Contamination characteristics and migration of PAHs derivatives in soils
CHENG Peng-fei1,3, WANG Ze-ming2, ZHAO Xu-qiang2, GAO Yan-zheng2
1. Institute of Environmental Health and Ecological Security, School of Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China; 2. Institute of Organic Contaminant Control and Soil Remediation, Nanjing Agricultural University, Nanjing 210095, China; 3. Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and Management, Institute of Eco-environmental and Soil Sciences, Guangdong Academy of Sciences, Guangzhou 510650, China
Abstract：In this paper, the contamination levels and occurrence forms of chlorinated polycyclic aromatic hydrocarbons (ClPAHs) and nitrated polycyclic aromatic hydrocarbons (NPAHs) were reviewed in different regions and different utilization types of soils. The properties of ClPAHs and NPAHs, such as polarity, soil adsorption coefficient, bioconcentration factors, and energy level orbit were obtained by EPI Suite software and density functional theory calculation. The effects of the type, quantity and location of substituent groups on the properties and environmental trend of PAHs derivatives were also analyzed. Meanwhile, the migration behaviors of ClPAHs and NPAHs in soils, such as adsorption-desorption, photodegradation, redox and biodegradation, were summarized emphatically. Finally, the currently existing problems and trends of PAHs derivatives were also discussed. It is necessary to further optimize the detection method, establish the soil PAHs derivatives contaminant database, and explore the transformation data and mechanism, in order to provide more comprehensive information for soil PAHs derivatives contamination characteristics and migration.
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