脱碱赤泥对餐厨垃圾催化热解产物分布的影响

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摘要本文采用固定床反应器、气相色谱-质谱联用仪(GC-MS)、荧光分光光度计(UV-F)和原位红外(In-situ DRIFTS)等方法探究了不同热解温度下脱碱赤泥对餐厨垃圾热解产物分布的影响.结果表明,相同热解温度下,脱碱赤泥能够抑制热解气的生成,促进热解油的生成且在450℃时产率最高为39.46%.热解油主要以脂肪酸、N化合物和酯类为主.由于脱碱赤泥不仅能促进甘油三酯的分解产生长链羧酸,还能促进了蛋白质裂解产生芳香蛋白类物质,使得热解油中的酸类含量增加和芳构化程度加深.同时热解焦中的羧酸官能团和C≡N吸收峰显著升高进一步验证了脱碱赤泥能够促进热解油中酸类和N化合物的生成.

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	刘亮
	曾宏亮
	卿梦霞
	贺梓航
	吴佳俊
	康向京
	向军
	刘一帆

关键词 ：脱碱赤泥, 餐厨垃圾, 催化热解, 热解油产物分布

Abstract：In this paper, the effects of de-alkalized red mud on the distribution of food waste pyrolysis products at different pyrolysis temperatures were investigated using a fixed bed reactor, Gas Chromatography-Mass Spectrometry (GC-MS), Fluorescence Spectrophotometry (UV-F), and In-Situ Infrared (In-situ DRIFTS). The results showed that under the same pyrolysis temperature, the formation of pyrolysis gas was inhibited and the production of pyrolysis oil was promoted, with the highest yield of 39.46% at 450℃, by de-alkalized red mud. The pyrolysis oil was mainly dominated by fatty acids, N compounds, and esters. Not only was the decomposition of triglycerides promoted to produce long-chain carboxylic acids but also the cleavage of proteins was promoted to produce aromatic proteins by de-alkalized red mud, which led to the increase of acid content and deepening of the degree of aromatization in the pyrolysis oil. Meanwhile, the significant growth of carboxylic acid functional groups and C≡N absorption peaks in pyrolysis coke further confirmed that the de-alkalized red mud could promote the production of acids and N compounds in pyrolysis oil.

Key words： de-alkalized red mud kitchen waste catalytic pyrolysis pyrolysis oil product distribution

收稿日期: 2024-03-09

PACS:

X705

基金资助:国家自然科学基金资助项目(52106131);湖南省研究生创新项目(CX20220929);湖南省教育厅重点项目(21A0201)

通讯作者: 卿梦霞,副教授,qingmx@csust.edu.cn E-mail: qingmx@csust.edu.cn

作者简介: 刘亮(1967-),男,湖南岳阳人,教授,博士,主要从事煤与生物质清洁高效利用.发表论文100余篇.liuliang_hn@163.com.

引用本文:

刘亮, 曾宏亮, 卿梦霞, 贺梓航, 吴佳俊, 康向京, 向军, 刘一帆. 脱碱赤泥对餐厨垃圾催化热解产物分布的影响[J]. 中国环境科学, 2024, 44(10): 5678-5686. LIU Liang, ZENG Hong-liang, QING Meng-xia, HE Zi-hang, WU Jia-jun, KANG Xiang-jing, XIANG Jun, LIU Yi-fan. Effect of de-alkalized red mud on the distribution of catalytic pyrolysis products from food waste. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(10): 5678-5686.

链接本文:

