Principle and application of urea wastewater biological treatment technology
JIA Fang-xu, LIU Ying-jie, YU Xiao-hua, CAI Wei-wei, XING Wei, YAO Hong
Beijing Key Laboratory of Aqueous Typical Pollutants Control and Water Quality Safeguard, School of Civil Engineering, Beijing Jiaotong University, Beijing 100044, China
Abstract:The treatment of urea wastewater has become an urgent problem. Biological treatment is a popular method in dealing with urea wastewater due to the advantages of short process flow, low cost, anti-shock load and no secondary pollution etc. In this review, based on the principle of urea bio-hydrolysis, the development process, enzymatic structure and hydrolysis mechanism of urease were analyzed in depth from the mechanism, and the application of traditional biological urea denitrification method was systematically reviewed. In addition, in order to better understand the potential of anaerobic ammonia-oxidizing bacteria to degrade urea and its application in practical engineering, this paper summarized the relevant research results from the perspectives of microbiology and engineering application. Finally, the Suggestions and prospects of the research on biological treatment of urea wastewater are put forward in order to provide a strong theoretical basis and technical support for practical engineering application.
Cozzi S, Mistaro A, Sparnocchia S, et al. Anthropogenic loads and biogeochemical role of urea in the Gulf of Trieste[J]. Science of The Total Environment, 2014,493:271-281.
[2]
Jh Meessen H P. Urea. In:Ullmann's encyclopedia of industrial chemistry. Wiley-VCH, Weinheim[M]. Weinheim:Wiley-VCH, 2010.
[3]
Koebel M, Elsener M, Kleemann M. Urea-SCR:a promising technique to reduce NOx emissions from automotive diesel engines[J]. Catalysis Today, 2000,59(3/4):335-345.
[4]
薛明.含尿素和氨的化工废水处理技术探讨[J]. 化工管理, 2017,(18):182. Xue M. Discussion on treatment Technology of Chemical Wastewater containing Urea and ammonia[J]. Chemical Enterprise Management, 2017,(18):182.
[5]
李飘.ADC工业污水资源回收及处理技术研究[D]. 哈尔滨:哈尔滨工程大学, 2018. Li P. Research on Recovery and Treatment Technology of ADC Industrial Sewage Resources[D]. Harbin:Harbin Engineering University, 2018.
[6]
李明华,刘昭斌,李永效.利用深度水解技术处理强素工艺冷凝液[J]. 氮肥技术, 2006,(6):27-30. Li M H, Liu Z B, Li Y X. Treatment of urea process condensate by deep hydrolysis technology[J]. Nitrogenous Fertilizer Technology, 2006,(6):27-30.
[7]
Rahimpour M R, Azarpour A. Simulation of a urea thermal hydrolysis reactor[J]. Chemical Engineering Communications, 2005,192(1-3):155-167.
[8]
Boggs B, King R, Botte G. Urea electrolysis:direct hydrogen production from urine[J]. Chemical Communications, 2009,32:4859-4861.
[9]
Singla J, Sangal V K, Verma A. Evaluation and optimization of the process parameters for the photo-electrochemical treatment of urea using mixed metal oxide anodes[J]. Process Safety and Environmental Protection, 2019,130:197-208.
[10]
Shen S, Li M, Li B, et al. Catalytic hydrolysis of urea from wastewater using different aluminas by a fixed bed reactor[J]. Environmental Science and Pollution Research, 2014,21:12563-12568.
[11]
Xue C, Wilson L D. Kinetic study on urea uptake with chitosan based sorbent materials[J]. Carbohydrate Polymers, 2016,135:180-186.
[12]
Liu J, Chen X, Shao Z, et al. Preparation and Characterization of Chitosan/Cu(Ⅱ) Affinity Membrane for Urea Adsorption[J]. Journal of Applied Polymer, 2003,90(4):1108-1112.
[13]
刘长荣,张风丽,李志勇.固定化海洋脲酶制备及其在尿素废水处理中的应用[J]. 生物技术通报, 2019,35(9):75-82. Liu C R, Zhang F L, Li Z Y. Immobilization of Marine Urease and Its Utilization in the Treatment of Urea Wastewater[J] Biotechnology Bulletin, 2019,35(9):75-82.
