Economic analysis of industrial ammonia pollution abatement in different forms
ZHANG Di1,2, CAO Hong-bin1,2, ZHAO Yue-hong1, ZHAO He1, LIU Chen-ming1, GUO Shao-hua1
1. Beijing Engineering Research Center of Process Pollution Control, Institute of Process Engineering, Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China
Abstract：In this research, the cost-effectiveness of ammonia treatment technologies in different species and media were revealed. A cost-benefit modelling methodology was developed to discuss the main parameters that affect the operating cost of various ammonia treatment technologies. The results showed that the critical concentration between resources-recovery and wastes-treatment of ammonia is 10%, i.e. the benefits of ammonia utilization can offset the cost of operation in this concentration. In the liquid medium, the operating cost of ammonia utilization can be as low as 0.19~0.41 Yuan/kg NH3 under alkaline condition, while it would increase by 2, 8 and 13 times respectively in the ionic forms, complex forms of heavy metal and complex forms of organic compounds respectively. In the gaseous medium, the operating cost of ammonia waste gas treatment was about -0.5~6 Yuan/kg NH3 among the eight commonly used techniques, and it would increase with the additional heating and concentration process in practical projects. What's more, the multi-media transfer of ammonia contamination was a risk factor in the actual processing. In the future, the whole-process pollution control (WPPC) should be applied to coordinate control the ammonia pollution with multiple media, so as to minimize the economic cost and environmental risk.
李涛,杨喆,周大为,等.我国水污染物排放总量控制政策评估[J]. 干旱区资源与环境, 2019,33(8):92-99. Li T, Yang Z, Zhou D, et al. Evaluation on total amount control policy of water pollution discharge in China[J]. Journal of Arid Land Resources and Environment, 2019,33(8):92-99.
[2]
许其功,曹金玲,高如泰,等.我国湖泊水质恶化趋势及富营养化控制阶段划分[J]. 环境科学与技术, 2011,34(11):147-151. Xu Q, Cao J, Gao R, et al. Trend of water quality deterioration and eutrophication control phases partition in China[J]. Environmental Science & Technology, 2011,34(11):147-151.
[3]
第二次全国污染源普查公报[R]. 公告2020年第33号, 2020-6-9. Communiqué on the second national pollution source survey[R]. Announcement No. 33of 2020, 2020-6-9.
[4]
陆学.基于资源效用视角的循环经济理论探讨[D]. 兰州:兰州大学, 2014. Lu X. A Theoretical discussion of circular economy based on resource utility[D]. Lanzhou:Lanzhou University, 2014.
[5]
欧盟委员会联合研究中心.氨、无机酸和化肥工业污染综合防治最佳可行技术[M]. 北京:化学工业出版社, 2016. Joint Research Center, European Communities. Reference document on best available techniques for the manufacture of large volume inorganic chemicals-ammonia, acids and fertilisers[M]. Beijing:Chemical Industry Press, 2016.
[6]
宗刚,杨凯.资源化回收废水中氨氮的研究进展[J]. 应用化工, 2016,45(12):2336-2338,2342. Zong G, Yang K. The research progress of ammonia nitrogen waste water treatment[J]. Applied Chemical Industry, 2016,45(12):2336-2338,2342.
[7]
钱前,史玉龙,杨红军,等.废水中氨氮脱除的技术概述[J]. 安徽化工, 2019,45(6):8-10,17. Qian Q, Shi Y, Yang H, et al. Technical overview of treatment for high NH3-N wastewater[J]. Anhui Chemical Industry, 2019,45(6):8-10,17.
[8]
张文琦.中高浓度氨氮废水处理方法的比较研究[D]. 长沙:湖南大学, 2018. Zhang W Q. Comparative study on treatment methods for ammonia nitrogen wastewater with middle-high concentration[D]. Changsha:Hunan University, 2018.
[9]
Yan Z, Zheng X, Fan J, et al. China national water quality criteria for the protection of freshwater life:Ammonia[J]. Chemosphere, 2020, 251:126379.
[10]
王孝青.高氨氮废水预处理工艺设计及运行控制技术研究[D]. 石家庄:河北科技大学, 2016. Wang X. Process design and operation control technology of high ammonia-nitrogen wastewater pretreatment[D]. Shijiazhuang:Hebei University of Science and Technology, 2016.
[11]
穆大刚.化肥工业高浓度氯化铵废水的处理技术研究[D]. 青岛:中国海洋大学, 2004. Mu D. A Study on The disposal technique of high strength ammonium-chloride wastewater from fertilizer industry[D]. Qingdao:Ocean University of China, 2004.
[12]
杨楠.磷酸铵镁结晶法去除和回收煤气化废水中的氨氮[D]. 哈尔滨:哈尔滨工业大学, 2009. Yang N. Removal and recovery of ammonia nitrogen from coal gasification wastewater with magnesium ammonium phosphate crystallization[D]. Harbin:Harbin Institute of Technology, 2009.
