Long-term trends of HCHO columns in Shanxi Province based on satellite remote sensing
YANG Ai-qin1, YU Xiao-hong1, CHEN Ling1,2,3,4, YAN Shi-ming1,2, ZHU Ling-yun1,2, GUO Wei1,2, LI Ming-ming1,2, LI Yan-yu1,2,5, LI Ying1,2, HE Jie-ying1,2
1. Monitoring & Assessment Center For GHG & Carbon Neutrality, Shanxi Branch, Shanxi Institute of Meteorological Science, Taiyuan 030002, China; 2. Wutaishan Cloud Physics Field Experiment Base, China Meteorological Administration, Taiyuan 030002, China; 3. School of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China; 4. Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China; 5. Faculty of Geographical Science, Beijing Normal University, Beijing 100875, China
Abstract:The long-term trends of formaldehyde (HCHO) column in Shanxi Province from May to August over the period 2013~2022 were analyzed, using satellite measurements from Ozone Monitoring Instrument (OMI) and auxiliary data. The research examines the influence of biogenic volatile organic compounds (BVOCs) and anthropogenic volatile organic compounds (AVOCs) emissions on the observed variations in HCHO levels. Results indicate that the average HCHO column ranged from 4.1×1015 to 53.6×1015 molecules/cm2, with an annual mean of 14.3 × 1015 molecules/cm2. From 2013 to 2018, HCHO column exhibited an increasing trend, followed by a fluctuating decline from 2019 to 2022. Rural areas consistently showed higher HCHO concentrations compared to urban regions. After removing temperature effects, decreases in HCHO concentrations were observed mostly in urban areas with intense human activities, while increases were observed in rural villages with minimal anthropogenic influence. In temperature-sensitive regions, the rise in HCHO concentrations in northern Datong was attributed to increased BVOCs emissions from croplands. Similarly, in western Xinzhou to northern Lüliang, elevated HCHO concentrations were linked to higher BVOCs emissions from croplands, dense shrublands, mixed forests, and savannas. Conversely, central Jinzhong and southern Linfen to northern Yuncheng experienced reductions in HCHO concentrations due to simultaneous decreases in both AVOCs and BVOCs emissions, with reductions in AVOCs playing a particularly significant role.
杨爱琴, 于小红, 陈玲, 闫世明, 朱凌云, 郭伟, 李明明, 李雁宇, 李莹, 贺洁颖. 卫星遥感的山西HCHO柱浓度长期变化趋势[J]. 中国环境科学, 2024, 44(12): 6608-6616.
YANG Ai-qin, YU Xiao-hong, CHEN Ling, YAN Shi-ming, ZHU Ling-yun, GUO Wei, LI Ming-ming, LI Yan-yu, LI Ying, HE Jie-ying. Long-term trends of HCHO columns in Shanxi Province based on satellite remote sensing. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(12): 6608-6616.