[14]
Daneshfar A, Matsuura T, Emadzadeh D, et al. Urease-carrying electrospun polyacrylonitrile mat for urea hydrolysis[J]. Reactive and Functional Polymers, 2015,87:37-45.
[15]
王辉.吹脱-生化组合工艺处理尿素废水的技术研究[D]. 哈尔滨:哈尔滨工业大学, 2006. Wang H. Research on treatment of urea wastewater via combined process of air stripping and biotechnology technology[D]. Harbin:Harbin Institute of Technology, 2006.
[16]
Matijašević L, Dejanović I, Lisacb H. Treatment of wastewater generated by urea production[J]. Resources, Conservation and Recycling, 2010,54(3):149-154.
[17]
Krajewska B. Ureases I. Functional, catalytic and kinetic properties:A review[J]. Journal of Molecular Catalysis B:Enzymatic, 2009, 59(1-3):9-21.
[18]
Sumner J B. The isolation and crystallization of the enzyme urease. Preliminary paper[J]. Journal of Biological Chemistry, 1926,69(2):435-441.
[19]
Dixon N E, Gazzola T C, Blakeley R L, et al. Letter:Jack bean urease (EC 3.5.1.5). A metalloenzyme. A simple biological role for nickel?[J]. Journal of the American Chemical Society, 1975,97(14):4131-4133.
[20]
Follmer C, Barcellos G B, Zingali R B, et al. Canatoxin, a toxic protein from jack beans (Canavalia ensiformis), is a variant form of urease (EC 3.5.1.5):biological effects of urease independent of its ureolytic activity[J]. Biochemical Journal, 2001,360:217-224.
[21]
Kappaun K, Piovesan A R, Carlini C R, et al. Ureases:Historical aspects, catalytic, and non-catalytic properties-A review[J]. Journal of Advanced Research, 2018,13:3-17.
[22]
Jabri E, Carr M, Hausinger R, et al. The crystal structure of urease from Klebsiella aerogenes[J]. Science, 1995,268:998-1004.
[23]
Schäfer U, Kaltwasser H. Urease from Staphylococcus saprophyticus:purification, characterization and comparison to Staphylococcus xylosus urease[J]. Archives of microbiology, 1994,161:393-399.
[24]
L M, F M, S. C. Urease[G]. The Royal Chemical Society, 2017:60-97.
[25]
Schoep T D, Fulurija A, Good F, et al. Surface Properties of Helicobacter pylori Urease Complex Are Essential for Persistence[J]. PLoS One, 2010,5(11):e15042.
[26]
Mobley H L, Island M D, Hausinger R P. Molecular biology of microbial ureases.[J]. Microbiology and Molecular Biology Reviews, 1995,59(3):451-480.
[27]
Jones B, Mobley H. Proteus mirabilis urease:nucleotide sequence determination and comparison with jack bean urease.[J]. Journal of bacteriology, 1989,171(12):6414-6422.
[28]
Iwona K, Paulina Z, Marek K, et al. Bacterial Urease and its Role in Long-Lasting Human Diseases[J]. Current Protein and Peptide Science, 2012,13:789-806.
[29]
Benini S, Kosikowska P, Cianci M, et al. The crystal structure of Sporosarcina pasteurii urease in a complex with citrate provides new hints for inhibitor design[J]. journal of biological Inorganic chemistry, 2013,18(3):391-399.
[30]
Krajewska B. A combined temperature-pH study of urease kinetics. Assigning pKa values to ionizable groups of the active site involved in the catalytic reaction[J]. Journal of Molecular Catalysis B:Enzymatic, 2016,124:70-76.
[31]
Maroney M, Ciurli S. Nonredox nickel enzymes[J]. Chemical reviews, 2014,114(8):4206-4228.
[32]
Benini S, Rypniewski W R, Wilson K S, et al. A new proposal for urease mechanism based on the crystal structures of the native and inhibited enzyme from Bacillus pasteurii:why urea hydrolysis costs two nickels[J]. Structure, 1999,7(2):205-16.
[33]
Karplus P A, Pearson M A, Hausinger R P. 70years of crystalline urease:what have we learned?[J]. Accounts of Chemical Research, 1997,30(8):330-337.
