Abstract:The low-temperature plasma and a dielectric barrier discharge reactor were used to gasify poplar sawdust, cellulose, xylan and lignin. The control variable method was employed to study the effect of frequency, carrier gas on the gas production capacity, and the gasification characteristics of the chemical composition of biomass. The results showed that the lower frequency and carrier gas ionization energy could take the higher gasification rate, the best gasification rate of poplar was 64.11%. The gasification productions of xylan and cellulose were similar, the gas production rate was higher than that of cellulose and lignin and it could produce more CO. Also, lignin mainly produced coke. At the same time, SEM and BET were used to characterize the raw materials and coke, it was found that alkali metals were crystallized at high temperatures. Xylan could be melted during gasification. And the high power of plasma and more oxidizing substances could make the specific surface area of coke increased significantly, reached to 150.71m2/g.
王晴, 李先春, 李月慧, 葛玉洁, 王焕然. DBD低温等离子体气化杨木及模型化合物[J]. 中国环境科学, 2021, 41(6): 2752-2760.
WANG Qing, LI Xian-chun, LI Yue-hui, GE Yu-jie, WANG Huan-ran. DBD low-temperature plasma gasification of poplar and model compounds. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(6): 2752-2760.
Diaz G, Sharma N, Leal-Quiros E, et al. Enhanced hydrogen production using steam plasma processing of biomass:Experimental apparatus and procedure[J]. International Journal of Hydrogen Energy, 2015,40(5):2091-2098.
[2]
Cao Y, Tang M, Yang P, et al. Atmospheric low-temperature plasma-induced changes in the structure of the lignin macromolecule:An experimental and theoretical investigation[J]. Journal of Agricultural and Food Chemistry, 2019,68(2):451-460.
[3]
Favas J, Monteiro E, Rouboa A. Hydrogen production using plasma gasification with steam injection[J]. International Journal of Hydrogen Energy, 2017,42(16):10997-11005.
[4]
尚超,韦献革,白敏冬,等.低温等离子体催化降解烟气中甲苯的研究[J]. 中国环境科学, 2020,40(9):3714-3720. Shang C, Wei X G, Bai M D, et al. Degradation of toluene in flue gas by low temperature plasma catalysis[J]. Chinese Environmental Science, 2020(9):3714-3720.
[5]
黄柯靓,李国庆,刘亚男,等.常压等离子体射流去除水中糖皮质激素污染物[J]. 中国环境科学, 2020,40(8):3417-3423. Huang K L, Li G Q, Liu Y N, et al. Degradation of glucocorticoids in water by atmospheric pressure plasma jet[J]. Chinese Environmental Science, 2020,40(8):3417-3423.
[6]
Benoit M, Rodrigues A, Zhang Q, et al. Depolymerization of cellulose assisted by a nonthermal atmospheric plasma[J]. Angewandte Chemie International Edition, 2011,50(38):8964-8967.
[7]
Grigaitienė V, Snapkauskienė V, Valatkevičius P, et al. Water vapor plasma technology for biomass conversion to synthetic gas[J]. Catalysis Today, 2011,167(1):135-140.
[8]
Sikarwar V S, Zhao M, Clough P, et al. An overview of advances in biomass gasification[J]. Energy & Environmental Science, 2016,9:2939-2977.
[9]
Pang Y, Hammer T, Müller D, et al. Investigation on the influence of non-thermal plasma on reaction degree of wood gasification in a drop tube reactor[J]. Fuel, 2019,253:95-105.
[10]
Xu B, Xie J, Yin X, et al. Mechanisms of toluene removal in relation to the main components of biosyngas in a catalytic nonthermal plasma process[J]. Energy & Fuels, 2019,33(5):4287-4301.
[11]
Liu S, Mei D, Wang L, et al. Steam reforming of toluene as biomass tar model compound in a gliding arc discharge reactor[J]. Chemical Engineering Journal, 2017,307:793-802.