http://www.zghjkx.com.cn/CN/ 或 http://www.zghjkx.com.cn/CN/Y2024/V44/I10/5678

[1] 张莹,谷萌,孙捷,等.餐厨垃圾水热炭化产物分配规律及液固产物特性研究[J]. 中国环境科学, 2022,42(1):239-249. Zhang Y, Gu M, Sun J, et al. Study on the distribution law of hydrothermal carbonization products and the characteristics of liquid- solid products of kitchen waste [J]. China Environmental Science, 2022,42(1):239-249.
[2] 尚泽洲,胜晨静,汪锐,等.不同麦秆生物炭强化餐厨垃圾厌氧消化[J]. 中国环境科学, 2023,43(5):2381-2392. Shang Z Z, Sheng C J, Wang R, et al. Enhanced anaerobic digestion of kitchen waste with different straw biochar [J]. China Environmental Science, 2023,43(5):2381-2392.
[3] 张陶陶,张健,邰俊,等.餐厨垃圾厌氧沼渣在不同温度下的热解特性[J]. 燃烧科学与技术, 2023,29(3):347-354. Zhang T T, Zhang J, Tai J, et al. Pyrolysis characteristics of kitchen waste anaerobic digestate at different temperatures [J]. Combustion Science and Technology, 2023,29(3):347-354.
[4] Ly H V, Tran Q K, Kim S S, et al. Catalytic upgrade for pyrolysis of food waste in a bubbling fluidized-bed reactor [J]. Environ. Pollut., 2021,275:116023.
[5] Okopi S I, Wang J, Kong W, et al. Valorization of food waste impurities by catalytic co-pyrolysis for production of pyrolysis oil with high energy potential [J]. J Anal. Appl. Pyrolysis., 2023,170.
[6] Qiu B, Tao X, Wang J, et al. Research progress in the preparation of high-quality liquid fuels and chemicals by catalytic pyrolysis of biomass: A review [J]. Energy Conversion and Management, 2022,261: 115647.
[7] 方宏萍,梁文俊,任思达,等.改性赤泥催化剂制备及其催化燃烧甲苯性能[J]. 中国环境科学, 2021,41(12):5764-5770. Fang H P, Liang W J, Ren S D, et al. Preparation of modified red mud catalyst and its performance in catalytic combustion of toluene [J]. China Environmental Science, 2021,41(12):5764-5770.
[8] Wang Y, Li Y, Wang G, et al. Effect of Fe components in red mud on catalytic pyrolysis of low-rank coal [J]. Journal of the Energy Institute, 2022,100:1-9.
[9] 宋健,杨家宽,梁莎,等. Fenton试剂与赤泥调理污泥泥饼热解产气效果研究[J]. 环境科学与技术, 2016,39(8):40-45. Song J, Yang J K, Liang S, et al. Study on the effect of gas production by pyrolysis of Fenton's reagent and red mud-conditioned sludge sludge cake [J]. Environmental Science and Technology, 2016,39(8): 40-45.
[10] Qiu B, Yang C, Shao Q, et al. Recent advances on industrial solid waste catalysts for improving the quality of bio-oil from biomass catalytic cracking: A review [J]. Fuel, 2022,315:123218.
[11] Zhang Y, Wang Y, Cui H, et al. Co-pyrolysis of biomass with Red Mud: An efficient approach to improving bio-oil quality and resourceful utilization of the iron in Red Mud [J]. Fuel, 2024,355: 129482.
[12] Gu H, Li W, Li Z, et al. Leaching Behavior of Lithium from Bauxite Residue Using Acetic Acid [J]. Mining, Metallurgy & Exploration, 2020,37(2):443-451.
[13] 朱晓波,王涛,李望.醋酸浸出赤泥及P507萃取浸出液回收钇的实验研究[J]. 工程科学与技术, 2021,53(4):240-246. Zhu X B, Wang T, Li W. Experimental study on the recovery of yttrium from acetic acid leached red mud and P507 extracted leach solution [J]. Engineering Science and Technology, 2021,53(4):240- 246.
[14] Li H, Xu J, Mbugua N S, et al. Food waste pyrolysis by traditional heating and microwave heating: A review [J]. Fuel, 2022,324:24574.
[15] Kumar M, Srivastava N, Upadhyay S N, et al. Thermal degradation of dry kitchen waste: kinetics and pyrolysis products [J]. Biomass Conversion and Biorefinery, 2021,13(4):2779-2796.
[16] Che D, Wang L, Liu H, et al. Effects of lipids on sludge and chlorella protein pyrolysis by thermogravimetry Fourier transform infrared spectrometry [J]. Journal of Environmental Chemical Engineering, 2022,10(1):107011.
[17] Wei L, Liu M, Liang F, et al. Effects of CaO on nitrogen transformation during pyrolysis of soybean protein [J]. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 2018,40(22): 2641-2647.
[18] Shi Y, Gao C, Xing E, et al. Ni nanoparticles encapsulated within H-type ZSM-5crystals for upgrading palmitic acid to diesel-like fuels [J]. Chinese Chemical Letters, 2022,33(2):803-816.