[34]
Estiu G, Merz K M. Competitive hydrolytic and elimination mechanisms in the urease catalyzed decomposition of urea[J]. The Journal of Physical Chemistry B, 2007,111(34):10263-10274.
[35]
Kuypers M M M, Marchant H K, Kartal B. The microbial nitrogen-cycling network[J]. Nature Reviews Microbiology, 2018,16(5):263-276.
[36]
Burton S A Q, Prosser J I. Autotrophic Ammonia Oxidation at Low pH through Urea Hydrolysis[J]. Applied and Environmental Microbiology, 2001,67(7):2952-2957.
[37]
Koch H, Lücker S, Albertsen M, et al. Expanded metabolic versatility of ubiquitous nitrite-oxidizing bacteria from the genus Nitrospira[J]. Proceedings of the National Academy of Sciences-PNAS, 2015,112(36):11371-11376.
[38]
Hallam S J, Mincer T J, Schleper C, et al. Pathways of Carbon Assimilation and Ammonia Oxidation Suggested by Environmental Genomic Analyses of Marine Crenarchaeota[J]. PLoS Biology, 2006, 4(4):520-536.
[39]
Qin W, Amin S A, Martens-Habbena W, et al. Marine ammonia-oxidizing archaeal isolates display obligate mixotrophy and wide ecotypic variation[J]. Proceedings of the National Acadamy of Sciences of the United States of America, 2014,111(34):12504-12509.
[40]
Koops H, Pommerening-Roser A. Distribution and ecophysiology of the nitrifying bacteria emphasizing cultured species[J]. FEMS Microbiology Ecology, 2001,37:1-9.
[41]
Alonso-Saez L, Waller A S, Mende D R, et al. Role for urea in nitrification by polar marine Archaea[J]. Proceedings of the National Academy of Sciences, 2012,109(44):17989-17994.
[42]
Rittstieg K, Robra K H, Somitsch W. Aerobic treatment of a concentrated urea wastewater with simultaneous stripping of ammonia[J]. Applied Microbiology and Biotechnology, 2001,56(5/6):820-825.
[43]
闫立龙,张颖,李伟光,等. BACF处理高浓度尿素废水的效能研究[J]. 中国给水排水, 2010,26(9):108-111. Yan L L, Zhang Y, Li W G, et al. Treatment Efficiency of High-concentration Urea Wastewater by BACF[J]. China Water & Wastewater, 2010,26(9):108-111.
[44]
张东伟.曝气生物滤池(BAF)处理尿素解吸废水的试验研究[D]. 哈尔滨:哈尔滨工业大学, 2006. Zhang D W. Study on biological aerated filter (BAF) used for urea containing wastewater treatment[D]. Harbin:Harbin Institute of Technology, 2006.
[45]
付文博.SBR工艺处理高浓度尿素废水的试验研究[D]. 哈尔滨:哈尔滨工业大学, 2007. Fu W B. Experimental Research on High Concentration Urea Wastewater Treatment by SBR[D]. Harbin:Harbin Institute of Technology, 2007.
[46]
闫立龙,张颖,任源. SBR工艺处理高浓度尿素废水影响因素研究[J]. 工业水处理, 2009,29(3):25-28. Yan L L, Zhang Y, Ren Y. Influential factors of SBR process on the treatment of highly concentrated urea wastewater[J]. Industrial Water Treatment, 2009,29(3):25-28.
[47]
Garrido J M, Méndez R, Lema J M. Simultaneous urea hydrolysis, formaldehyde removal and denitrification in a multifed upflow filter under anoxic and anaerobic conditions[J]. 2001,35(3):691-698.
[48]
崔连起,莫光成,李雅琦,等.生物水解法处理尿素废水[J]. 化工环保, 1992,(6):325-329. Cui L Q, Mo G C, Li Y Q, et al. Treatment of Urea Wastewater by Biological Hydrolysis[J]. Environmental Protection of Chemical Industry, 1992,(6):325-329.
[49]
Pathe P P, K S A P. Urea Hydrolysis by Upflow Anaerobic Filter[J]. Journal of Environmental Health, 1987,29(2):128-138.
