Abstract:As one of the most commonly used nanoparticles, nano zero valent iron (nZVI) had been extensively studied in the removal of pollutants from environmental water. This review systematically and comprehensively summarized the related progress of nZVI, introduced various aspects of nZVI and then guided its development direction. Among them, the research contents mainly included preparation method, modification method, mechanism of action and catalytic mechanism for removing different pollutants in water, application in site research, and mechanism of toxicity. In this paper, it was found that there were still problems such as lack of comprehensive evaluation methods, limited application, and asynchronous research on nano zero valent iron. The future development of nZVI should have evaluation methods that consider reactivity, stability, mobility, and toxicity, to avoid the time difference of the same modified material in different research directions, so that the application of nZVI can be better applied to field research, and promote the application of nZVI in the field.
张永祥, 杜伟, 李雅君, 赵崇辉. 纳米零价铁在水处理中的应用研究综述[J]. 中国环境科学, 2022, 42(11): 5163-5178.
ZHANG Yong-xiang, DU Wei, LI Ya-jun, ZHAO Chong-hui. A review of nano zero valent iron in water treatment. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(11): 5163-5178.
Wang C M, Baer D R, Thomas L E, et al. Void formation during early stages of passivation:Initial oxidation of iron nanoparticles at room temperature[J]. Journal of Applied Physics, 2005,98(9):94308.
[2]
Qian J, Gao X, Pan B. Nanoconfinement-mediated water treatment:from fundamental to application[J]. Environmental Science & Technology, 2020,54(14):8509-8526.
[3]
Lefevre E, Bossa N, Wiesner M R, et al. A review of the environmental implications of in situ remediation by nanoscale zero valent iron (nZVI):Behavior, transport and impacts on microbial communities[J]. Science of The Total Environmen, 2016,565:889-901.
[4]
Mukherjee R, Kumar R, Sinha A, et al. A review on synthesis, characterization, and applications of nano zero valent iron (nZVI) for environmental remediation[J]. Critical reviews in environmental science and technology, 2016,46(5):443-466.
[5]
Wang P, Fu F, Liu T. A review of the new multifunctional nano zero-valent iron composites for wastewater treatment:Emergence, preparation, optimization and mechanism[J]. Chemosphere, 2021,285:131435.
[6]
Stefaniuk M, Oleszczuk P, Ok Y S. Review on nano zerovalent iron (nZVI):from synthesis to environmental applications[J]. Chemical Engineering Journal, 2016,287:618-632.
[7]
Chen X, Yao X, Yu C, et al. Hydrodechlorination of polychlorinated biphenyls in contaminated soil from an e-waste recycling area, using nanoscale zerovalent iron and Pd/Fe bimetallic nanoparticles[J]. Environmental Science and Pollution Research, 2014,21(7):5201-5210.
[8]
Jamei M R, Khosravi M R, Anvaripour B. A novel ultrasound assisted method in synthesis of nzvi particles[J]. Ultrasonics Sonochemistry, 2014,21(1):226-233.
[9]
Ribas D, Pešková K, Jubany I, et al. High reactive nano zero-valent iron produced via wet milling through abrasion by alumina[J]. Chemical Engineering Journal, 2019,366:235-245.
[10]
Liang Z, Yan Q, Chen D. Degradation of p-nitrophenol by nanoscale zero-valent iron produced by Microwave-Assisted Ball Milling[J]. Journal of Environmental Engineering, 2018,144(3):04018003.
[11]
Chen S, Hsu H, Li C. A new method to produce nanoscale iron for nitrate removal[J]. Journal of Nanoparticle Research, 2004,6(6):639-647.
[12]
Long Y, Liang J, Xue Y. Ultrasound-assisted electrodeposition synthesis of nZVI-Pd/AC toward reductive degradation of methylene blue[J]. Environmental Science and Pollution Research, 2021,28(47):67098-67107.
