The absorption of Cd(II) on NaOH modified fish bone meal function materials
LUO Wen-wen, XU Ying-ming, WANG Nong, SUN Yue-bing
Key Laboratory of Original Agro-Environmental Pollution Prevention and Control, Ministry of Agriculture and Rural Affairs, Tianjin Key Laboratory of Agro-Environment and Agro-Product Safety, Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, Tianjin 300191, China
Higher performance function of fish bone meal (FBMT) treated by NaOH was obtained, and then BET, XRD, FTIR, SEM-EDS, and TEM were used to investigate the structure characteristics of samples and the properties and mechanisms of Cd removal. The results showed that compared with FBM a certain number of medium-and macro-porous appeared in FBMT, and higher volume and average width of pore were got in FBMT, being 68.57% and 24.69%, respectively, higher than that of FBM. After treated with NaOH, the amount function groups such as -OH, C=O and PO43- in FBMT was increased. The adsorption of Cd (Ⅱ) on FBM and FBMT included an initial fast sorption phase and a second slow sorption phase, and the process of adsorption kinetics was well fitted by Pseudo-second-order, with correlation coefficients R2 0.8635 and 0.9480, respectively. The isothermal adsorption process could be well fitted with Langmuir isotherms, and the maximum adsorption capacity of Cd increased from 9.28mg/g on FBM to 22.47mg/g on FBMT, and the adsorption intensity (the values of KF) was correspondingly increased. The value of separation factor (0 < RL < 1) indicated that the adsorption process of Cd (Ⅱ) was favorable. The interaction mechanisms of function materials and Cd (Ⅱ) involved special cation adsorption, electrostatic adsorption, ion exchange, surface complexation and precipitation. Therefore, the research above supports an economic and effective method for the remediation of Cd contamination using fish bone meal.
罗文文, 徐应明, 王农, 孙约兵. NaOH改性鱼骨粉材料对Cd(II)的吸附[J]. 中国环境科学, 2019, 39(9): 3824-3831.
LUO Wen-wen, XU Ying-ming, WANG Nong, SUN Yue-bing. The absorption of Cd(II) on NaOH modified fish bone meal function materials. CHINA ENVIRONMENTAL SCIENCECE, 2019, 39(9): 3824-3831.
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