Field study on ERT monitoring high-pressure rotary jet repairing PAHs pollution
LIU Di1, SONG Quan-wei2,3, LI Ling4, HU Jie1, WANG Ting-jun4, DU Xian-yuan2,3, DENG Yong-feng5, KE Han1
1. Key Laboratory of Soft Soils and Geoenvironmental Engineering, Ministry of Education, Institute of Geotechnical Engineering, Zhejiang University, Hangzhou 310058, China; 2. State Key Laboratory of Petroleum Pollution Control, Beijing 102206, China; 3. CNPC Research Institute of Safety and Environment Technology, Beijing 102206, China; 4. CECEP DADI Environmental Remediation Co., Ltd., Beijing 100085, China; 5. Institute of Geotechnical Engineering, Transportation College, Southeast University, Nanjing 210096, China
Abstract:In this study, sodium persulfate (PS) was selected as the oxidant, Fe0[μm], Fe0[nm, BC-nZVI and NaOH were chosen as activators, and repair PAHs-contaminated soil through high-pressure rotary spraying process by mixture of PS and activators. The high-density electrical resistivity tomography (ERT) technique was employed to monitor the distribution of soil resistivity during the rotary jet process, enabling an analysis of the migration and transformation patterns of the oxidation agents during the remediation process. Additionally, the remediation effects of the 4 agent groups were compared after a 48-hour jet period.The experimental results demonstrated that ERT accurately reflected the locations of pollution remediation, with a maximum deviation of less than 0.5m. The changes in resistivity showed a positive correlation with naphthalene remediation. However, discrepancies existed between the estimated remediation values obtained from fitting curves and the actual remediation values, with errors ranging from 10.3% to 22.6%. Among the tested reagents, carbon-supported iron powder exhibited excellent stability and sustained release performance, leading to an extension of the stable oxidation stage by approximately 8hours after jet. Ultimately, the predetermined remediation area achieved the highest level of pollutant removal in the following order:BC-nZVI>Fe0[nm]>Fe0[μm]≈NaOH.
柳迪, 宋权威, 李玲, 胡杰, 王颋军, 杜显元, 邓永锋, 柯瀚. ERT法监测高压旋喷修复PAHs污染现场试验研究[J]. 中国环境科学, 2023, 43(11): 5933-5943.
LIU Di, SONG Quan-wei, LI Ling, HU Jie, WANG Ting-jun, DU Xian-yuan, DENG Yong-feng, KE Han. Field study on ERT monitoring high-pressure rotary jet repairing PAHs pollution. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(11): 5933-5943.
杜延军,金飞,刘松玉,等.重金属工业污染场地固化/稳定处理研究进展[J]. 岩土力学, 2011,32(1):116-124. Du Y J, Jin F, Liu S Y, et al. Review of stabilization/solidification technique for remediation of heavy metals contaminated lands [J]. Rock and Soil Mechanics, 2011,32(1):116-124.
[2]
王颖.土壤气相抽提修复苯系物污染场地模拟及效果预测研究[D]. 保定:河北农业大学, 2020. Wang Y. Study on simulation and prediction of BTET contaminated site remediation effect by soil vapor extraction [D]. Baoding:Hebei Agricultural University, 2020.
[3]
Zhang W, Mi Y, Jiao W. Study on the migration mechanisms of water-soluble agents in high-pressure rotary jetting remediation [J]. Environ Sci Pollut Res Int, 2022,29:74038-74050.
[4]
Ma B, Wang Z, Yuan X, et al. In situ stabilization of heavy metals in a tailing pond with a new method for the addition of mineral stabilizers-high-pressure rotary jet technology [J]. Environmental Science and Pollution Research, 2020,27:15388-15400.
[5]
Ranc B, Faure P, Croze V, et al. Selection of oxidant doses for in situ, chemical oxidation of soils contaminated by polycyclic aromatic hydrocarbons (PAHs):A review [J]. Journal of Hazardous Materials, 2016,312:280-297.