[13]
Fazlzadeh M, Rahmani K, Zarei A, et al. A novel green synthesis of zero valent iron nanoparticles (NZVI) using three plant extracts and their efficient application for removal of Cr(VI) from aqueous solutions[J]. Advanced Powder Technology, 2017,28(1):122-130.
[14]
Dumitrache F, Morjan I, Alexandrescu R, et al. Nearly monodispersed carbon coated iron nanoparticles for the catalytic growth of nanotubes/nanofibres[J]. Diamond and Related Materials, 2004,13(2):362-370.
[15]
Wang S, Zhao M, Zhou M, et al. Biochar-supported nZVI (nZVI/BC) for contaminant removal from soil and water:A critical review[J]. Journal of Hazardous Materials, 2019,373:820-834.
[16]
Fu R, Zhang X, Xu Z, et al. Fast and highly efficient removal of chromium (VI) using humus-supported nanoscale zero-valent iron:Influencing factors, kinetics and mechanism[J]. Separation and Purification Technology, 2017,174:362-371.
[17]
Fan W, Cheng Y, Yu S, et al. Preparation of wrapped nZVI particles and their application for the degradation of trichloroethylene (TCE) in aqueous solution[J]. Journal of Water Reuse and Desalination, 2015, 5(3):335-343.
[18]
Wang Q, Kanel S R, Park H, et al. Controllable synthesis, characterization, and magnetic properties of nanoscale zerovalent iron with specific high Brunauer-Emmett-Teller surface area[J]. Journal of Nanoparticle Research, 2009,11(3):749-755.
[19]
Cheng Y, Dong H, Hao T. CaCO3 coated nanoscale zero-valent iron (nZVI) for the removal of chromium(VI) in aqueous solution[J]. Separation and Purification Technology, 2021,257:117967.
[20]
Azad A, Kesavan S, Al-Batty S. A closed-loop proposal for hydrogen generation using steel waste and a prototype solar concentrator[J]. International Journal of Energy Research, 2009,33(5):481-498.
[21]
Visentin C, Trentin A W D S, Braun A B, et al. Lifecycle assessment of environmental and economic impacts of nano-iron synthesis process for application in contaminated site remediation[J]. Journal of Cleaner Production, 2019,231:307-319.
[22]
shashanka r s r, uzun o u o, chaira d c d. Synthesis of nano-structured duplex and ferritic stainless steel powders by dry milling and its comparison with wet milling[J]. archives of metallurgy and materials, 2020,65(1):5-14.
[23]
Gu Y, Wang B, He F, et al. Mechanochemically sulfidated microscale zero valent iron:pathways, kinetics, mechanism, and efficiency of trichloroethylene dechlorination[J]. Environmental Science & Technology, 2017,51(21):12653-12662.
[24]
Zhang W. Nanoscale iron particles for environmental remediation:an overview[J]. Journal of nanoparticle research:An Interdisciplinary Forum for Nanoscale Science and Technology, 2003,5(3):323-332.
[25]
Akhgar B N, Pourghahramani P. Implementation of sonochemical leaching for preparation of nano zero-valent iron (NZVI) from natural pyrite mechanochemically reacted with Al[J]. International Journal of Mineral Processing, 2017,164:1-5.
[26]
Ribas D, Cernik M, Martí V, et al. Improvements in nanoscale zero-valent iron production by milling through the addition of alumina[J]. Journal of Nanoparticle Research, 2016,18(7):1-11.
[27]
程荣,王建龙,张伟贤.纳米金属铁降解有机卤化物的研究进展[J]. 化学进展, 2006,1:93-99. Cheng R, Wang J L, Zhang W X, et al. The research progress on degradation of halogenated organic compounds by Nano Iron[J]. Progress In Chemistry, 2006,1:93-99.
[28]
Gu Y, Zhao J, Liu Q, et al. Zero-valent iron (Fe(0)) mediated RAFT miniemulsion polymerization:a facile approach for the fabrication of Fe(0)-encapsulated polymeric nanoparticles[J]. Polymer Chemistry, 2014,5(14):4215.
