Research progress on the enantioselectivity of a neonicotinoid pesticide dinotefuran
LIU Zi-qi1,2, HU Xiao1,2, LI Li1, ZHU Feng3, YUAN Long-fei1, LI Wei1, CHENG You-pu2, CHEN Zeng-long1
1. State Key Laboratory of Integrated Management of Pest Insects and Rodents, Institute of Zoology, Chinese Academy of Sciences, Beijing 100101, China; 2. College of Horticulture and Landscape, Tianjin Agricultural University, Tianjin 300384, China; 3. Guizhou Institute of Plant Protection, Guiyang 550006, China
Abstract:In the agricultural production, dinotefuran is sold and used in the form of racemate. Enantioselective degradation, absorption, metabolism and excretion of dinotefuran were observed in the ecological environment. Traditional risk assessments brought potential hazards to the rational use and ecological safety of dinotefuran without consideration of the differences between enantiomers. S-dinotefuran was an enantiomer with both high toxicities and activities, and its ecological toxicities were 13.9~145.9times than that of R-dinotefuran. However, R-dinotefuran also had comparable bioactivities and degraded preferentially in crops. The development of a high proportion of R-form pesticide could maintain the insecticidal potency and further reduce the negative effects to non-target organisms and ecological environment. This manuscript aimed to review the research progress on the enantioselective bioactivity, ecotoxicology, and environmental fate of dinotefuran, which will be conducive to propose novel ideas for solving the above scientific problems and further to provide theoretical foundation for effective management of dinotefuran.
刘子琪, 呼啸, 李莉, 朱峰, 袁龙飞, 李薇, 程有普, 陈增龙. 新烟碱类农药呋虫胺对映体选择性研究进展[J]. 中国环境科学, 2021, 41(10): 4811-4819.
LIU Zi-qi, HU Xiao, LI Li, ZHU Feng, YUAN Long-fei, LI Wei, CHENG You-pu, CHEN Zeng-long. Research progress on the enantioselectivity of a neonicotinoid pesticide dinotefuran. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(10): 4811-4819.
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