[12]
Zhu F, Zhang H, Yang H, et al. Plasma reforming of tar model compound in a rotating gliding arc reactor:Understanding the effects of CO2 and H2O addition[J]. Fuel, 2020,259:116271.
[13]
Saleem F, Harris J, Zhang K, et al. Non-thermal plasma as a promising route for the removal of tar from the product gas of biomass gasification-A critical review[J]. Chemical Engineering Journal, 2020,382:122761.
[14]
Wang Y, Yang H, Tu X. Plasma reforming of naphthalene as a tar model compound of biomass gasification[J]. Energy Conversion and Management, 2019,187:593-604.
[15]
杜长明,黄娅妮,巩向杰.等离子体净化苯系物[J]. 中国环境科学, 2018,38(3):871-892. Du C M, Huang Y N, Gong X J, et al. Decomposition of benzene series by plasma technology[J]. Chinese Environmental Science, 2018,38(3):871-892.
[16]
刘立.我国能源供应体系建设的思考[J]. 国土资源情报, 2019, (12):58-63. Liu L. Thoughts on the construction of China's energy supply system[J]. Land and Resources Information, 2019,(12):58-63.
[17]
Dhyani V, Bhaskar T. A comprehensive review on the pyrolysis of lignocellulosic biomass[J]. Renewable Energy, 2018,129:695-716.
[18]
Deng J, Xiong T, Wang H, et al. Effects of cellulose, hemicellulose, and lignin on the structure and morphology of porous carbons[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016,4(7):3750-3756.
[19]
杜长明,吴焦,黄娅妮.等离子体热解气化有机废弃物制氢的关键技术分析[J]. 中国环境科学, 2016,36(11):3429-3440. Du C M, Wu J, Huang Y N. Analysis of critical technology for hydrogen production in plasma pyrolysis and gasification of organic waste[J]. Chinese Environmental Science, 2016,36(11):3429-3440.
[20]
Blanquet E, Nahil M A, Williams P T. Enhanced hydrogen-rich gas production from waste biomass using pyrolysis with non-thermal plasma-catalysis[J]. Catalysis Today, 2019,337:216-224.
[21]
Du C, Wu J, Ma D, et al. Gasification of corn cob using non-thermal arc plasma[J]. International Journal of Hydrogen Energy, 2015, 40(37):12634-12649.
[22]
Huang X, Cheng D, Chen F, et al. Reaction pathways of hemicellulose and mechanism of biomass pyrolysis in hydrogen plasma:A density functional theory study[J]. Renewable Energy, 2016,96:490-497.
[23]
Minami E, Fujimoto S, Saka S. Complete gasification of cellulose in glow-discharge plasma[J]. Journal of Wood Science, 2018,64(6):854-860.
[24]
闫兴伟,崔琳,张林,等.杨木制备纤维乙醇过程中化学成分变化的分析[J]. 中南林业科技大学学报, 2015,35(2):119-122. Yan X W, Cui L, Zhang L, et al. Analysis on chemical components changes in preparation process of cellulosic ethanol from poplar wood[J]. Journal of Central South University of Forestry & Technology, 2015,35(2):119-122.
[25]
Xu F, Shi Y, Wang D, et al. X-ray scattering studies of lignocellulosic biomass:A review[J]. Carbohydrate Polymers, 2013,94(2):904-917.
[26]
Wang S, Dai G, Yang H, et al. Lignocellulosic biomass pyrolysis mechanism:A state-of-the-art review[J]. Progress in Energy and Combustion Science, 2017,62:33-86.
[27]
Carolina F P. Modelling of tar formation and evolution for biomass gasification:A review[J]. Applied Energy, 2013,111:129-141.
[28]
Collard F, Blin J. A review on pyrolysis of biomass constituents:Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin[J]. Renewable and Sustainable Energy Reviews, 2014,38:594-608.
[29]
Wang S, Ru B, Lin H, et al. Degradation mechanism of monosaccharides and xylan under pyrolytic conditions with theoretic modeling on the energy profiles[J]. Bioresource Technology, 2013, 143:378-383.