[29]
Huang Y, Yang C, Lang J, et al. Metal nanoparticle harvesting by continuous rotating electrodeposition and separation[J]. Matter, 2020,3(4):1294-1307.
[30]
Slijepčević N, Pilipović D T, Kerkez, et al. A cost effective method for immobilization of Cu and Ni polluted river sediment with nZVI synthesized from leaf extract[J]. Chemosphere, 2021,263:127816.
[31]
Monga Y, Kumar P, Sharma R K, et al. Sustainable Synthesis of Nanoscale Zerovalent Iron Particles for Environmental Remediation[J]. ChemSusChem, 2020,13(13):3288-3305.
[32]
Martins F, Machado S, Albergaria T, et al. LCA applied to nano scale zero valent iron synthesis[J]. The International Journal of Life Cycle Assessment, 2017,5(22):707-714.
[33]
Nisticò R, Carlos L. High yield of nano zero-valent iron (nZVI) from carbothermal synthesis using lignin-derived substances from municipal biowaste[J]. Journal of Analytical and Applied Pyrolysis, 2019,140:239-244.
[34]
Song Y, Wang L, Lv B, et al. Removal of trace Cr(VI) from aqueous solution by porous activated carbon balls supported by nanoscale zero-valent iron composites[J]. Environmental Science and Pollution Research, 2020,27(7):7015-7024.
[35]
Zhang H, Ruan Y, Liang A, et al. Carbothermal reduction for preparing nZVI/BC to extract uranium:Insight into the iron species dependent uranium adsorption behavior[J]. Journal of Cleaner Production, 2019,239:117873.
[36]
Hoch L B, Mack E J, Hydutsky B W, et al. Carbothermal synthesis of carbon-supported nanoscale zero-valent iron particles for the Remediation of Hexavalent Chromium[J]. Environmental Science & Technology, 2008,42(7):2600-2605.
[37]
Meng F, Li Z, Lei C, et al. Removal of trichloroethene by iron-based biochar from anaerobic water:key roles of Fe/C ratio and iron carbides[J]. Chemical Engineering Journal, 2021,413:127391.
[38]
Liu X, Yang L, Zhao H, et al. Pyrolytic production of zerovalent iron nanoparticles supported on rice husk-derived biochar:simple, in situ synthesis and use for remediation of Cr(VI)-polluted soils[J]. Science of The Total Environment, 2020,708:134479.
[39]
Dai Y, Hu Y, Jiang B, et al. Carbothermal synthesis of ordered mesoporous carbon-supported nano zero-valent iron with enhanced stability and activity for hexavalent chromium reduction[J]. Journal of Hazardous Materials, 2016,309:249-258.
[40]
Wang Z M, Wang D, Zhang L L, et al. Efficient preparation of nanoscale zero-valent iron by high gravity technology for enhanced Cr(VI) removal[J]. The Canadian Journal of Chemical Engineering, 2019,97(S1):1451-1458.
[41]
Liu H, Wang Q, Wang C, et al. Electron efficiency of zero-valent iron for groundwater remediation and wastewater treatment[J]. Chemical Engineering Journal, 2013,215:90-95.
[42]
Zhou L, Li Z, Yi Y, et al. Increasing the electron selectivity of nanoscale zero-valent iron in environmental remediation:A review[J]. Journal of hazardous materials, 2022,421:126709.
[43]
Duan L, Dai Y, Shi L, et al. Humic acid addition sequence and concentration affect sulfur incorporation, electron transfer, and reactivity of sulfidated nanoscale zero-valent iron[J]. Chemosphere 2022,294:133826.
[44]
Hou J, Li Y, Ci H, et al. Influence of aggregation and sedimentation behavior of bare and modified zero-valent-iron nanoparticles on the Cr(VI) removal under various groundwater chemistry conditions[J]. Chemosphere, 2022,296:133905.