[1] Sillman S, Logan J A, Wofsy S C. The sensitivity of ozone to nitrogen oxides and hydrocarbons in regional ozone episodes [J]. Journal of Geophysical Research: Atmospheres, 1990,95(D2):1837-1851. [2] Kleinman L I, Daum P H, Lee Y-N, et al. Sensitivity of ozone production rate to ozone precursors [J]. Geophysical Research Letters, 2001,28(15):2903-2906. [3] Liu Y T, Tang G Q, Wang Y H, et al. Spatiotemporal differences in tropospheric ozone sensitivity and the impact of “dual carbon” goal [J]. Science Bulletin, 2024,69(4):422-425. [4] Zhu L, Jacob D J, Keutsch F N, et al. Formaldehyde (HCHO) As a Hazardous Air Pollutant: Mapping Surface Air Concentrations from Satellite and Inferring Cancer Risks in the United States [J]. Environmental Science & Technology, 2017,51(10):5650-5657. [5] Zhu L, Jacob D J, Mickley L J, et al. Anthropogenic emissions of highly reactive volatile organic compounds in eastern Texas inferred from oversampling of satellite (OMI) measurements of HCHO columns [J]. Environmental Research Letters, 2014,9,doi:10.1088/ 1748-9326/9/11/114004. [6] Li D R, Wang S S, Xue R B, et al. OMI-observed HCHO in Shanghai, China, during 2010-2019and ozone sensitivity inferred by an improved HCHO/NO2 ratio [J]. Atmospheric Chemistry and Physics, 2021,21(20):15447-15460. [7] Sprengnether M, Demerjian K L, Donahue N M, et al. Product analysis of the OH oxidation of isoprene and 1,3-butadiene in the presence of NO [J]. Journal of Geophysical Research: Atmospheres, 2002,107,doi:10.1029/2001JD000716. [8] Palmer P I, Jacob D J, Fiore A M, et al. Mapping isoprene emissions over North America using formaldehyde column observations from space [J]. Journal of Geophysical Research: Atmospheres, 2003,108, doi:10.1029/2002JD002153. [9] Guenther A, Karl T, Harley P, et al. Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature) [J]. Atmospheric Chemistry and Physics, 2006, 6(11):3181-3210. [10] Fiore A M, Dentener F J, Wild O, et al. 2009:Multimodel estimates of intercontinental source-receptor relationships for ozone pollution [J]. Journal of Geophysical Research: Atmospheres, 2009,114,doi:10. 1029/2008JD010816. [11] Prather M J, Holmes C D, Hsu J. Reactive greenhouse gas scenarios: Systematic exploration of uncertainties and the role of atmospheric chemistry [J]. Geophysical Research Letters, 2012,39,doi:10.1029/ 2012GL051440. [12] Voulgarakis A, Naik V, Lamarque J-F, et al. Analysis of present day and future OH and methane lifetime in the ACCMIP simulations [J], Atmospheric Chemistry and Physics, 2013,13(5):2563-2587. [13] Wuebbles D J, Hayhoe K. Atmospheric methane and global change [J]. Earth-Science Reviews, 2002,57(3/4):177-210. [14] Lelieveld J, Gromov S, Pozzer A, et al. Global tropospheric hydroxyl distribution, budget and reactivity [J]. Atmospheric Chemistry and Physics, 2016,16(19):12477-12493. [15] Guenther A, Hewitt C N, Erickson D, et al. A global model of natural volatile organic compound emissions [J]. Journal of Geophysical Research: Atmospheres, 1995,100(D5):8873-8892. [16] Palmer P I, Abbot D S, Fu T-M, et al. Quantifying the seasonal and interannual variability of North American isoprene emissions using satellite observations of the formaldehyde column [J]. Journal of Geophysical Research: Atmospheres, 2006,111,doi:10.1029/2005JD006689. [17] 张玉洁,庞小兵,牟玉静.北京市植物排放的异戊二烯对大气中HCHO的贡献[J]. 