Removal of tetracycline in groundwater by iron-manganese co-oxide filter
YAO Xuan1,2,3, HUANG Ting-lin1,2,3, CHENG Ya1,2,3, LI Yu-yang1,2,3, SUN Chang-xi1,2,3
1. School of Environment and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China;
2. Shanxi Key Laboratory of Environmental Engineering, Xi'an 710055, China;
3. Key Laboratory of Northwest Water Resource, Environment and Ecology, Ministry of Education, Xi'an 710055, China
In this study, the iron-manganese (Fe-Mn) co-oxide filter media were adopted from a pilot-scale water treatment plant. This plant has been running for 5years continuously. Both the static and continuous flow column experiments were conducted to explore the performance and mechanism of tetracycline removal by the Fe-Mn co-oxide filter media. The results indicated that the removal process followed the quasi-secondary reaction kinetics model. The better removal efficiency could be obtained with increasing the material quantity and initial concentration. When the concentration of coexisting cations reached 0.01mol/L, the inhibition of tetracycline removal could be observed. Nevertheless, Ca2+、K+ exhibited little effect on the tetracycline removal. Through the continuous flow column experiment and the toxicity evaluation based on luminescent bacteria, it indicated that the Fe-Mn co-oxide filter media had higher tetracycline removal efficiency than that of the original quartz sand filter media, and the acute toxicity was reduced after treatment by the Fe-Mn co-oxide filter media. In addition, the experimental results of mechanism exploration confirmed that the removal of tetracycline by the Fe-Mn co-oxide filter media was a combined process of adsorption and oxidation.
姚萱, 黄廷林, 程亚, 李宇洋, 孙常席. 铁锰复合氧化物滤料去除地下水中四环素的效能[J]. 中国环境科学, 2020, 40(4): 1723-1731.
YAO Xuan, HUANG Ting-lin, CHENG Ya, LI Yu-yang, SUN Chang-xi. Removal of tetracycline in groundwater by iron-manganese co-oxide filter. CHINA ENVIRONMENTAL SCIENCECE, 2020, 40(4): 1723-1731.
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