[45]
Jung B, O'Carroll D, Sleep B. The influence of humic acid and clay content on the transport of polymer-coated iron nanoparticles through sand[J]. Science of The Total Environment, 2014,496:155-164.
[46]
Wu Y, Dong H, Tang L, et al. Influence of humic acid and its different molecular weight fractions on sedimentation of nanoscale zero-valent iron[J]. Environmental Science and Pollution Research, 2020,27(3):2786-2796.
[47]
Ezzatahmadi N, Ayoko G A, Millar G J, et al. Clay-supported nanoscale zero-valent iron composite materials for the remediation of contaminated aqueous solutions:A review[J]. Chemical Engineering Journal, 2017,312:336-350.
[48]
Unuabonah E I, Taubert A. Clay-polymer nanocomposites (CPNs):Adsorbents of the future for water treatment[J]. Applied Clay Science, 2014,99:83-92.
[49]
刘学,李小燕,陈玉洁,等.石墨负载纳米零价铁去除溶液中U(Ⅵ)[J]. 中国有色金属学报, 2020,30(8):1967-1973. Liu X, Li X Y, Chen X J, et al.Removal of U(Ⅵ) in aqueous solution by graphite loading nano-zero-valent iron[J]. The Chinese Journal of Nonferrous Metals, 2020,30(8):1967-1973.
[50]
Zhang S, Lyu H, Tang J, et al. A novel biochar supported CMC stabilized nano zero-valent iron composite for hexavalent chromium removal from water[J]. Chemosphere, 2019,217:686-694.
[51]
Wen R, Tu B, Guo X, et al. An ion release controlled Cr(VI) treatment agent:nano zero-valent iron/carbon/alginate composite gel[J]. International Journal of Biological Macromolecules, 2020,146:692-704.
[52]
Wang Z, Yang J, Li Y, et al. In situ carbothermal synthesis of nanoscale zero-valent iron functionalized porous carbon from metal-organic frameworks for efficient detoxification of chromium (VI)[J]. European Journal of Inorganic Chemistry, 2018,2018(1):23-30.
[53]
Tran M L, Nguyen C H, Tran T T V, et al. One-pot synthesis of bimetallic Pt/nZVI nanocomposites for enhanced removal of oxytetracycline:roles of morphology changes and Pt catalysis[J]. Journal of the Taiwan Institute of Chemical Engineers, 2020,111:130-140.
[54]
Ryu A, Jeong S, Jang A, et al. Reduction of highly concentrated nitrate using nanoscale zero-valent iron:effects of aggregation and catalyst on reactivity[J]. Applied Catalysis B:Environmental, 2011,105(1/2):128-135.
[55]
Chang C, Lian F, Zhu L. Simultaneous adsorption and degradation of γ-HCH by nZVI/Cu bimetallic nanoparticles with activated carbon support[J]. Environmental Pollution, 2011,159(10):2507-2514.
[56]
Wang X, Wang W, Lowry G, et al. Preparation of palladized carbon nanotubes encapsulated iron composites:highly efficient dechlorination for trichloroethylene and low corrosion of nanoiron[J]. Royal Society open science, 2018,5(6):172242.
[57]
He F, Li Z, Shi S, et al. Dechlorination of excess trichloroethene by bimetallic and sulfidated nanoscale zero-valent iron[J]. Environmental Science & Technology, 2018,52(15):8627-8637.
[58]
Wang T, Su J, Jin X, et al. Functional clay supported bimetallic nZVI/Pd nanoparticles used for removal of methyl orange from aqueous solution[J]. Journal Of Hazardous Materials, 2013,262:819-825.
[59]
Venkateshaiah A, Silvestri D, Wacławek S, et al. A comparative study of the degradation efficiency of chlorinated organic compounds by bimetallic zero-valent iron nanoparticles[J]. Environmental science water research & technology, 2021,8(1):162-172.
[60]
Huang K, Bian H, Zhang M, et al. Characterization of bimetallic Fe/Ni nanoparticles supported by amphiphilic block copolymer and its application in removal of 1,1,1-trichloroethane in water[J]. Environ Sci Pollut Res Int, 2020,27(27):34503-34512.