[19] 苏怡霖,袁金虎,杨忠臣,等.一类联苯酯二聚体分子的合成及液晶性能[J]. 西安工业大学学报, 2023,43(5):478-483. Su Y L, Yuan J H, Yang Z C, et al. Synthesis and liquid crystal properties of a class of biphenyl ester dimer molecules [J]. Journal of Xi'an University of Technology, 2023,43(5):478-483.
[20] Zhou H, Tang X, Wang Z, et al. Process performance and kinetics of the esterification of diketene to methyl acetoacetate in helical continuous-flow microreactors [J]. Chemical Engineering Science, 2022,262:117970.
[21] 刘亮,龙雨田,卿梦霞,等.餐厨垃圾典型组分的热解产物分布特性[J]. 可再生能源, 2023,41(1):16-22. Liu L, Long Y T, Qing M X, et al. Characterization of pyrolysis product distribution of typical components of kitchen waste [J]. Renewable Energy, 2023,41(1):16-22.
[22] 余桢婷.微波场中多孔泡沫陶瓷催化热解油脂制备富烃燃油研究[D]. 南昌:南昌大学, 2021. Yu Z T. Catalytic pyrolysis of fats and oils to prepare hydrocarbon rich fuels by porous foam ceramics in microwave field [D]. Nanchang: Nanchang University, 2021.
[23] Guo S, Liu L, Guo X, et al. Unveiling the mechanism of NO precursor formation during sewage sludge pyrolysis: Effects of-carbohydrate- protein interactions [J]. Journal of Environmental Chemical Engineering, 2022,10(3):107579.
[24] Zhou N, Hua M, Yu A, et al. Effects of incompatible substances on the thermal stability of dimethyl 2,2'-azobis(2-methylpropionate) (AIBME) in the application process [J]. Journal of Loss Prevention in the Process Industries, 2021,71:104478.
[25] 周晓涵.赤泥催化玉米秸秆热解气化反应特性及机理研究[D]. 济南:山东大学, 2023. Zhou X H. Characteristics and mechanism of red mud-catalyzed pyrolysis gasification of corn 01stover [D]. Jinan: Shandong University, 2023.
[26] 董文燕.赤泥载镍催化剂催化竹屑气化的研究[D]. 贵州:贵州大学, 2023. Dong W Y. Study on the catalytic gasification of bamboo chips by red mud-loaded nickel catalyst [D]. Guizhou: Guizhou University, 2023.
[27] 张曌.污泥催化热解工艺过程效能与机理研究[D]. 哈尔滨:哈尔滨工业大学, 2022. Zhang J Research on process efficiency and mechanism of sludge catalytic pyrolysis process [D]. Harbin: Harbin Institute of Technology, 2022.
[28] Sani M J. Theoretical survey on the electronic, linear, and nonlinear optical properties of substituted benzenes and polycondensed π-systems. A density functional theory study [J]. Computational and Theoretical Chemistry, 2023,1223:114100.
[29] 薛梓涛,储雪飞,邢丽波,等.蚯蚓堆肥处理校园有机垃圾的热解特性及物质转化特征[J]. 环境工程, 2023,41(6):82-91. Xue Z T, Zu X F, Xing L B, et al. Characteristics of pyrolysis and material transformation of organic wastes from a campus treated with vermicomposting [J]. Environmental Engineering, 2023,41(6):82-91.
[30] 杨金强,赵南京,殷高方,等.城市生活污水处理过程三维荧光光谱在线监测分析方法[J]. 光谱学与光谱分析, 2020,40(7):1993-1997. Yang J Q, Zhao N J, Yin G F, et al. On-line monitoring and analyzing method of three-dimensional fluorescence spectroscopy for urban domestic wastewater treatment process [J]. Spectroscopy and Spectral Analysis, 2020,40(7):1993-1997.
[31] 唐琳钦,宿程远,赵力剑,等.不同基质生物炭对厌氧处理餐厨垃圾效能及微生态的影响[J]. 中国环境科学, 2020,40(11):4831-4840. Tang L Q, Su C Y, Zhao L J, et al. Effects of different substrate biochar on the efficacy and microecology of anaerobic treatment of kitchen waste [J]. China Environmental Science, 2020,40(11):4831-4840.
[32] Guo S, Liu T, Che D, et al. Effects of carbohydrates on NOx precursor formation from proteins during sewage sludge pyrolysis [J]. Environmental Technology & Innovation, 2021,23:101594.
[33] Yao B, Li X, Zhou C, et al. Co-pyrolysis of dyeing sludge and pine sawdust in a fluidized bed: Characterization and analysis of pyrolytic products and investigation of synergetic effects [J]. Waste Management, 2023,167:122-134.
[34] 张海峰,陈璐,刘先宇,等.基于赤泥载氧体的蓝藻化学链热解和气化特性研究[J]. 燃料化学学报, 2021,49(12):1802-1811. Zhang H F, Chen L, Liu X Y, et al. Characterization of pyrolysis and gasification of cyanobacterial chemical chains based on red mud oxygen carriers [J]. Journal of Fuel Chemistry, 2021,49(12):1802- 1811.
[35] 刘亮,郑扬,黄思彪,等.生物质热解过程中氮迁移转化机理研究进展[J]. 农业工程学报, 2022,38(19):227-236. Liu L, Zheng Y, Huang S B, et al. Progress of nitrogen transport and transformation mechanism in biomass pyrolysis [J]. Journal of Agricultural Engineering, 2022,38(19):227-236.