Polycyclic aromatic hydrocarbons about the atmosphere in scrap vehicle dismantling base
RAN Xue-ling1, LI Lin2, QIN Yu-fei3,4, LIANG Yun-yan3, XIE Hai-hua3, HE Zi-zhen1, WANG Jian-bo1, LU Yan1, ZHAN Lu4, XU Zhen-ming4
1. College of Environment and Resources, Southwest University of Science and Technology, Mianyang 621000, China; 2. Liaoning Ziyu Environmental Engineering Co., LTD., Yingkou 115000, China; 3. Jiangxi Green Recycling Co, Ltd, Yichun 331100, China; 4. School of Environmental Science and Engineering, Shanghai Jiaotong University, Shanghai 201100, China
Abstract:On the basis of the data analyzed from the samples collected in the study, the concentration distribution characteristics and component characteristics of PAHs in each region of the scrap vehicle dismantling base were analyzed. The main sources of the pollutants in the scrap vehicle dismantling base were investigated using positive definite factor matrix model (PMF). The BaP toxic equivalent method (BaPeq), incremental lifetime carcinogenic risk (ILCR) model and comprehensive scoring method were employed to evaluate the impact of PAHs on human health and to identify priority controlling pollutants of PAHs. The results showed that concentration of PM2.5, PM10, and gas phase was respectively 0.638μg/m3, 0.634μg/m3 and 1.6131μg/m3; illustrating that the concentration of PAHs in gas phase was much higher than that in particulate matter. The order of the concentration of PAHs in both gas phase and particular matter according to ring number was 2~3rings> 4rings> 5~6rings; the main sources of the pollutants were identified as synthetic fiber emission and petroleum volatileization; The carcinogenic risk may exist in the scrap carstorage area, other areas in the factory, mechanical crushing area, car dismantling area, vehicle dismantling area and manual sorting area; The priority controlling pollutants were identified and their controling order shallbe Nap> Chr> Flu> Fla> BaA> BbF> BaP> BkF> IcdP> BghiP.
[1] 何 涛,彭 燕,李 璐,等.长三角一次局地污染过程分析[J]. 环保科技, 2017,23(2):42−46. He T, Peng Y, Li L, et al. Analysis of a local air pollution event in Yangtze River Delta[J]. Environmental protection and technology, 2017,23(2):42−46. [2] Epa O U. EPA History:Clean air act amendments of 1990[Z]. [3] 谭吉华,毕新慧,段菁春,等.广州市大气可吸入颗粒物(PM10)中PAHs的季节变化[J]. 环境科学学报, 2005,25(7):855−862. Tan J H, Bi X H, Duan J C, et al. Seasonal variation of polycyclic aromatic hydrocarbons (PAHs) in atmospheric particulate matter (PM10) in Guangzhou[J]. Chinese Journal of Environmental Science, 2005,25(7):855−862. [4] Wu X, Nethery R C, Sabath B M, et al. Exposure to air pollution and COVID-19mortality in the United States[J]. MedRxiv, 2020, doi:10.1101/2020.04.05.20054502. [5] 蒋 波,周自强.国内外报废汽车拆解回收技术和行业现状[J]. 常州工学院学报, 2019,32(3):14−20. Jiang B, Zhou Z Q. Domestic and foreign scrap automobile dismantling and recycling technology and industry status quo[J]. Journal of Changzhou Institute of Technology, 2019,32(3):14−20. [6] 陈元华,杨沿平,胡纾寒,等.我国报废汽车回收利用现状分析与对策建议[J]. 中国工程科学, 2018,20(1):113−119. Chen Y H, Yang Y P, Hu S H, et al. Analysis of the status quo of end-of-life vehicle recycling in China and countermeasures[J]. China Engineering Science, 2018,20(1):113−119. [7] 倪飞箭.报废汽车破碎残余物热裂解/气化回收机理与资源化初探[D]. 上海:上海交通大学, 2015. Ni F J. Preliminary study on the mechanism and resource utilization of thermal cracking/gasification recovery of scrap car crushing residues[D]. Shanghai:Shanghai Jiaotong University, 2015. [8] 中华人民共和国商务部流通业发展司.中国再生资源回收行业发展报告(2018)[EB/OL]. (2018−06−20)[2018−11−01]. Department of Circulation Industry Development of the Ministry of Commerce of the People's Republic of China. Report on the development of China's renewable resources recycling industry (2018)[EB/OL]. (2018−06−20)[2018−11−01]. [9] 王 雷,解 鹏,王传磊.报废汽车拆解现状及工艺探讨[J]. 资源再生, 2016,(4):48−51. Wang L, Xie P, Wang C L. Discussion on the status quo and process of scrapped vehicle disassembly[J]. Resource Regeneration, 2016, (4):48−51. [10] 常 焜.报废汽车回收研究综述及政策梳理[J]. 中国物流与采购, 2022,(14):59−60. Chang K. Research review and policy sorting of end-of-life vehicle recycling[J]. China Logistics and Procurement, 2022,(14):59−60. [11] 刘劲松,朱国华,尹文华,等.某电子垃圾拆解园周边农田土壤中PAHs的污染特征及风险评估[J]. 环境污染与防治, 2015,37(5):1−5. Liu J S, Zhu G H, Yin W H, et al Pollution characteristics and risk assessment of polycyclic aromatic hydrocarbons in farmland soil around an electronic waste disposal park[J] Environmental Pollution and Prevention, 2015,37(5):1−5. [12] 刘明洋,李会茹,宋爱民,等.环境和人体中氯代/溴代PAHs的研究进展—污染来源,分析方法和污染特征[J]. 