Source analysis and pollution assessment of soil heavy metals in the economic belt on the northern slope of Tianshan Mountains
YE Pan-qing1, Abdugheni Abliz1,2, SUN Xiao-li1, Halidan Aisaiduli1
1. College of Geographical and Remote Sensing science, Xinjiang University, Urumqi 830046, China; 2. Ecological Post-Doctoral Research Station, Xinjiang University, Urumqi 830046, China
Abstract:In order to quantitatively identify and evaluate the sources and ecological risks of heavy metals in the Qitai, Jimsar, Fukang and other areas on the north slope of the Tianshan Mountains, we collected 171soil samples from the study area and analyzed the concentrations of Zn, Cu, Cr, Pb, Hg, As and Cd in soil. We used statistical methods of principal component analysis, positive matrix factorization (PMF) and potential ecological risk index to evaluate the degree of heavy metal pollution and to carry out source analysis. The results showed that:except for Zn, Cu, and Cr, the average concentration of Pb, Hg, As, and Cd in the soil exceeded Xinjiang soil heavy metal background values 4.1, 2.0, 8.0and 48.0times, respectively; compared with the national soil heavy metal risk screening value, the concentrations of Zn, Cr, and Hg were within the safe range. A few sample points of Cu and Pb were seriously polluted, exceeding the screening value. The average values of As and Cd exceeded the screening value by 3.09 times and 19.17times, respectively. According to the results of pollution source analysis the main pollution sources of soil in the study area are coal combustion, transportation, atmospheric dust, agricultural and industrial emissions as well as natural factors. The ecological risk assessment results showed that at all sampling points Zn, Cu, Cr, and Pb were at a slight risk state, Cd was at a very high-risk level; 73.68% of Hg was at a medium risk, 18.71% was at the high risk, 43.86% of As was at a moderate ecological risk, 51.46% was at the high risk. The comprehensive potential ecological risk index of the study area ranged from 472 to 2575.69, and the contribution rate of Cd to the comprehensive potential ecological index reached 89.24%, followed by As and Hg. The results indicated that Cd in the study area was very harmful to the soil eco-environment. As and Hg concentrations should be paid close attention.
叶盼青, 阿不都艾尼·阿不里, 孙小丽, 哈力旦·艾赛都力. 天山北坡经济带土壤重金属来源及污染评价[J]. 中国环境科学, 2022, 42(10): 4704-4712.
YE Pan-qing, Abdugheni Abliz, SUN Xiao-li, Halidan Aisaiduli. Source analysis and pollution assessment of soil heavy metals in the economic belt on the northern slope of Tianshan Mountains. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(10): 4704-4712.
董騄睿,胡文友,黄标,等.基于正定矩阵因子分析模型的城郊农田土壤重金属源解析[J].中国环境科学, 2015,35(7):2103-2111.Dong L R, Hu W Y, Huang B, et al.Source appointment of heavy metals in suburban farmland soils based on positive matrix factorization[J].China Environmental Science, 2015,35(7):2103-2111.
[2]
Lei C, Wang Y H, Xin W, et al.Quantitative source apportionment of heavy metals in cultivated soil and associated model uncertainty[J].Ecotoxicology and Environmental Safety, 2021,215:112150.
[3]
Fei X, Lou Z, Xiao R, et al.Source analysis and source-oriented risk assessment of heavy metal pollution in agricultural soils of different cultivated land qualities[J].Journal of Cleaner Production, 2022,341:130942.
[4]
Anaman R, Peng C, Jiang Z C, et al.Identifying sources and transport routes of heavy metals in soil with different land uses around a smelting site by GIS based PCA and PMF[J].Science of The Total Environment, 2022,823:153759.
[5]
姜凤成,李义连,杨森,等.秦王川盆地土壤重金属来源、分布及污染评价[J].中国环境科学, 2018,38(6):2243-2252.Jiang F C, Li Y L, Yang S, et al.Source analysis, distribution and pollution assessment of the soil heavy metals in the Qinwangchuan Basin[J].China Environmental Science, 2018,38(6):2243-2252.
[6]
Mashi S A, Yaro S A, Eyong P N.A survey of trends related to the contamination of street dust by heavy metals in Gwagwalada, Nigeria[J].Management of Environmental Quality An International Journal, 2005,16(1):71-76.
[7]
姚峰,包安明,古丽·加帕尔,等.新疆准东煤田土壤重金属来源与污染评价[J].中国环境科学, 2013,33(10):1821-1828.Yao F, Bao A M, Guli J, et al.Soil heavy metal sources and pollution assessment in the coalfield of East Junggar Basin in XinJiang[J].China Environmental Science, 2013,33(10):1821-1828.
[8]
任加国,王越,师华定,等.乐安河流域农用地表层土壤重金属污染评价及来源分析[J].环境化学, 2021,40(9):9.Ren J G, Wang Y, Shi H D, et al.Evaluation and source analysis of heavy metal pollution of surface soil in agricultural land of Lean River basin[J].Environmental Chemistry, 2021,40(9):9.
