Abstract：In order to study the emission and temporal and spatial distribution characteristics of volatile organic compounds (BVOCs) from natural sources in Beijing, Tianjin and Hebei regions in recent 20 years, based on five periods of China's land use data obtained from satellite remote sensing interpretation in 2000, 2005, 2010, 2015 and 2020, this paper calculates and obtains the emission and emission composition of BVOCs from cities and counties in Beijing, Tianjin and Hebei, At the same time, the temporal and spatial distribution of BVOCs emission in Beijing Tianjin Hebei region in recent 20 years is analyzed The results show that the average total emission of BVOCs in Beijing Tianjin Hebei region in recent 20 years is 764000 T/A, of which the average total emission of Hebei Province, Beijing and Tianjin are 591100T/A, 152900T/A and 20000t/a respectively; According to the analysis of emission composition, the average total emission of ISOP is 168000T/A, accounting for 21.99% of the total emission, the average total emission of TMT is 296200T/A, accounting for 38.77% of the total emission, and the average total emission of OVOCs is 299700T/ A, accounting for 39.23% of the total emission According to the analysis of emission time characteristics, the BVOCs emission in Beijing Tianjin Hebei region is the lowest in winter and the highest in summer The spatial distribution of BVOCs emissions is closely related to land use types and vegetation distribution. There are significant differences in the contribution of BVOCs emissions from different land use types. The average BVOCs emissions from forest land, cultivated land and grassland in Beijing Tianjin Hebei region in recent 20 years are 603300T/A, 127800T/A and 23100T/a respectively, accounting for 78.90%, 16.79% and 3.04% of the total emissions respectively The spatial emission distribution of BVOCs in Beijing Tianjin Hebei region is obviously different, and the overall emission in the north and northeast is significantly higher than that in the South and Southeast This study can provide research ideas for the calculation of BVOCs, and provide relevant basic data for air pollution control in Beijing, Tianjin and Hebei.
亓浩雲, 王晓琦, 程水源, 蔡斌, 李奥哲. 2000~2020年京津冀BVOCs排放量估算及时空分布特征[J]. 中国环境科学, 2022, 42(4): 1501-1509.
QI Hao-yun, WANG Xiao-qi, CHENG Shui-yuan, CAI Bin, LI Ao-zhe. Estimation of BVOCs emissions from Beijing, Tianjin and Hebei from 2000 to 2020 and its temporal and spatial distribution characteristics. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(4): 1501-1509.
Kesselmeier J, Staudt M J. Biogenic Volatile Organic Compounds (VOC):An Overview on Emission, Physiology and Ecology[J]. Journal of Atmospheric Chemistry, 1999,33(1):23-88.
[2]
Guenther A, Baugh B, Brasseur G, et al. Isoprene emission estimates and uncertainties for the central African EXPRESSO study domain[J]. Journal of Geophysical Research Atmospheres, 1999,104(D23):30625-30639.
[3]
Sartelet K N, F Couvidat, Seigneur C, et al. Impact of biogenic emissions on air quality over Europe and North America[J]. Atmospheric Environment, 2012,53(JUN.):131-141.
[4]
Arneth A, Schurgers G, J Lathière, et al. Global terrestrial isoprene emission models:sensitivity to variability in climate and vegetation[J]. Atmospheric Chemistry and Physics, 2011,11(15):8037-8052.
[5]
Rasheed M U, Kivimenp M, Kasurinen A. Emissions of biogenic volatile organic compounds (BVOCs) from the rhizosphere of Scots pine (Pinus sylvestris) seedlings exposed to warming, moderate N addition and bark herbivory by large pine weevil (Hylobius abietis)[J]. Plant and Soil, 2021:1-16.
[6]
Lee Ki Ho, Kim Hyeong Cheol, Hu Chul Goo. A Study on the Estimation of BVOCs Emission in Jeju Island (1)[J]. Journal of Environmental Science International, 2014,23(12):13.