[13]
许海青,陶莉,刘晨明,等.LED产业含氨含氢废气处理技术发展现状[J]. 环境科技, 2019,32(2):53-56. Xu H, Tao L, Liu C, et al. Development status of ammonia-hydrogen-containing waste gas treatment technology in LED industry[J]. Environmental Science and Technology, 2019,32(2):53-56.
[14]
宋爽,高凤雨,唐晓龙,等.含氨废气的催化氧化研究进展[J]. 现代化工, 2019,39(6):31-35. Song S, Gao F, Tang X, et al. Review on catalytic oxidation of ammonia-containing waste gas. Modern Chemical Industry[J]. 2019, 39(6):31-35.
[15]
尹承龙,单忠健,计中坚.三种焦化废水处理技术的运行费用比较[J]. 给水排水, 2000,(10):43-45,1. Yin C, Shan Z, Ji Z. Comparison of operating cost in three coking wastewater treatment technologies[J]. Water & Wastewater Engineering, 2000,(10):43-45,1.
[16]
刘丽.基于LCA的AAO与AO污水处理工艺比较[D]. 大连:大连理工大学, 2015. Liu L. Comparison of AAO and AO sewage treatment process based on LCA[D]. Dalian:Dalian University of Technology, 2015.
[17]
白婧平,金明姬,齐书亭.A/O工艺在污水处理厂的运行性能及经济性评价[J]. 水处理技术, 2016,42(10):125-128. Bai J, Jin M, Qi S. The performance and economic evaluation of the A/O process in sewage treatment plant[J]. Technology of Water Treatment, 2016,42(10):125-128.
[18]
Hernandez-Sancho F, Molinos-Senante M, Sala-Garrido R. Cost modelling for wastewater treatment processes[J]. Desalination, 2011, 268:1-5.
[19]
Rama R, Jaya N S, Venkateswarlu C. Critical review of abatement of aammonia from wastewater[J]. Journal of Molecular Liquids, 2018, 261:21-31.
[20]
Gupta V K, Sadegh H, Yari M, et al. Removal of ammonium ions from wastewater:a short review in development of efficient methods[J]. Global Journal of Environmental Science and Management, 2015,1(2):149-158.
[21]
古创,姚春阳,彭磊,等.蒸氨法脱除垃圾渗滤液中氨氮的研究[J]. 中国给水排水, 2019,35(9):67-70. Gu C, Yao C, Peng L, et al. Removal of ammonia nitrogen from landfill leachate by ammonia evaporation method[J]. China Water & Wastewater, 2019,35(9):67-70.
[22]
吕秀平.超声波吹脱-化学沉淀联合工艺预处理高浓度氨氮废水与综合利用研究[D]. 兰州:兰州大学, 2009. Lü X P. Research on pretreating ammonium-nitrogen wastewater with high concentration by the jion technology of ultrasonic stripping-chemical precipitation and comprehensive utilization[D]. Lanzhou:Lanzhou University, 2009.
[23]
《2015年国家鼓励发展的环境保护技术目录(水污染治理领域)》典型应用案例[R]. 中国环境保护产业协会, 2016-1. Typical application cases of environmental protection technology directory (water pollution treatment) encouraged by the state in 2015[R]. China Environmental Protection Industry Association, 2016-1.
[24]
李梁萌,郑述平.含氨典型废气净化及工程示范装置运行总结[J]. 中氮肥, 2014,(4):1-4,26. Li L, Zheng S P. Operation summary of typical ammoniac waste gas purification and project demonstration plant[J]. M-Sized Nitrogenous Fertilizer Progress, 2014,(4):1-4,26.
[25]
沈娟.气态膜分离技术对含氨废气的回收[J]. 环境与发展, 2018,30(7):99-100. Shen J. Recovery of ammonia-containing waste gas by gas membrane separation technology[J]. Environment Development, 2018,30(7):99-100.
[26]
董智敏.某氨基酸生产企业废气改造治理工程[D]. 杭州:浙江大学, 2016. Dong Z M. Reform design engineering of waste gas for an amino aacid production enterprise[D]. Hangzhou:Zhejiang University, 2016.
[27]
李宝荣,宁永淼,向三明,等.催化氧化法处理含氨工业废气的应用探索[J]. 化工环保, 2016,36(4):449-453. Li B, Ning Y, Xiang S, et al. Application of catalytic oxidation process in treatment of ammonia-containing industrial waste gas[J]. Environmental Protection of Chemical Industry, 2016,36(4):449-453.
[28]
Chung Y, Lin Y, Tseng C. Operational characteristics of effective removal of h2s and nh3waste gases by activated carbon biofilter[J]. Journal of the Air & Waste Management Association, 2012,54:450-458.
[29]
芜湖德豪润达光电科技有限公司含氨废气回收处理项目环境影响报告书[R]. 环行审
[2016]06号. Environmental impact report on the recovery and treatment of ammonia waste gas of Elec-Tech (Wuhu) Co,. Ltd[R].
[2016] No.06.
[30]
Cao H, Zhao H, Zhang D, et al. Whole-process pollution control for cost-effective and cleaner chemical production-a case study of the tungsten industry in China[J]. Engineering, 2019,(5):768-776.
