标准件行业VOCs排放特征及环境影响分析

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摘要为研究标准件行业VOCs排放特征及其环境影响，选取了典型标准件企业进行现场调研与采样，运用GC-MS/FID测定了废气中102种VOCs物种，建立了标准件行业VOCs源成分谱，并估算了行业VOCs的环境污染影响、排放因子及排放量.结果表明，标准件行业各工序VOCs均以烷烃（29.58%~68.94%）为主要排放组分.正十二烷、乙烷、丙烷等烷烃，邻-二甲苯、对二甲苯等芳香烃，乙酸丁酯、乙醛等含氧VOCs为该行业高排放物种.芳香烃是该行业臭氧生成潜势的主要贡献组分，烷烃是该行业二次有机气溶胶生成潜势的主要贡献组分.标准件行业VOCs排放因子为1.51kg/t，2018~2020年全国标准件行业VOCs排放量分别为11496.84，13301.89，14365.69t，年均增长率为11.85%，其排放以华北和华东地区为主，两地区排放量累计占比范围为84.55%~89.08%.

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	郑海胜
	王晓琦
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	沈泽亚
	程水源

关键词 ：标准件行业, 挥发性有机物, 排放特征, 环境影响, 排放因子, 排放量

Abstract：In order to study the VOCs emissions characteristics of fastener industry and its impact on air quality, typical industries were selected and a sampling project was conducted. 102 species of VOCs were analyzed utilizing GC-MS/FID. The VOC spectrums of fastener industries were established. The emission inventory, emission factors and its impact on air quality were estimated.Results indicated that the alkane was the dominant component of VOCs in all processes of fastener industries with proportions ranging from 29.58% to 68.94%. Alkanes including n-dodecane, ethane and propane, aromatic hydrocarbons including o-xylene and p-xylene, and oxygenated hydrocarbons including butyl acetate and acetaldehyde were the components with high emission load. Aromatics were the major contributors to the potential of ozone generation, while alkanes were the main contributor to the formation potential of secondary organic aerosols. The VOCs emission factor of the fastener industry was 1.51 kg/t. The national annual VOCs emissions of fastener industry from 2018 to 2020 were 11, 496.84, 13, 301.89 and 14,365.69 tons in respective, with the annual growth rate of 11.85%.

Key words： fastener industry volatile organic compounds emission characteristics environmental impact emission factor emissons

收稿日期: 2021-08-17

PACS:

X511

基金资助:国家自然科学基金资助项目（51638001）

通讯作者: 程水源,教授,chengsy@bjut.edu.cn E-mail: chengsy@bjut.edu.cn

作者简介: 郑海胜(1996-),男,河南信阳人,北京工业大学硕士研究生,主要从事大气污染防治及环境规划管理方面研究.

引用本文:

郑海胜, 王晓琦, 王瑞鹏, 王凯, 沈泽亚, 程水源. 标准件行业VOCs排放特征及环境影响分析[J]. 中国环境科学, 2022, 42(3): 1048-1056. ZHENG Hai-sheng, WANG Xiao-qi, WANG Rui-peng, WANG Kai, SHEN Ze-ya, CHENG Shui-yuan. VOCs emission characteristics and environmental impact analysis of fastener industry. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(3): 1048-1056.

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http://www.zghjkx.com.cn/CN/ 或 http://www.zghjkx.com.cn/CN/Y2022/V42/I3/1048