[61]
Qu G, Chu R, Wang H, et al. Simultaneous removal of chromium(VI) and tetracycline hydrochloride from simulated wastewater by nanoscale zero-valent iron/copper-activated persulfate[J]. Environmental Science and Pollution Research, 2020,27(32):40826-40836.
[62]
Zhang D, Li Y, Sun A, et al. Enhanced nitrobenzene reduction by modified biochar supported sulfidated nano zerovalent iron:Comparison of surface modification methods[J]. Science of The Total Environment, 2019,694:133701.
[63]
Wu G, Kong W, Gao Y, et al. Removal of chloramphenicol by sulfide-modified nanoscale zero-valent iron activated persulfate:Performance, salt resistance, and reaction mechanisms[J]. Chemosphere, 2022,286(Pt 3):131876.
[64]
Su Y, Adeleye A S, Keller A A, et al. Magnetic sulfide-modified nanoscale zerovalent iron (S-nZVI) for dissolved metal ion removal[J]. Water Research, 2015,74:47-57.
[65]
Li J, Zhang X, Sun Y, et al. Advances in sulfidation of zerovalent iron for water decontamination[J]. Environmental Science & Technology, 2017,51(23):13533-13544.
[66]
Xu J, Avellan A, Li H, et al. Sulfur loading and speciation control the hydrophobicity, electron transfer, reactivity, and selectivity of sulfidized nanoscale Zerovalent Iron[J]. Advanced Materials, 2020, 32(17):1906910.
[67]
Xu J, Avellan A, Li H, et al. Iron and sulfur precursors affect crystalline structure, speciation, and reactivity of sulfidized nanoscale zerovalent iron[J]. Environmental Science & Technology, 2020, 54(20):13294-13303.
[68]
Zhan J, Yang X, Zhang X, et al. Bioprecipitation facilitates the green synthesis of sulfidated nanoscale zero-valent iron particles for highly selective dechlorination of trichloroethene[J]. Journal of Environmental Chemical Engineering, 2021,9(5):106050.
[69]
Mangayayam M C, Perez J P H, Dideriksen K, et al. Structural transformation of sulfidized zerovalent iron and its impact on long-term reactivity[J]. Environmental science-Nano, 2019,6(11):3422-3430.
[70]
Liang L, Li X, Guo Y, et al. The removal of heavy metal cations by sulfidated nanoscale zero-valent iron (S-nZVI):The reaction mechanisms and the role of sulfur[J]. Journal of Hazardous Materials, 2021,404:124057.
[71]
Ren L, Dong J, Chi Z, et al. Reduced graphene oxide-nano zero value iron (rGO-nZVI) micro-electrolysis accelerating Cr(VI) removal in aquifer[J]. Journal of Environmental Sciences, 2018,73:96-106.
[72]
Dong H, He Q, Zeng G, et al. Chromate removal by surface-modified nanoscale zero-valent iron:Effect of different surface coatings and water chemistry[J]. Journal of Colloid and Interface Science, 2016, 471:7-13.
[73]
Wan J, Feng X, Li Y, et al. Effect of mesoporous silica molecular sieve coating on nZVI for 2,4-DCP degradation:Morphology and mechanism during the reaction[J]. Chemical Engineering and Processing-Process Intensification, 2019,135:68-81.
[74]
Dong H, Lo I M C. Influence of humic acid on the colloidal stability of surface-modified nano zero-valent iron[J]. Water Research, 2013,47(1):419-427.
[75]
周红艺,陈勇,梁思,等.海藻酸钠固定化纳米铁还原脱色活性红X3B[J]. 中国环境科学, 2016,36(12):3576-3582. Zhou H Y, Chen Y, Liang S, et al. Reductive decolorization of azo-dye X3B by sodium alginate immobilized iron nanoparticles[J]. China Environment Science, 2016,36(12):3576-3582.