[50]
Eiroa M, Kennes C, Veiga M C. Formaldehyde and urea removal in a denitrifying granular sludge blanket reactor[J]. Water Research, 2004, 38(16):3495-3502.
[51]
Vidal G, Jiang Z P, Omil F, et al. Continuous anaerobic treatment of wastewaters containing formaldehyde and urea[J]. Bioresource Technology, 1999,70(3):283-291.
[52]
贾方旭,彭永臻,王衫允,等.厌氧氨氧化菌细胞的超微结构及功能[J]. 应用与环境生物学报, 2014,20(5):944-954. Jia F X, Peng Y Z, Wang S Y, et al. Ultrastructure and function of anaerobic ammonium oxidation bacteria cells[J]. Chinese Journal of Applied and Environmental Biology, 2014,20(5):944-954.
[53]
贾方旭,彭永臻,杨庆.厌氧氨氧化菌与其他细菌之间的协同竞争关系[J]. 环境科学学报, 2014,34(6):1351-1361. Jia F X, Peng Y Z, Yang Q. Competition and synergism between anammox bacteria and other bacteria[J]. Acta Scientiae Circumstantiae, 2014,34(6):1351-1361.
[54]
Kuenen J G. Anammox bacteria:from discovery to application[J]. Nat Rev Microbiol, 2008,6(4):320-326.
[55]
Kalvelage T, Lavik G, Lam P, et al. Nitrogen cycling driven by organic matter export in the South Pacific oxygen minimum zone[J]. Nature Geoscience, 2013,6:228-234.
[56]
Babbin A R, Peters B D, Mordy C W, et al. Multiple metabolisms constrain the anaerobic nitrite budget in the Eastern Tropical South Pacific[J]. Global Biogeochemical Cycles, 2017.
[57]
Widner B, Fuchsman C A, Chang B X, et al. Utilization of urea and cyanate in waters overlying and within the eastern tropical north Pacific oxygen deficient zone[J]. FEMS Microbiology Ecology, 2018, 94(10).
[58]
Ganesh S, Bertagnolli A D, Bristow L A, et al. Single cell genomic and transcriptomic evidence for the use of alternative nitrogen substrates by anammox bacteria[J]. The ISME Journal, 2018,12(11):2706-2722.
[59]
van de Vossenberg, Woebken D, Maalcke W J, et al. The metagenome of the marine anammox bacterium ‘Candidatus Scalindua profunda’ illustrates the versatility of this globally important nitrogen cycle bacterium[J]. Environmental Microbiology, 2012,15(5):1275-1289.
[60]
Ganesh S, Bristow L A, Larsen M, et al. Size-fraction partitioning of community gene transcription and nitrogen metabolism in a marine oxygen minimum zone[J]. ISME Journal, 2015,9:2682-2696.
[61]
Sliekers A O, Haaijer S, Schmid M, et al. Nitrification and Anammox with Urea as the Energy Source[J]. Systematic and Applied Microbiology, 2004,27(3):271-278.
[62]
Liu S, Gong Z, Yang F, et al. Combined process of urea nitrogen removal in anaerobic Anammox co-culture reactor[J]. Bioresource Technology, 2008,99(6):1722-1728.
[63]
刘思彤.电/磁场强化厌氧氨氧化及多菌群协同自养生物脱氮[D]. 大连:大连理工大学, 2009. Liu S T. The enhancement by electrical/magnetic field and Multi-species coupling of Anammox technology for autotrophic nitrogen removal[D]. Dalian:Dalian University of Technology, 2009.
[64]
卢健聪.基于能源回收的中低温城市污水厌氧氨氧化生物脱氮新工艺[D]. 哈尔滨:东北林业大学, 2013. Lu J C. A novel municipal wastewater treating process base on Anammox for energy production and autotrophic nitrogen[D]. Harbin:Northeast Forestry University, 2013.
[65]
李玖龄.基于信号分子AHLs检测的微氧废水处理系统脱氮机制研究[D]. 哈尔滨:哈尔滨工业大学, 2016. Li J L. The mechanism of nitrogen removal in a microaerobic wastewater treatment system based on the detection of signal molecule AHLs[D]. Harbin:Harbin Institute of Technology, 2016.