J M, Ji X H, Huo L J, et al. The characteristic of reductive material in paddy soil and its relation to methane emission[J]. Research of Agricultural Modernization, 2014,35(5):644-648.
[16]
袁文真.傍河开采驱动下河水入渗地下水过程中铁锰生物地球化学过程研究[D]. 长春:吉林大学, 2017. Yuan W Z. Biogeochemical process of Fe and Mn during river bank infiltration affected by groundwater exploiting[D]. Changchun:Jilin University, 2017.
[17]
Appelo C A J, Postma D. Geochemistry, groundwater and pollution[M]. CRC press, 2005:438-432.
[18]
Champ D R, Gulens J, Jackson R E. Oxidation-reduction sequences in ground water flow systems[J]. Canadian Journal of Earth Sciences, 1979,16(1):12-23.
[19]
Lyngkilde J, Christensen T H. Redox zones of a landfill leachate pollution plume (Vejen, Denmark)[J]. Journal of Contaminant hydrology, 1992,10(4):273-289.
[20]
Lensing H J, Vogt M, Herrling B. Modeling of biologically mediated redox processes in the subsurface[J]. Journal of Hydrology, 1994, 159(1-4):125-143.
[21]
Massmann G, Pekdeger A, Merz C. Redox processes in the Oderbruch polder groundwater flow system in Germany[J]. Applied Geochemistry, 2004,19(6):863-886.
[22]
湖南省洞庭湖区生态地球化学调查项目部.湖南省洞庭湖区生态地球化学调查总体综合评价报告[R]. 北京:中国地质调查局, 2008:63-64. Project Department of ecological geochemical survey of Dongting Lake District, Hunan Province. Report on the overall evaluation of ecological geochemical survey of Dongting Lake District, Hunan Province[R]. Beijing:China Geological Survey, 2008:63-64.
[23]
湖南省地质调查院.中国区域地质志(湖南志)[M]. 北京:地质出版社, 2017:158-194. Hunan Geological Survey Institute. China regional geological records (Hunan volume)[M]. Beijing:Geological Press, 2017:158-194.
[24]
魏军才,张建新,邢旭东,等.洞庭湖区沉积物物源推断的地球化学指标与应用[J]. 大地构造与成矿学, 2010,34(3):444-449. Wei J C, Zhang J X, Xing X D, et al. Geochemical characteristics of sediments from the Dongting Lake Area and its application for inferring their sources[J]. Geotectonica et Metallogenia, 2010,34(3):444-449.