[6]
Brusseau M L, Nelson N T, Zhang Z, et al. Source-zone characteri-zation of a chlorinated-solvent contaminated Superfund site in Tucson, AZ [J]. Journal of Contaminant Hydrology, 2015,90(1/2):21-40.
[7]
Xia W Y, Du Y J, Li F S, et al. In-situ solidification/stabilization of heavy metals contaminated site soil using a dry jet mixing method and new hydroxyapatite based binder [J]. Journal of Hazardous Materials, 2019,369:353-361.
[8]
宛召.高压旋喷工艺在上海某污染场地修复中的应用研究[D]. 长春:吉林大学, 2017. Wan Z, Study on the application of high pressure jet grouting technology in the remediation of a contaminated Site in Shanghai [D]. Changchun:Jilin University, 2017.
[9]
董万涛.新型复合氧化剂在石油污染场地修复的应用研究[D]. 兰州:兰州理工大学, 2021. Dong Wan-tao. Research on application of new complex oxidants in petroleum contaminated site [D]. Lanzhou:Lanzhou University of Technology, 2021.
[10]
Site Characterization technologies for DNAPL Investigations [Z]. EPA 542-R-04-017, 2004.
[11]
Lane J W, Day L F D, Casey C C. Geophysical monitoring of a field-scale bio-stimulation pilot project [J]. Ground Water, 2010, 44(3).
[12]
Peale J G D, Mueller J, Molin J.Successful ISCR enhanced bioremediation of a TCE DNAPL source utilizing EHC and KB-1[J]. Remediation Journal, 2010,20(3):63-81.
[13]
GB/T 50123-2019土工试验方法标准[S]. GB/T 50123-2019 Standard for geotechnical testing method [S].
[14]
GB/T 50145-2007土的工程分类标准[S]. GB/T 50145-2007 Standard for classification of engineering soils [S].
[15]
HJ/T 166-2004土壤环境监测技术规范[S]. HJ/T 166-2004 The technical specification for soil environmental monitoring [S].
[16]
HJ 1019-2019地块土壤和地下水中挥发性有机物采样技术导则:[S]. HJ 1019-2019 Technical guideline for site soil and groundwater sampling of volatile organic compounds [S].
[17]
HJ 605-2011土壤和沉积物挥发性有机物的测定吹扫捕集/气象色谱-质谱法[S] HJ 605-2011 Soil and sediment-determination of volatile organic compounds-purge and trap gas chromatography/mass spectrometry method [S].
[18]
HJ 766-2015固体废物金属元素的测定电感耦合等离子体质谱法[S]. HJ 766-2015 Solid waste-determination of metals inductively coupled plasma mass spectrometry (ICP-MS) [S].
[19]
HJ 804-2016土壤8种有效态元素的测定二乙烯三胺五乙酸浸提-电感耦合等离子体发射光谱法[S]. HJ 804-2016 Soil-determination of bioavailable form of eight elements-Extraction withbuffered DTPA solution/Inductively coupled plasma optical emission spectrometry [S].
[20]
GB36600-2018土壤环境质量建设用地土壤污染风险管控标准(试行) [S]. GB36600-2018 Soil environmental quality risk control standard for soil contamination of development land [S].
[21]
潘栋宇,侯梅芳,刘超男,等.多环芳烃污染土壤化学修复技术的研究进展[J]. 安全与环境工程, 2018,25(3):54-66. Pan D Y, Hou M F, Liu C N, et al. Review of chemical remediation technology of polycyclic aromatic hydrocarbons contaminated soil. [J]. Safety and Environmental Engineering, 2018, 25(3):54-66.
[22]
Killian P F, Bruell C J, Marley M C, et al. Iron (II) activated persulfate oxidation of MGP contaminated soil [J]. Journal of Soil Contamination, 2007,16(6):523-537.