[1]	Li L Y, Xie S D, Zeng L M, et al. Characteristics of volatile organic compounds and their role in ground-level ozone formation in the Beijing-Tianjin-Hebei region, China[J]. Atmospheric Environment,2015,113:247-254.
[2]	李红,彭良,毕方,等.我国PM2.5与臭氧污染协同控制策略研究[J].环境科学研究, 2019,32(10):1763-1778.Li H, Peng L, Bi F, et al. Strategy of coordinated control of PM2.5 and ozone in China[J]. Research of Environmental Sciences, 2019,32(10):1763-1778.
[3]	肖龙,王帅,周颖,等.中国典型背景站夏季VOCs污染特征及来源解析[J].中国环境科学, 2021,41(5):2014-2027.Xiao L, Wang S, Zhou Y, et al. The characteristics and source apportionments of VOCs at typical background sites during summer in China[J]. Chinese Environmental Science, 2021,41(5):2014-2027.
[4]	Hamid R, Mojgan H M, Parthasarathi M, et al. Emissions of volatile organic compounds from crude oil processing-Global emission inventory and environmental release[J]. Science of the Total Environment, 2020,727:138-154.
[5]	Shen L J, Xiang P, Liang S W, et al. Sources profiles of volatile organic compounds (VOCs) measured in a typical industrial process in Wuhan, Central China[J]. Atmosphere, 2018,9(8):297-312.
[6]	郭凤艳,刘芯雨,程晓娟,等.天津临港某石化企业VOCs排放特征研究[J].中国环境科学, 2017,37(6):2072-2079.Guo F Y, Liu X Y, Cheng X J, et al. Study on VOCs emission characteristic of a petrochemical enterprise in Tianjin Lingang[J].China Environmental Science, 2017,37(6):2072-2079.
[7]	Song C B, Wu L, Xie Y C, et al. Air pollution in China:Status and spatiotemporal variations[J]. Environmental Pollution, 2017,227:334-347.
[8]	冯凝,唐梦雪,李孟林,等.深圳市城区VOCs对PM2.5和O3耦合生成影响研究[J].中国环境科学, 2021,41(1):11-17.Feng N, Tang M X, Li M L, et al. Research on the influence of VOCs on the coupling generation of PM2.5 and O3 in Shenzhen[J]. China Environmental Science, 2021,41(1):11-17.
[9]	包亦姝,王斌,邓也,等.成都市典型有机溶剂使用行业VOCs组成成分谱及臭氧生成潜势研究[J].环境科学学报, 2020,40(1):76-82.Bao Y S, Wang B, Deng Y, et al. Source profiles and ozone formation potential of VOCs emitted from typical industries using organic solvents in Chengdu[J]. Acta Scientiae Circumstantiae, 2020,40(1):76-82.
[10]	王银海,董莉,刘景洋,等.典型溶剂使用行业O3和SOA生成潜势分析[J].现代化工, 2020,40(11):11-19.Wang Y H, Dong L, Liu J Y, et al. Analysis and research on generation potential of ozone and SOA in typical solvent use industries[J].Modern Chemical Industry, 2020,40(11):11-19.
[11]	Yuan B, Shao M, Lu S H, et al. Source profiles of volatile organic compounds associated with solvent use in Beijing, China[J].Atmospheric Environment, 2010,44:1919-1926.
[12]	于艳,王秀艳,杨文.天津市机动车二次有机气溶胶生成潜势的估算[J].中国环境科学, 2015,35(2):381-386.Yu Y, Wang X Y, Yang W. Estimate of vehicles generation of secondary organic aerosols of Tianjin[J]. China Environmental Science, 2015,35(2):381-386.
[13]	段乐君,袁自冰,沙青娥,等.不同排放标准下机动车挥发性有机物种排放特征趋势研究[J].环境科学学报, 2021,41(4):1239-1249.Duan L J, Yuan Z B, Sha Q E, et al. Investigation on the trend of emission characteristics of volatile organic compounds from motor vehicle exhaust under different emission standards[J]. Acta Scientiae Circumstantiae, 2021,41(4):1239-1249.
[14]	吕大器,陆思华,谭鑫,等.典型地方炼化企业VOCs排放特征及其对二次污染生成的贡献[J].环境科学研究, 2021,34(1):103-113.LüD Q, Lu S H, Tan X, et al. Emission characteristics of VOCs from typical local refineries and associated contributions to secondary pollution[J]. Research of Environmental Sciences, 2021,34(1):103-113.
[15]	Han S J, Zhao Q Y, Zhang R Q, et al. Emission characteristic and environmental impact of process-based VOCs from prebaked anode manufacturing industry in Zhengzhou, China[J]. Atmospheric Pollution Research, 2020,11:67-77.
[16]	王学臣,王帅,刘大喜,等.典型工业源挥发性有机物排放特征及臭氧生成潜势分析[J].环境污染与防治, 2020,42(11):1387-1391.Wang X C, Wang S, Liu D X, et al. VOCs emission characteristics and ozone formation analysis of typical industrial sources[J].Environmental Pollution and Prevention, 2020,42(11):1387-1391.
[17]	程水源,李文忠,魏巍,等.炼油厂分季节VOCs组成及其臭氧生成潜势分析[J].北京工业大学学报, 2013,39(3):438-444.Cheng S Y, Li W Z, W W, et al. Refinery VOCs seasonal composition and analysis of ozone formation potential[J]. Journal of Beijing University of Technology, 2013,39(3):438-444.
[18]	李国昊,魏巍,程水源,等.炼焦过程VOCs排放特征及臭氧生成潜势[J].北京工业大学学报, 2014,40(1):92-99.Li G H, Wei W, Cheng S Y, et al. Emission characterization and ozone formation potential of VOCs during the coking process[J]. Journal of Beijing University of Technology, 2014,40(1):92-99.