[9]
Luo Q, Wang S, Wang Y, et al.Multivariate statistical analysis of heavy metal concentration in suburb agricultural soils of Nanning City[J].Safety and Environmental Engineering, 2018,25(2):81-87,106.
[10]
Chandrasekaran A, Ravisankar R, Harikrishnan N, et al.Multivariate statistical analysis of heavy metal concentration in soils of Yelagiri Hills, Tamilnadu, India-Spectroscopical approach[J].Spectrochimica acta, Part A.Molecular and biomolecular spectroscopy, 2015,137:589-600.
[11]
Watanabe K, Yamamoto N, Kusano H, et al.Elucidation of mechanisms of heavy metal accumulation in stream aquatic insects by nitrogen and carbon stable isotope analysis[J].Journal of Japan Society on Water Environment, 2005,28(12):737-744.
[12]
Syl A, Jlca B, Xyba C, et al.Deciphering source contributions of trace metal contamination in urban soil, road dust, and foliar dust of Guangzhou, southern China[J].Science of The Total Environment, 695:133596-133596.
[13]
曹佳艺.基于UNMIX模型的农田土壤重金属源解析及污染损失评价[D].北京:中国地质大学, 2019.Cao J Y.Source analysis and pollution loss evaluation of heavy metals in farmland soil based on UNMIX model[D].Beijing:China University of Geosciences, 2019.
[14]
马广玉,李悦昭,陈瑞晖,等.抚仙湖上游土壤重金属污染负荷计算及来源解析[J].北京师范大学学报:自然科学版, 2021:255-230.Ma G Y, Li Y Z, Chen R H, et al.Load and source of heavy metal pollution in the upper reaches of Fuxian Lake[J].Journal of Beijing Normal University.Natural Science, 2021:255-230.
[15]
Alidadi R, Mansouri N, Hemasi A H, et al.Source apportionment of heavy metal with UNMIX in ambient air of Ahvaz City, Southwest of Iran[J].International Journal of Environmental Science and Technology, 2021,18(10):3099-3106.
[16]
王星蒙.基于PMF模型的柴河铅锌尾矿库周边农田土壤重金属源解析[J].绿色科技, 2021,23(10):160-162.Wang X M.Source analysis of heavy metals in farmland soil around Chaihe lead zinc tailings pond based on PMF model[J].Journal of Green Science and Technology, 2021,23(10):160-162.
[17]
柴磊,王新,马良,等.基于PMF模型的兰州耕地土壤重金属来源解析[J].中国环境科学, 2020,40(9):3919-3929.Chai L, Wang X, Ma L, et al.Sources appointment of heavy metals in cultivated soils of Lanzhou based on PMF models[J].China Environmental Science, 2020,40(9):3919-3929.
[18]
李娇,滕彦国,吴劲,等.PMF模型解析土壤重金属来源的不确定性[J].中国环境科学, 2020,40(2):716-725.Li J, Teng Y G, Wu J, et al.Uncertainty analysis of soil heavy metal source apportionment by PMF model[J].China Environmental Science, 2020,40(2):716-725.
[19]
张晟玮.济南市道路灰尘中重金属污染研究[D].西安:陕西师范大学, 2019.Zhang S W.Study on heavy metal pollution in road dust in Jinan[D].Xi'an:Shaanxi Normal University, 2019.
[20]
尹芳,封凯,尹翠景,等.青海典型工业区耕地土壤重金属评价及源解析[J].中国环境科学, 2021,41(11):5217-5226.Yin F, Feng K, Yin C J, et al.Evaluation and source analysis of heavy metal in cultivated soil around typical industrial district of Qinghai province[J].China Environmental Science, 2021,41(11):5217-5226.
[21]
沈宸宇,闫钰,于瑞莲,等.APCS-MLR结合PMF模型解析厦门杏林湾近郊流域沉积物金属来源[J].环境科学, 2022,43(5):2476-2488.Shen C Y, Yan Y, Yu R L, et al.Apcs-mlr combined with PMF model to analyze the source of sediment metals in the suburb of Xinglin Bay, Xiamen[J].Environmental Science, 2022,43(5):2476-2488.
[22]
Yin X L, Xie Z Y, Wang W P.Source Apportionment of Heavy Metals in Soil of Guangzhou:Comparison of Three Receptor Models[J].Journal of University of science and Technology of China, 2021, 51(11):813.
[23]
Wu J T, Margenot J, Xiao W.Source apportionment of soil heavy metals in fluvial islands, Anhui section of the lower Yangtze River:comparison of APCS-MLR and PMF[J].Journal of Soils and Sediments, 2020,20(9):3380-3393.
[24]
霍明珠.基于APCS-MLR的农田重金属污染源解析[D].天津:中国农业科学院, 2021.Huo M Z.Analysis of heavy metal pollution sources in farmland based on APCS-MLR[D].Chinese Academy of Agricultural Sciences, 2021.
[25]
Mohammad A H B, Shamal C K, M B, et al.Sources and ecological risk mapping of heavy metals in agricultural soils of Dhaka district employing SOM, PMF and GIS methods[J].Chemosphere, 2020,263:128339.
