Migration of iron and manganese ions during ice melting
ZHANG Yan1, REN Fang-yun1, TANG Yuan-qing1, ZHAO Wan-li1, ZHAO Tong-guo1, LIU Tong-shuai1, LIU Yu-can1, SHEN Hung-tao2
1. School of Civil Engineering, Yantai University, Yantai 264005, China; 2. Department of Civil and Environmental Engineering, Clarkson University, Potsdam New York 13699-5710, USA
Abstract：In order to explore the migration law of heavy metal ions in the process of ice melting, indoor simulated ice melting experiments were carried out to study the migration law with iron and manganese ions as example metal ions, and the effects of initial concentration and freezing temperature on the migration process were also analyzed. The results showed that under different initial concentrations and freezing temperatures, the concentration distribution of iron and manganese ions in ice was as follows:middle layer < upper layer < lower layer; In the process of ice melting, 51.17%~71.67% of iron and manganese ions were released in the early stage of ice melting (0~25%), and in the middle and late stages, iron and manganese ions were released stably and evenly. In addition, the initial concentration had little effect on the migration of iron and manganese ions during ice melting. When the freezing temperature was low, the concentration of iron and manganese ions increased basically in melt 1. In the process of ice melting, with the increase of accumulated melt water volume, the ratio of the concentration of iron ion and manganese ion in melt water to initial concentration of ice body gradually decreased, and showed an exponential function attenuation mode.
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