[76]
Lu H J, Wang J K, Ferguson S, et al. Mechanism, synthesis and modification of nano zerovalent iron in water treatment[J]. Nanoscale, 2016,8(19):9962-9975.
[77]
Hua Y, Li D, Gu T, et al. Enrichment of uranium from aqueous solutions with nanoscale zero-valent iron:Surface Chemistry and Application Prospect[J]. Acta Chimica Sinica, 2021,79(8):1008-1022.
[78]
Xie Y, Lu G, Tao X, et al. A collaborative strategy for elevated reduction and immobilization of Cr(VI) using nano zero valent iron assisted by schwertmannite:Removal performance and mechanism[J]. Journal of Hazardous Materials, 2022,422:126952.
[79]
O Carroll D, Sleep B, Krol M, et al. Nanoscale zero valent iron and bimetallic particles for contaminated site remediation[J]. Advances in Water Resources, 2013,51:104-122.
[80]
Pan Y, Leung P, Li Y, et al. Enhancement effect of nanoscale zero-valent iron addition on microbial degradation of BDE-209 in contaminated mangrove sediment[J]. Science of The Total Environment, 2021,781:146702.
[81]
Lee C, Sedlak D L. Enhanced formation of oxidants from bimetallic nickel-Iron nanoparticles in the presence of oxygen[J]. Environmental Science & Technology, 2008,42(22):8528-8533.
[82]
Anang E, Liu H, Fan X, et al. Compositional evolution of nanoscale zero valent iron and 2,4-dichlorophenol during dechlorination by attapulgite supported Fe/Ni nanoparticles[J]. Journal of Hazardous Materials, 2021,412:125246.
[83]
Rodríguez-Maroto J M, García-Herruzo F, García-Rubio A, et al. Kinetics of the chemical reduction of nitrate by zero-valent iron[J]. Chemosphere, 2009,74(6):804-809.
[84]
Yoshino H, Kawase Y. Kinetic modeling and simulation of zero-valent iron wastewater treatment process:simultaneous reduction of Nitrate, hydrogen peroxide, and phosphate in semiconductor acidic wastewater[J]. Industrial & Engineering Chemistry Research, 2013, 52(50):17829-17840.
[85]
Shan A, Idrees A, Zaman W Q, et al. Synthesis of nZVI-Ni@BC composite as a stable catalyst to activate persulfate:trichloroethylene degradation and insight mechanism[J]. Journal of Environmental Chemical Engineering, 2021,9(1):104808.
[86]
Nagoya S, Nakamichi S, Kawase Y. Mechanisms of phosphate removal from aqueous solution by zero-valent iron:a novel kinetic model for electrostatic adsorption, surface complexation and precipitation of phosphate under oxic conditions[J]. Separation and Purification Technology, 2019,218:120-129.
[87]
Hamid S, Abudanash D, Han S, et al. Strategies to enhance the stability of nanoscale zero-valent iron (NZVI) in continuous BrO3− reduction[J]. Journal of environmental management, 2019,231:714-725.
[88]
Xie Y, Yi Y, Qin Y, et al. Perchlorate degradation in aqueous solution using chitosan-stabilized zero-valent iron nanoparticles[J]. Separation and Purification Technology, 2016,171:164-173.
[89]
Li S, Tang J, Wang L, et al. Carbon coating enhances single-electron oxygen reduction reaction on nZVI surface for oxidative degradation of nitrobenzene[J]. Science of The Total Environment, 2021,770:144680.
[90]
Xu X, Li X. Degradation of azo dye orange g in aqueous solutions by persulfate with ferrous ion[J]. Separation and Purification Technology, 2010,72(1):105-111.
[91]
Raji M, Mirbagheri S A, Ye F, et al. Nano zero-valent iron on activated carbon cloth support as Fenton-like catalyst for efficient color and COD removal from melanoidin wastewater[J]. Chemosphere, 2021,263:127945.
