污染场地中VOCs的环境行为与调查评估技术

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摘要在梳理场地VOCs环境行为及影响因子研究基础上, 分析了我国VOCs污染场地调查和风险评估领域面临的问题,主要体现在现有土壤调查方法未充分考虑VOCs在土壤气相中的赋存, 导致采样过程中的VOCs逃逸而低估了场地实际污染; VOCs风险评估方法忽略了有机质的非线性吸收、源强的衰减以及优先通道的传输,造成风险评估结果存在不确定性.针对国内VOCs调查评估存在的问题, 详细回顾和分析了国际上土壤气监测技术、风险评估模型, 以及多证据风险评估方法研究及应用, 并在此基础上提出了未来我国VOCs污染场地调查评估领域的发展建议, 即在充分认识VOCs环境行为的基础上,进一步探索适合我国污染场地实际应用情景的调查和风险评估方法, 切实提高我国工业遗留场地土壤污染风险防控水平.

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	张文毓
	钟茂生
	姜林
	王世杰
	宋博宇
	赖劲宇
	马琳
	李吉鸿
	王嘉敏

关键词 ：污染场地, 挥发性有机物, 蒸气入侵, 土壤气采样, 风险评估

Abstract：Volatile Organic Compounds (VOCs) are common in contaminated sites, presenting complex environmental behaviors and high risks for investigation and risk assessment. This paper outlines the major environmental processes of VOCs partitioning and transport in soil, followed by a review of VOCs investigation techniques, risk screening methods, vapor intrusion models, and integrated VI risk assessment methods using multi-lines of evidence. Additionally, the main issues in investigating and assessing VOCs contaminated sites in China are compared to international lessons, from which valuable insights can be gained. Finally, recommendations for improving the investigation and risk assessment of VOCs contaminated sites in China are also provided.

Key words： contaminated site volatile organic compounds vapour intrusion soil gas sampling risk assessment

收稿日期: 2022-10-18

PACS:

X52

基金资助:国家重点研发计划(2018YFC1801303);国家自然科学基金资助(42177404)

通讯作者: 姜林,研究员,Jianglin@cee.cn E-mail: Jianglin@cee.cn

作者简介: 张文毓(1985-),女,河南郑州人,副研究员,博士,主要从事固体废物及土壤污染治理研究.发表论文20余篇.zhangwenyu@cee.cn

引用本文:

张文毓, 钟茂生, 姜林, 王世杰, 宋博宇, 赖劲宇, 马琳, 李吉鸿, 王嘉敏. 污染场地中VOCs的环境行为与调查评估技术[J]. 中国环境科学, 2023, 43(6): 2814-2822. ZHANG Wen-yu, ZHONG Mao-sheng, JIANG Lin, WANG Shi-jie, SONG Bo-yu, LAI Jin-yu, MA Lin, LI Ji-hong, WANG Jia-min. Environmental behavior, investigation and risk assessment technologies of VOCs in contaminated sites. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(6): 2814-2822.

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http://www.zghjkx.com.cn/CN/ 或 http://www.zghjkx.com.cn/CN/Y2023/V43/I6/2814

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