[7]
宋媛媛,张艳燕,王勤耕,等.基于遥感资料的中国东部地区植被VOCs排放强度研究[J]. 环境科学学报, 2012,32(9):2216-2227. Song Y Y, Zhang Y Y, Wang Q G, et al. 2012.Estimation of biogenic VOCs emissions in Eastern China based on remote sensing data[J]. Acta Scientiae Circumstantiae, 2012,32(9):2216-2227.
[8]
宁文涛,赵善伦.东亚地区生物源ISOP排放的估算[J]. 绿色科技, 2012,(4):209-212. Ning W T, Zhao S L. Estimation of biologically derived isoprene emissions in East Asia[J]. Journal of Green Science and Technology, 2012,(4):209-212.
[9]
刘岩,李莉,安静宇,等.长江三角洲2014年天然源BVOCs排放、组成及时空分布[J]. 环境科学, 2018,39(2):608-617. Liu Yan, Li Li, An Jing-yu, et al. Emissions,Chemical Composition, and Spatial and Temporal Allocation of the BVOCs in the Yangtze River Delta Region in 2014[J]. Environmental Science, 2018,39(2):608-617.
[10]
郑君瑜,郑卓云,王兆礼,等.珠江三角洲天然源VOCs排放量估算及时空分布特征[J]. 中国环境科学, 2009,29(4):345-350. Zheng Jun-yu, Zheng Zhuo-yun, Wang Zhao-li, et al. Biogenic VOCs emission inventory and its temporal and spatial characteristics in the Pearl River Delta area[J]. China Environmental Science, 2009,29(4):345-350.
[11]
Lun X, Lin Y, Chai F, et al. Reviews of emission of biogenic volatile organic compounds(BVOCs) in Asia[J]. Journal of Environmental Sciences, 2020,95(9):266-277.
[12]
Guenther A, Hewitt C N, Erickson D, et al. A global model of natural volatile organic compound emissions[J]. Journal of Geophysical Research Atmospheres, 1995,100(D5):8873-8892.
[13]
A A G, B C G, C T P, et al. Natural emissions of non-methane volatile organic compounds, carbon monoxide, and oxides of nitrogen from North America-ScienceDirect[J]. Atmospheric Environment, 2000, 34(12-14):2205-2230.
[14]
吴莉萍,翟崇治,周志恩,等.重庆市主城区挥发性有机物天然源排放量估算及分布特征研究[J]. 三峡环境与生态, 2013,35(4):12-15. Wu Li-ping, Zhai Chong-zhi, Zhou Zhi-en, et al. Research on the Emission Estimation and Distribution Characteristics of Biogenic VOCs from Natural Sources in Urban Chongqing[J]. Environment and Ecology in the Three Gorges, 2013,35(4):12-15.
[15]
高翔,刘茂辉,徐媛,等.天津市植被排放挥发性有机物估算及时空分布[J]. 西部林业科学, 2016,45(6):108-114. Gao Xiang, Liu Mao-hui, Xu Yuan, et al. Biogenic VOCs Emission in Tianjin City and Its Temporal and Spatial Distribution[J]. Journal of West China Forestry Science, 2016,45(6):108-114.
[16]
Alex B. Guenther, Patrick R. Zimmerman, Peter C. Harley, et al. Isoprene and monoterpene emission rate variability:Model evaluations and sensitivity analyses[J]. Journal of Geophysical Research Atmospheres, 1993,98(D7):9.
[17]
Guenther, Alex. Seasonal and spatial variations in natural volatile organic compound emissions[J]. Ecological Applications, 1997,7(1):34-45.
[18]
张蕾,姬亚芹,赵杰,等.乌鲁木齐市天然源VOCs排放量估算与时空分布特征[J]. 中国环境科学, 2017,37(10):3692-3698. Zhang Lei, Ji Ya-qin, Zhao Jie, et al. Estimation of biogenic VOCs emissions and its spatial-temporal distribution in Urumqi[J]. China Environmental Science, 2017,37(10):3692-3698.