[19]	中华人民共和国生态环境部.关于印发《2020年挥发性有机物治理攻坚方案》的通知[EB/OL]. https://www.mee.gov.cn/xxgk2018/xxgk/xxgk03/202006/t20200624_785827.html, 2020-06-24.Ministry of Ecology and Environment of the People's Republic of China. Circular on the issuance of the 2020 volatile organic compounds treatment solution[EB/OL]. https://www.mee.gov.cn/xxgk2018/xxgk/xxgk03/202006/t20200624_785827.html, 2020-06-24.
[20]	巩保光,吴立波,高志贤.永年标准件产业发展现状及问题研究[J].邯郸职业技术学院学报, 2014,27(3):18-20.Gong B G, Wu L B, Gao Z X. Research on the development status and problems of the fastener industry in Yongnian[J]. Journal of Handan Polytechnic College, 2014,27(3):18-20.
[21]	李利平.邯郸市永年区标准件产业现状、污染问题及对策探讨[J].皮革制作与环保科技, 2021:120-122.Li L P. Current situation, pollution problems and countermeasures of standard parts industry in Yongnian district of Handan city[J]. Leather Manufacture Environmental Technology, 2021:120-122.
[22]	HJ 732-2014固定污染源废气挥发性有机物的采样气袋法[S].HJ 732-2014 Stationary source waste gas Sampling of volatile organic compounds air pocket method[S].
[23]	HJ 759-2015环境空气挥发性有机物的测定罐采样/气相色谱-质谱法[S].HJ 759-2015 Ambient air-Determination of volatile organic compounds Canister sampling/gas chromatography-mass spectrometry[S].
[24]	方莉,刘文文,陈丹妮,等.北京市典型溶剂使用行业VOCs成分谱[J].环境科学, 2019,40(10):4398-4403.Fang L, Liu W W, Chen D N, et al. Source profiles of volatile organic compounds (VOCs) from typical solvent-based industries in Beijing[J]. Environmental Science, 2019,40(10):4398-4403.
[25]	Ran L, Zhao C S, Xu W Y, et al. VOC reactivity and its effect on ozone production during the Hachi summer campaign[J].Atmospheric Chemistry and Physics, 2011,11(10):4657-4667.
[26]	李用宇,朱彬,安俊琳,等.南京北郊秋季VOCs及其光化学特征观测研究[J].环境科学, 2013,34(8):2933-2942.Li Y Y, Zhu B, An J L, et al. Characteristics of VOCs and their photochemical reactivity in autumn in Nanjing northern suburb[J].Environmental Science, 2013,34(8):2933-2942.
[27]	邹宇,邓雪桥,李菲,等.广州番禺大气成分站复合污染过程VOCs对O3与SOA的生成潜势[J].环境科学, 2017,38(6):2246-2255.Zou Y, Deng X Q, Li F, et al. Effect of VOCs on O3 and SOA formation potential during the combined pollution process in Guangzhou Panyu atmospheric composition station[J]. Environmental Science, 2017,38(6):2246-2255.
[28]	武蕾丹,王秀艳,杨文,等.某工业园区VOCs臭氧生成潜势及优控物种[J].环境科学, 2018,39(2):511-516.Wu L D, Wang X Y, Yang W, et al. Ozone formation potential and priority species of VOCs in an industrial park[J]. Environmental Science, 2018,39(2):511-516.
[29]	Cheng N N, Jing D, Zhang C, et al. Process-based VOCs source profiles and contributions to ozone formation and carcinogenic risk in a typical chemical synthesis pharmaceutical industry in China[J].Science of Total Environment, 2021,752:141899.
[30]	Liang X M, Sun X B, Xu J T, et al. Improved emissions inventory and VOCs speciation for industrial OFP estimation in China[J]. Science of the Total Environment, 2020,745:140838.
[31]	Gao Y Q, Li M, Wan X, et al. Important contributions of alkenes and aromatics to VOCs emissions, chemistry and secondary pollutants formation at an industrial site of central eastern China[J].Atmospheric Environment, 2021,244:117927.
[32]	Wang H L, Hao R, Fang L, et al. Study on emissions of volatile organic compounds from a typical coking chemical plant in China[J].Science of Total Environment, 2021,752:141927.
[33]	Carter W P L. Development of the SAPRC-07chemical mechanism[J].Atmospheric Environment, 2010,44(40):5324-5335.
[34]	Zheng J, Yu Y, Mo Z, et al. Industrial sector-based volatile organic compound (VOC) source profiles measured in manufacturing facilities in the Pearl River Delta, China[J]. Science of The Total Environment,2013,456-457:127-136.
[35]	Derwent R G, Jenkin M E, Utembe S R, et al. Secondary organic aerosol formation from a large number of reactive man-made organic compounds[J]. Science of The Total Environment, 2010,408(16):3374-3381.
[36]	中研智业研究院.中国标准件产品市场发展预测及投资策略研究报告2021-2026年[R].北京:中研智业华泰信息技术研究院, 2021.Zhongyan Zhiye research Institute. Report on market development forecast and investment strategy of fastener products in China (2021-2026)[R]. Beijing:Zhongyan Zhiye Huatai Information Technology Research Institute, 2021.
[37]	余宇帆.珠江三角洲地区典型工业VOCs源排放成分谱研究[D].广州:华南理工大学, 2012.Yu Y F. A study on chemical compostions of typical industrial VOC emission sources in the Pearl River Delta region[D]. Guangzhou:South China University of Technology, 2012.
[38]	邵奕欣.典型行业挥发性有机物排放特征及减排潜力研究[D].杭州:浙江大学, 2019.Shao Y X. Study on emission characteristics and emission reduction potential of volatile organic compounds from typical industries[D].Hangzhou:Zhejiang university, 2019.