Abstract:In order to evaluate the accuracy of BAM (Beta Attenuation Monitor) with simultaneous cone-sampler, two types of configuration instruments are compared with the long-term ambient air monitoring of inhalable particles (PM10) and fine particles (PM2.5), by using the BAM with step-by-step sampler as the reference method. According to EN 16450, this work evaluates the validity of the linear relationship of the data, establishes a modified linear equation, and derives the uncertainty evaluation formula between methods. The results demonstrate the effective linear relationship between the measuring results of BAM simultaneous cone-sampler and step-by-step sampler. After the concentration slope and concentration intercept are corrected by the built-in correction parameters, the slope, intercept and correlation coefficient (between reference method) of PM10 and PM2.5 meet the requirements of EPA-CFR-40-part53, even in case of relatively large concentration range (0~250μg/m3) and adequate data sets (n>100).
吴娟, 徐可欣, 迟颖, 周刚, 王玮. 两种不同构型b射线颗粒物分析仪线性关系的有效性评价[J]. 中国环境科学, 2022, 42(12): 5617-5625.
WU Juan, XU Ke-xin, CHI Ying, ZHOU Gang, WANG Wei. Evaluation of the linear relationship validity between two beta attenuation monitors with different configurations. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(12): 5617-5625.
GB 3095-2012环境空气质量标准[S]. GB 3095- 2012 Ministry of environmental protection. Ambient air quality standards[S].
[2]
Courtney W J, Shaw R W, Dzubay T G. Precision and accuracy of a β gauge for aerosol mass determinations[J]. Environmental Science and Technology, 1982,16:236-239.
[3]
Vincent J H. Aerosol sampling:science, standards, instrumentation and applications[M]. Chichester, England:John Wiley & Sons Ltd., 2007:114-116.
[4]
潘焕双,刘宏,张帅,等.多膜片校准方法在β射线法大气颗粒物监测仪中的应用[J]. 安徽科技, 2016,23(3):50-52. Pan H S, Liu H, Zhang S, et al. Application of multi-diaphragm calibration method in β-ray atmospheric particulate matter monitor[J]. Anhui Science & Technology, 2016,23(3):50-52.
[5]
HJ 653-2013环境空气颗粒物(PM10和PM2.5)连续自动监测系统技术要求及检测方法[S]. HJ 653-2013 Specifications and test procedures for ambient air quality continuous automated monitoring system for PM10 and PM2.5[S].
[6]
HJ 1100-2020环境空气中颗粒物(PM10和PM2.5)β射线法自动监测技术指南[S]. HJ 1100-2020 Technical guide for automatic monitoring by beta ray method for particulate matter in ambient air (PM10 and PM2.5)[S].
[7]
Met One Instruments, Inc. BAM 1020 particulate monitor operation manual:rev W[EB/OL].(2018-09)[2020-12].https://metone.com/wp-content/uploads/2019/05/BAM-1020-9800-Manual-Rev-W.pdf.
[8]
GRUBBS F. Procedures for Detecting Outlying Observations in Samples[J]. Technometrics, 1969,11:1-21.
[9]
GB/T 4883-2008数据的统计处理和解释正态样本离群值的判断和处理[S]. GB/T 4883-2008 Statistical interpretation of data-Detection and treatment of outliers in the normal sample[S].
[10]
HJ 655-2013环境空气颗粒物(PM10和PM2.5)连续自动监测系统安装和验收技术规范[S]. HJ 655-2013 Technical specifications for installation and acceptance of ambient air quality continuous automated monitoring system for PM10 and PM2.5[S].
[11]
EN 16450-2017 Ambient air-Automated measuring systems for the measurement of the concentration of particulate matter (PM10; PM2.5)[S].
[12]
US EPA. CFR 40 part 53 Ambient air monitoring reference and equivalent methods:Subpart C-Procedures for determining comparability between candidate methods and reference methods[S].