[92]
Gu M, Farooq U, Lu S, et al. Degradation of trichloroethylene in aqueous solution by rGO supported nZVI catalyst under several oxic environments[J]. Journal of Hazardous Materials, 2018,349:35-44.
[93]
Eljamal O, Thompson I P, Maamoun I, et al. Investigating the design parameters for a permeable reactive barrier consisting of nanoscale zero-valent iron and bimetallic iron/copper for phosphate removal[J]. Journal of molecular liquids, 2020,299:112144.
[94]
Tosco T, Petrangeli Papini M, Cruz Viggi C, et al. Nanoscale zerovalent iron particles for groundwater remediation:areview[J]. Journal of cleaner production, 2014,77:10-21.
[95]
Li Q, Chen Z, Wang H, et al. Removal of organic compounds by nanoscale zero-valent iron and its composites[J]. Science of The Total Environment, 2021,792:148546.
[96]
Calderon B, Fullana A. Heavy metal release due to aging effect during zero valent iron nanoparticles remediation[J]. Water Research, 2015, 83:1-9.
[97]
Bian H, Wan J, Muhammad T, et al. Computational study and optimization experiment of nZVI modified by anionic and cationic polymer for Cr(VI) stabilization in soil:Kinetics and response surface methodology (RSM)[J]. Environmental Pollution, 2021,276:116745.
[98]
Busch J, Meißner T, Potthoff A, et al. A field investigation on transport of carbon-supported nanoscale zero-valent iron (nZVI) in groundwater[J]. Journal of Contaminant Hydrology, 2015,181:59-68.
[99]
Mueller N C, Braun J, Bruns J, et al. Application of nanoscale zero valent iron (NZVI) for groundwater remediation in Europe[J]. Environmental Science and Pollution Research, 2012,19(2):550-558.
[100]
Mondal P K, Furbacher P D, Cui Z, et al. Transport of polymer stabilized nano-scale zero-valent iron in porous media[J]. Journal of Contaminant Hydrology, 2018,212:65-77.
[101]
Asad M A, Khan U T, Krol M M. Subsurface transport of carboxymethyl cellulose (CMC)-stabilized nanoscale zero valent iron (nZVI):Numerical and statistical analysis[J]. Journal of Contaminant Hydrology, 2021,243:103870.
[102]
Ahn J, Kim C, Kim H, et al. Effects of oxidants on in situ treatment of a DNAPL source by nanoscale zero-valent iron:A field study[J]. Water Research, 2016,107:57-65.
[103]
Wei Y, Wu S, Chou C, et al. Influence of nanoscale zero-valent iron on geochemical properties of groundwater and vinyl chloride degradation:A field case study[J]. Water Research, 2010,44(1):131-140.
[104]
Qian L, Chen Y, Ouyang D, et al. Field demonstration of enhanced removal of chlorinated solvents in groundwater using biochar-supported nanoscale zero-valent iron[J]. Science of The Total Environment, 2020,698:134215.
[105]
Li S, Wang W, Yan W, et al. Nanoscale zero-valent iron (nZVI) for the treatment of concentrated Cu(II) wastewater:a field demonstration[J]. Environ Sci Process Impacts, 2014,16(3):524-533.
[106]
Chowdhury A I A, Krol M M, Kocur C M, et al. nZVI injection into variably saturated soils:Field and modeling study[J]. Journal of Contaminant Hydrology, 2015,183:16-28.
[107]
Ahn J, Kim C, Jun S, et al. Field-scale investigation of nanoscale zero-valent iron (NZVI) injection parameters for enhanced delivery of NZVI particles to groundwater[J]. Water Research, 2021,202:117402.
[108]
Nunez Garcia A, Boparai H K, de Boer C V, et al. Fate and transport of sulfidated nano zerovalent iron (S-nZVI):A field study[J]. Water Research, 2020,170:115319.
[109]
Kocur C M, Chowdhury A I, Sakulchaicharoen N, et al. Characterization of nZVI Mobility in a Field Scale Test[J]. Environmental Science & Technology, 2014,48(5):2862-2869.