环境科学, 2009,30(4):976-981. Zhang Y J, Pang X B, Mu Y J. Contribution of isoprene emitted from vegetable to atmospheric formaldehyde in the ambient air of Beijing city [J] Environmental Science, 2009,30(4):976-981. [18] Fu T-M, Jacob D J, Palmer P I, et al. Space-based formaldehyde measurements as constraints on volatile organic compound emissions in east and south Asia and implications for ozone [J]. Journal of Geophysical Research: Atmospheres, 2007,112(D6),D06312.https://doi.org/10.1029/2006JD007853. [19] Shen L, Jacob D J, Zhu L, et al. The 2005~2016 trends of formaldehyde columns over China observed by satellites: Increasing anthropogenic emissions of volatile organic compounds and decreasing agricultural fire emissions [J]. Geophysical Research Letters, 2019,46(8):4468-4475. [20] 明桂英,朱曼妮,沙青娥,等.2006~2020年广东省大气甲醛排放演变特征[J]. 环境科学, 2023,44(9):4819-4831. Ming G Y, Zhu M N, Sha Q E, et al. Evolution characteristics of atmospheric formaldehyde emissions in Guangdong Province from 2006 to 2020[J]. Environmental Science, 2023,44(9):4819-4831. [21] Fan J C, Ju T Z, Wang Q H, et al. Spatiotemporal variations and potential sources of tropospheric formaldehyde over eastern China based on OMI satellite data [J]. Atmospheric Pollution Research, 2021, 12(1):272-285. [22] Zhao T L, Mao J Q, Simpson W R, et al. Source and variability of formaldehyde (HCHO) at northern high latitudes: an integrated satellite, aircraft, and model study [J]. Atmospheric Chemistry and Physics, 2022,22(11):7163-7178. [23] Millet D B, Jacob D J, Turquety S, et al. Formaldehyde distribution over North America: Implications for satellite retrievals of formaldehyde columns and isoprene emission [J]. Journal of Geophysical Research: Atmospheres, 2006,111,doi:10.1029/2005JD006853. [24] Duncan B N, Yoshida Y, Damon M R, et al. Temperature dependence of factors controlling isoprene emissions [J]. Geophysical Research Letters, 2009,36,doi:10.1029/2008GL037090. [25] Marais E A, Jacob D J, Guenther A, et al. Improved model of isoprene emissions in Africa using Ozone Monitoring Instrument (OMI) satellite observations of formaldehyde: implications for oxidants and particulate matter [J]. Atmospheric Chemistry and Physics, 2014,14(15):7693-7703. [26] Bauwens M, Stavrakou T, Müller J-F, et al. Nine years of global hydrocarbon emissions based on source inversion of OMI formaldehyde observations [J]. Atmospheric Chemistry and Physics, 2016,16(15):10133-10158. [27] Zhu L, Mickley L J, Jacob D J, et al. Long-term (2005~2014) trends in formaldehyde (HCHO) columns across North America as seen by the OMI satellite instrument: Evidence of changing emissions of volatile organic compounds [J]. Geophysical Research Letters, 2017b,44(13): 7079-7086. [28] Oomen G-M, Müller J-F, Stavrakou T, et al. Weekly derived top-down volatile-organic-compound fluxes over Europe from TROPOMI HCHO data from 2018 to 2021[J]. Atmospheric Chemistry and Physics, 2024,24(1):449-474. [29] Guenther A, Baugh B, Brasseur G, et al. Isoprene emission estimates and uncertainties for the Central African EXPRESSO study domain [J]. Journal of Geophysical Research: Atmospheres, 1999,104(D23): 30625-30639. [30] Sun W F, Zhu L, De Smedt I, et al. Global significant changes in formaldehyde(HCHO) columns observed from space at the early stage of the COVID-19 pandemic [J]. Geophysical Research Letters, 2021, 48:e2020GL091265. [31] De Smedt I, Müller J-F, Stavrakou T, et al. Twelve years of global observations of formaldehyde in the troposphere using GOME and SCIAMACHY sensors [J]. Atmospheric Chemistry and Physics, 2008,8(16):4947-4963. [32] Zhu L, Jacob D J, Kim P S, et al. Observing atmospheric formaldehyde (HCHO) from space: validation and intercomparison of six retrievals from four satellites (OMI, GOME2A, GOME2B, OMPS) with SEAC4RS aircraft observations over the southeast US [J]. Atmospheric Chemistry and Physics, 2016,16(21):13477-13490. [33] Jin X M, Fiore A, Boersma K F, et al. Inferring changes in summertime surface Ozone-NOx-VOC chemistry over US. urban areas from two decades of satellite and ground-based observations [J]. Environmental Science & Technology, 2020,54(11):6518-6529. [34] Damien S-M, Mark A F. MODIS Collection 6.1(C61) Land Cover Type Product User Guide [EB/OL]. April 20, 2022. https://landweb.modaps.eosdis.nasa.gov/QA_WWW/forPage/user_guide/MCD12Q1_C61_UserGuide_05_03_22.pdf. [35] 韩恒霄,夏士勇,罗遥,等.