[23]
Do S H, Kwon Y J, Kong S H. Effect of metal oxides on the reactivity of persulfate/Fe(II) in the remediation of diesel-contaminated soil and sand [J]. Journal of Hazardous Materials, 2010,182(1):933-936.
[24]
Pac T, Baldock J, Brodie B, et al. In situ chemical oxidation:Lessons learned at multiple sites [J]. Remediation Journal, 2019,29:75-91.
[25]
张羽,高春阳,陈昌照,等.零价铁活化过硫酸钠体系降解污染土壤中的多环芳烃[J]. 环境工程学报, 2019,13(4):955-962. Zhang Y, Gao C Y, Chen C Z, et al. Degradation of PAHs in contaminated soil by zero valent iron activatedsodium persulfate system [J]. Chinese Journal of Environmental Engineering, 2019,13(4):955-962.
[26]
Zhang B W, Guo Y, Huo J Y. Combining chemical oxidation and bioremediation for petroleum polluted soil remediation by BC-nZVI activated persulfate [J]. Chemical Engineering Journal, 2021,382(1):123055,2-9.
[27]
Kim J H, Yi M J, Park S G, et al. 4-D inversion of DC resistivity monitoring data acquired over a dynamically changing earth model [J]. Journal of Applied Geophysics, 2009,68(4):522-532.
[28]
Karaoulis M C, Kim J H, Tsourlos P I. 4D active time constrained resistivity inversion [J]. Journal of Applied Geophysics, 2011,73(1):25-34.
[29]
张文杰,秘永宝.高压旋喷修复中水溶性药剂径向迁移规律研究[J]. 岩土工程学报, 2023,45(5):1017-1023. Zhang Wen-jie, Mi Yong-bao. Radial migration of water-soluble agents in high-pressure rotary jetting remediation [J]. Chinese Journal of Geotechnical Engineering, 2023,45(5):1017-1023.
[30]
韩瑞瑞.碳载双金属活化过硫酸钠修复石油污染土壤[D]. 北京:北京化工大学, 2022.DOI:10.26939/d.cnki.gbhgu.2022.000769. Han Rui-rui. Remediation of petroleum-contaminated soil by sodium persulfate activated by carbon-suppprted bimetallic [D]. Beijing University of Chemical Technology, 2022.DOI:10.26939/d.cnki. gbhgu, 2022.000769.
[31]
Thao T T, Kim C, Hwang I. Application of nanosized zerovalent iron activated persulfate for treating groundwater contaminated with phenol. [J] Journal of Soil and Groundwater Environment, 2017,22(1):41-48.
[32]
Przemyslaw D, Leonidas P, Allaa, et al. Impact of peroxydisulfate in the presence of zero valent iron on the oxidation of cyclohexanoic acid and naphthenic acids from oil sands process-affected water [J]. Environmental Science & Technology, 2012,46(16):89-91.
[33]
Kim C, Ahn J Y, Kim T Y, et al. Activation of persulfate by nanosized zero-valent iron (NZVI):Mechanisms and transformation products of NZVI [J]. Environmental Science & Technology, 2018,52(6):3625-3633.
[34]
Furukawa Y, KIM J W, Watkins J, et al. Formation of ferrihydrite and associated iron corrosion products in permeable reactive barriers of zero-valent iron [J]. Environ-mental Science & Technology, 2002, 36(24):5469-5475.
[35]
Goi A, Trapido M, Kulik N, et al. Ozonation and Fenton treatment for remediation of diesel fuel contaminated soil [J]. Ozone Science & Engineering, 2006,28(1):37-46.
[36]
Christopher Power, Jason I. Gerhard, MariosKaraoulis, Panagiotis Tsourlos, Antonios Giannopoulos, Evaluating four-dimensional time-lapse electrical resistivity tomogram-phy for monitoring DNAPL source zone remediation [J]. Journal of Contaminant Hydrology, 2014, s162-163:27-46.