中国环境科学, 2021,41(4):1842−1855. Liu M Y, Li H R, Song A M, et al Research progress of chlorinated/brominated polycyclic aromatic hydrocarbons in environment and human body − pollution sources, analysis methods and pollution characteristics[J]. China Environmental Science, 2021,41(4):1842− 1855. [13] 黄业茹,狄一安,施钧慧,等.北京、东京、筑波大气中有机污染组成研究[J]. 环境科学研究, 2001,14(1):4-8. Huang Y R, Di Y A, Shi J H, et al. Composition of atmospheric organic pollution in Beijing, Tokyo and Tsukuba[J]. Research of Environmental Sciences, 2001,14(1):4−8. [14] 姚 敏,吴俊锋,冷湘梓,等.电子废物拆解企业污染物排放的污染特征及风险评估[J]. 环境工程, 2018,36(11):127−132. Yao M, Wu J F, Leng X Z, et al. Pollution characteristics and risk assessment of pollutants discharge from electronic waste disassembly enterprises[J]. Environmental Engineering, 2018,36(11):127–132. [15] 余 辉,吴军莲,蔡 璐.废家电处理中持久性有机污染物的减控管理综述[J]. 环境工程, 2017,35(3):123−126. Yu H, Wu J l, Cai L. Overview on the reduction and control management of persistent organic pollutants in waste household appliances treatment[J] Environmental Engineering, 2017,35(3):123– 126. [16] 李 菲,王 海.电子废弃物再生利用经济影响分析[J]. 中国外资, 2013,(21):180. Li F, Wang H. Analysis on the economic impact of electronic waste recycling[J]. Foreign Investment in China, 2013,(21):180. [17] Schmid Erik, Zur Lage L. Perspektiven für das recycling von altfahrzeugen[J]. Recycling und Rohstoffe, 2014,7:105−126. [18] European Commission. Eed of life vehicles(ELVs)[EB/OL].[2018−11−01]. https://ec.europa.eu/Eurostat/web/waste/key/waste-streams/elvs. [19] Sooa V K, Peeters J, Compston P, et al.Com-parative study of end-of-life vehicle recycling in Australia and Belgium[J]. Procedia CIRP, 2017,61:269−274. [20] Alsaadi N, Franchetti M. An integrated life cycle assessment and optimization approach for automotive de-manufacturing systems[D]. ohio:University of Toledo, 2017. [21] Brown S G, Frankel A, Hafner H R. Source apportionment of VOCs in the Los Angeles area using positive matrix factorization[J]. Atmospheric Environment, 2007,41:227−237. [22] Polissar A V, Hopke P K, Paatero P, et al. Atmospheric aerosol over Alaska. Elemental composition and sources[J]. Journal of Geophysical Research, 1998,103:19045−19057. [23] Keeler G J, Landis M S, Norris G, et al. Source of mercury wet deposition in Eastern Ohio, USA[J]. Environmental Science and Technology, 2006,40:5874−5881. [24] Vaccaro S, Sobiecha E, Contini S, et al. The application of positive matrix factorization in the analysis, characterisation and detection of contaminated soils[J]. Chemosphere, 2007,69:1055−1063. [25] Reinikainen S P, Laine P, Minkkinen P, et al. Factor analytical study on water quality in Lake Saimaa, Finland[J]. Fresenius Journal of Analytical Chemistry, 2001,369:727−732. [26] Larsen R K, Baker J E. Source apportionment of polycyclic aromatic hydrocarbons in the urban atmosphere:A comparison of three methods[J]. Environmental Science and Technology, 2003,37:1873−1881. [27] Paatero P. The multilinear engine -a table-driven, least squares program for solving multilinear problems, including the n-way parallel factor analysis model[J]. Journal of Computational and Graphical Statistics 1999,1:854−888. [28] Terry C, Rasoulpour R J, Knowles S, et al. Utilizing relative potency factors (RPF) and threshold of toxicological concern (TTC) concepts to assess hazard and human risk assessment profiles of environmental metabolites:a case study[J]. Regulatory Toxicology & Pharmacology Rtp, 2015,71(2):301−317. [29] GB 3095-2012 环境空气质量标准[S]. GB 3095-2012 Environmental air quality standard[S]. [30] HJ/T 55-2000 大气污染物无组织排放监测技术导则[S]. HJ/T 55-2000 Technical guidelines for monitoring air pollutant discharge without organization[S]. [31] HJ/T 93-2003 PM10采样器技术要求及检测方法[S]. HJ/T 93-2003 Technical requirement and test method of PM10 sampler[S]. [32] HJ 646-2013 环境空气和废气 气相和颗粒物中多环芳烃的测定 气相色谱-质谱法[S]. HJ 646-2013 Determination of polycyclic aromatic hydrocarbons in ambient air and exhaust gas phase and particulate matter by Gas chromatography-mass spectrometry[S]. [33] 齐静文,张瑞芹,姜 楠,等.洛阳市秋冬季PM2.5中多环芳烃的污染特征,来源解析及健康风险评价[J]. 环境科学, 2020,42(2):595-603. Qi J G, Zhang R Q, Jiang N, et al. Pollution characteristics, source analysis and health risk assessment of polycyclic aromatic hydrocarbons in PM2.5 in autumn and winter in Luoyang City[J]. Environmental Science, 2020,42(2):595-603. [34] 环境保护部.国家污染物环境健康风险名录.化学第一分册[M]. 北京:中国环境科学出版社, 2009. Ministry of Environmental Protection. National list of environmental health risks of pollutants. chemistry volume I[M]. Beijing:China Environmental Science Press, 2009.