深圳市大气甲醛四季污染特征及来源解析[J]. 中国环境科学, 2023,43(8):3867-3876. Han H X, Xia S Y, Luo Y, et al. Four seasons pollution characteristics and source analysis of atmospheric formaldehyde in Shenzhen [J]. China Environmental Science, 2023,43(8):3867-3876. [36] 蒲东川,王大康,朱雷,等.基于OLI和TROPOMI卫星数据的北京市臭氧前体物研究[J]. 中国环境科学, 2024,44(7):3592-3600. Pu D C, Wang D K, Zhu L, et al. Study on ozone precursors in Beijing based on OLI and TROPOMI satellite data [J]. China Environmental Science, 2024,44(7):3592-3600. [37] Kirschke S, Bousquet P, Ciais P, et al. Three decades of global methane sources and sinks [J]. Nature Geoscience, 2013,6(10):813-823. [38] Wiggins E B, Andrews A, Sweeney C, et al. Boreal forest fire CO and CH4 emission factors derived from tower observations in Alaska during the extreme fire season of 2015[J]. Atmospheric Chemistry and Physics, 2021,21(11):8557-8574. [39] Ding J, van der A R J, Mijling B, et al. Maritime NOx emissions over Chinese seas derived from satellite observations [J]. Geophysical Research Letters, 2018,45(4):2031-2037. [40] Silvern R F, Jacob D J, Mickley L J, et al. Using satellite observations of tropospheric NO2columns to infer long-term trends in US NOx emissions: the importance of accounting for the free tropospheric NO2 background [J]. Atmospheric Chemistry and Physics, 2019,19(13): 8863-8878. [41] Ding J, Miyazaki K, van der A R J, et al. Intercomparison of NOx emission inventories over East Asia [J]. Atmospheric Chemistry and Physics, 2017,17(16):10125-10141. [42] Li X, Cohen J B, Qin K, et al. Remotely sensed and surface measurement- derived mass-conserving inversion of daily NOx emissions and inferred combustion technologies in energy-rich northern China [J]. Atmospheric Chemistry and Physics, 2023,23(14): 8001-8019. [43] van der A R J, Mijling B, Ding J Y, et al. Cleaning up the air: effectiveness of air quality policy for SO2 and NOx emissions in China [J]. Atmospheric Chemistry and Physics, 2017,17(3):1775-1789. [44] Zhang Q, Zheng Y X, Tong D, et al. Drivers of improved PM2.5 air quality in China from 2013 to 2017[J]. Proceedings of the National Academy of Sciences, 2019,116(49):24463-24469. [45] Li L Y, Yang W Z, Xie S D, et al. Estimations and uncertainty of biogenic volatile organic compound emission inventory in China for 2008~2018[J]. Science of the Total Environment, 2020,733,doi.:10. 1016/j.scitotenv.2020.139301. [46] Gao M, Gao J, Zhu B, et al. Ozone pollution over China and India: seasonality and sources [J]. Atmospheric Chemistry and Physics, 2020,20(7):4399-4414. [47] Wang R Y, Wang L L, Sun J R, et al. Maximizing ozone control by spatial sensitivity-oriented mitigation strategy in the Pearl River Delta Region, China [J]. Science of The Total Environment, 2023,905,doi: 10.1016/j.scitotenv.2023.166987. [48] Li J, Li L Y, Wu R R, et al. Inventory of highly resolved temporal and spatial volatile organic compounds emission in China [C]. The 24th International Conference on Modelling, Monitoring and Management of Air Pollution, 2016,doi:10.2495/AIR160081. [49] 张蔷,李令军,赵文慧,等.北京森林BVOCs排放特征及对区域空气质量的影响[J]. 中国环境科学, 2021,41(2):622-632. Zhang Q, Li L J, Zhao W H, et al. Emission characteristics of VOCs from forests and its impact on regional air quality in Beijing [J]. China Environmental Science, 41(2):622-632.