Synthesis of polyallyl sodium sulfonate grafted hollow glass microbeads and its adsorption properties research
ZHENG Huai-li1, LIU Wang-qing1, AN Yan-yan1, CHEN Wei2, SUN Qiang1, WAN Xin-yuan1, ZHAO Rui1
1. Faculty of Environment and Ecology, Chongqing University, Chongqing 400044, China; 2. Faculty of Civil Engineering, Sichuan Agricultural University Chengdu 611830, China
Abstract：A noval hollow glass bead-based adsorbent (KNH-g-PSAS) was successfully fabricated by grafting sodium allyl sulfonate (SAS) and silane coupling agent onto the surface of hollow glass beads. KNH-g-PSAS was characterized by scanning electron microscope, energy dispersion spectroscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis and X-ray diffractometer, showing the successful grafting of SAS. In addition, the effects of pH value, reaction time, initial concentration and temperature on the adsorption of cationic dyes by KNH-g-PSAS were systematically studied. The pseudo-order kinetic model and Langmuir isotherm model fitted the kinetics and isotherm data well, indicating that the adsorption were determined by chemsorption and uniform monolayer adsorption. Adsorption experiment showed that the adsorption capacity of KNH-g-PSAS for basic fuchsin, auramine O, crystal violet and malachite green were 2247.19mg/g, 23174.61mg/g, 2557.54mg/g and 2808.98mg/g, respectively. In addition, KNH-g-PSAS had excellent self-floating performance and recovery performance.
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