[19]
Asner G P, Scurlock J, Hicke J A. Global synthesis of leaf area index observations:implications for ecological and remote sensing studies[J]. Global Ecology and Biogeography, 2003,12(3):191-205.
[20]
夏春林,肖琳.京津冀天然源挥发性有机物排放研究[J]. 环境科学学报, 2019,39(8):2680-2689. Xia Chun-lin, Xiao Lin. Estimation of biogenic volatile organic compounds emissions in Jing-Jin-Ji[J]. Acta Scientiae Circumstantiae, 2019,39(8):2680-2689.
[21]
张蔷,李令军,赵文慧,等.北京森林BVOCs排放特征及对区域空气质量的影响[J]. 中国环境科学, 2021,41(2):622-632. Zhang Qiang, Li Ling-jun, Zhao Wen-hui, et al. Emission characteristics of VOCs from forests and its impact on regional air quality in Beijing[J]. China Environmental Science, 2021,41(2):622-632.
[22]
樊冲.河北省森林植物源挥发性有机物排放量研究[D]. 北京:北京林业大学, 2019. Fan Chong. Study on Biogenic Volatile Organic Compounds Emission from Forest Plants in Heibei Province[D]. Beijing:Beijing Forestry University, 2019.
[23]
Wang Z, Bai Y, Zhang S. A biogenic volatile organic compounds emission inventory for Beijing[J]. Atmospheric Environment, 2003, 37(27):3771-3782.
[24]
胡泳涛,张远航,谢绍东,等.区域高时空分辨率VOC天然源排放清单的建立[J]. 环境科学, 2001,(6):1-6. Hu Yong-tao, Zhang Yuan-hang, Xie Shao-dong, et al. Development of Biogenic VOC Emissions Inventory with High Temporal and Spatial Resolution[J]. Environmental Science, 2001,(6):1-6.
[25]
冯宗炜,王效科,吴刚.中国森林生态系统的生物量和生产力[M]. 北京:科学出版社, 1999:34-311. Feng Zong-wei, Wang Xiao-ke, Wu Gang. Biomass and productivity of forest ecosystems in China[M]. Beijing:Science Press, 1999:34-311.
[26]
方精云,刘国华,徐嵩龄.中国陆地生态系统的碳库[M]. 北京:中国环境科学出版社, 1996:109-128. Fang Jing-yun, Liu Guo-hua, Xu Song-ling. Carbon pool of terrestrial ecosystem in China[M]. Beijing:China Environmental Science Press, 1996:109-128.
[27]
Monson R K, Guenther A B, Fall R. Physiological reality in relation to ecosystem- and global-level estimates of isoprene emission[M]. San Diego:1991:185-207.
[28]
Sharkey L. On the relationship between isoprene emission and photosynthetic metabolites under different environmental conditions[J]. Planta, 1993,189(3):420-424.
[29]
Chen W H, Guenther A B, Wang X M, et al. Regional to global biogenic isoprene emission responses to changes in vegetation from 2000 to 2015[J]. Journal of Geophysical Research Atmospheres, 2018,2018(7):10.
[30]
高超,张学磊,修艾军,等.中国生物源挥发性有机物(BVOCs)时空排放特征研究[J]. 环境科学学报, 2019,39(12):4140-4151. Gao Chao, Zhang Xue-lei, Xiu Ai-jun, et al. Spatiotemporal distribution of biogenic volatile organic compounds emissions in China[J]. Acta Scientiae Circumstantiae, 2019,39(12):4140-4151.
[31]
井潇溪.北京市森林植物挥发性有机物排放研究[D]. 北京:北京林业大学, 2020. Jing Xiao-xi. Study on Biogenic Volatile Organic Compounds Emission from Forest Plants in Beijing[D]. Beijing:Beijing Forestry University, 2020.
[32]
Li J, Li L Y, Wu R R, et al. Inventory of highly resolved temporal and spatial volatile organic compounds emission in China[C]//Air Pollution 2016. 2016.