[110]
Sun H, Wang J, Jiang Y, et al. Rapid aerobic inactivation and facile removal of escherichia coli with amorphous zero-valent iron Microspheres:Indispensable Roles of Reactive Oxygen Species and Iron Corrosion Products[J]. Environmental Science & Technology, 2019,53(7):3707-3717.
[111]
Lee C, Kim J Y, Lee W I, et al. Bactericidal effect of zero-valent iron nanoparticles on escherichia coli[J]. Environmental science & technology, 2008,42(13):4927-4933.
[112]
王见.纳米零价铁对大肠肝菌细胞毒性机制研究[D]. 武汉:华中师范大学, 2020. Wang J. Research on the cytotoxicity mechanism of nanoscale zero-valent iron to E.coli[D]. Wuhan Central China Normal University, 2020.
[113]
Lin J, Xue C, Guo S, et al. Effects of green synthesized and commercial nZVI on crystal violet degradation by Burkholderia vietnamiensis C09V:Dose-dependent toxicity and biocompatibility[J]. Chemosphere, 2021,279:130612.
[114]
Jiang C, Xu X, Megharaj M, et al. Inhibition or promotion of biodegradation of nitrate by Paracoccus sp. in the presence of nanoscale zero-valent iron[J]. Science of The Total Environment, 2015,530-531:241-246.
[115]
陆贤,郭美婷,张伟贤.纳米零价铁对耐四环素菌耐药特性的影响[J]. 中国环境科学, 2017,37(1):381-385. Lu X, Guo M T, Zhang W X, et al. Influence of nanoscale zero-valent iron (nZVI) on resistance character of tetracycline resistant bacteria[J]. China Environment Science, 2017,37(1):381-385.
[116]
Phenrat T, Long T C, Lowry G V, et al. Partial oxidation ("aging") and surface modification decrease the toxicity of nanosized zerovalent Iron[J]. Environmental Science & Technology, 2009,43(1):195-200.
[117]
Cheng Y, Dong H, Lu Y, et al. Toxicity of sulfide-modified nanoscale zero-valent iron to Escherichia coli in aqueous solutions[J]. Chemosphere, 2019,220:523-530.
[118]
Hu Y, Wang J, Sun H, et al. Roles of extracellular polymeric substances in the bactericidal effect of nanoscale zero-valent iron:trade-offs between physical disruption and oxidative damage[J]. Environmental Science-Nano, 2019,6(7):2061-2073.
[119]
Dong H, Lo I M C. Influence of humic acid on the colloidal stability of surface-modified nano zero-valent iron[J]. Water Research, 2013, 47(1):419-427.
[120]
Chen J, Xiu Z, Lowry G V, et al. Effect of natural organic matter on toxicity and reactivity of nano-scale zero-valent iron[J]. Water Research, 2011,45(5):1995-2001.
[121]
Uskoković V, Huynh E, Wu V M. Mimicking the transit of nanoparticles through the body:when the path determines properties at the destination[J]. Journal of Nanoparticle Research, 2020,22(7):1-27.
[122]
Yoon H, Pangging M, Jang M, et al. Impact of surface modification on the toxicity of zerovalent iron nanoparticles in aquatic and terrestrial organisms[J]. Ecotoxicology and Environmental Safety, 2018,163:436-443.
[123]
Ghosh I, Mukherjee A, Mukherjee A. Nanoscale zerovalent iron particles induce differential cytotoxicity, genotoxicity, oxidative stress and hemolytic responses in human lymphocytes and erythrocytes in vitro[J]. Journal of Applied Toxicology, 2019,39(12):1623-1639.
[124]
Semerad J, Pacheco N I N, Grasserova A, et al. In vitro study of the toxicity mechanisms of nanoscale zero-valent Iron (nZVI) and released iron ions ssing earthworm cells[J]. Nanomaterials, 2020, 10(11):2189.