[26]
王成,赵艳萍,谢鸣捷.苏南典型工农业交错区土壤铅富集特征及源解析——基于PCA-PMF方法[J].中国环境科学, 2021,41(1):279-287.Wang C, Zhao Y P, Xie M J.Characteristics of lead enrichment in the soil from a typical peri-urban agricultural area of the southern Jiangsu and source appointment based on the PCA-PMF method[J].China Environmental Science, 2021,41(1):279-287.
[27]
向秀容,潘韬,吴绍洪,等.基于生态足迹的天山北坡经济带生态承载力评价与预测[J].地理研究, 2016,35(5):875-884.Xiang X R, Pan T, Wu S H, et al.Assessment and prediction of ecological carrying capacity for the Northern Slope Economic Belt of Tianshan Mountains[J].Geographic research, 2016,35(5):875-884.
[28]
袁婷婷,王志强,汪溪远,等.准东红沙泉矿区重金属生态风险缓冲区分析[J].土壤通报, 2020,51(1):227-223.Yuan T T, Wang Z Q, Wang X Y, et al.Buffer analysis of heavy metal ecological risk in the Hongshaquan mining area of East Junggar Basin[J].Chinese Journal of Soil Science, 2020,51(1):227-223.
[29]
Curi N, Brait CHH, Filho N, et al.Heavy Metals in Hair of Wild Canids from the Brazilian Cerrado[J].Biological Trace Element Research, 2012,147(1):97-102.
[30]
Zhao Y C, Xu X H, Huang B, et al.Using robust kriging and sequential Gaussian simulation to delineate the copper and lead-contaminated areas of a rapidly industrialized city in Yangtze River Delta, China.[J].Environmental Geology, 2007,52(7):1423-1433.
[31]
Mao Z G, Gu X H, Lu X M, et al.[Pollution distribution and potential ecological risk assessment of heavy metals in sediments from the different eastern dredging regions of Lake Taihu[J].Environmental sciences, 2014,35(1):186-193.
[32]
林丽钦.应用毒理学安全评价数据推算重金属毒性系数的探讨[C].2009重金属污染监测、风险评价及修复技术高级研讨会论文集, 2009:60-63.Lin L Q.Discussion on calculating the Toxicity Coefficient of heavy metals by using toxicological safety evaluation data[C].proceedings of 2009 Advanced Symposium on heavy metal pollution monitoring, risk assessment and remediation technology, 2009:60-63.
[33]
GB15618-2018土壤环境质量,农用地土壤污染风险管控标准[S].GB15618-2018 Soil environment quality, risk control standard for soil contamination of agricultural land[S].
[34]
比拉力·依明,阿不都艾尼·阿不里,师庆东,等.基于PMF模型的准东煤矿周围土壤重金属污染及来源解析[J].农业工程学报, 2019, 35(9):185-192.Bilal L, Abudugheni A, Shi Q D, et al.Pollution and source identification of heavy metals in surrounding soils of Eastern Junggar Coalfield based on PMF model[J].Transactions of the Chinese Society of Agricultural Engineering, 2019,35(9):185-192.
[35]
Sakizadeh M, Zhang C S.Source identification and contribution of land uses to the observed values of heavy metals in soil samples of the border between the Northern Ireland and Republic of Ireland by receptor models and redundancy analysis[J].Geoderma, 2021,404:115313.
[36]
Abliz A, Shi Q, Keyimu M, et al.Spatial distribution, source, and risk assessment of soil toxic metals in the coal-mining region of northwestern China[J].Arabian Journal of Geosciences, 2018,11(24):1-13.
[37]
申恒伦,张清源,王洪凯,等.临沂水源地水库沉积物重金属分布,来源及生态风险评价[J].长江流域资源与环境, 2021,30(5):1211-1220.Shen H L, Zhang Q Y, Wang H K, et al.Spatial distribution, source and ecological risk assessment of heavy metals in in water resource reservoirs of Linyi city[J].Resources and Environment of the Yangtze River Basin, 2021,30(5):1211-1220.
[38]
杨忠平,卢文喜,刘新荣,等.长春市城区表层土壤重金属污染来源解析[J].城市环境与城市生态, 2009,5:29-33.Yang Z P, Lu W X, Liu X R, et al.Sources Identification of heavy metals in urban soil of Changchun based on principal component analysis[J].Urban Environment and Erban Ecology, 2009,5:29-33.
[39]
Qu M, Li W, Zhang C, et al.Source apportionment of soil heavy metal Cd based on the combination of receptor model and geostatistics[J].China Environmental Science, 2013,33(5):854-860.
[40]
穆克热木·阿布利孜.浅谈作物土壤中6种重金属元素来源及检测[J].中国计量, 2015,12:85-87.Mukhermu A.Discussion on the sources and detection of six heavy metals in crop soil[J].China Metrology, 2015,12:85-87.
[41]
杨磊,熊黑刚.新疆准东煤田土壤重金属来源分析及风险评价[J].农业工程学报, 2018,34(15):273-281.Yang L, Xiong H G.Soil heavy metal sources analysis and risk evaluation of Zhundong coal mine in Xinjiang[J].Transactions of the Chinese Society of Agricultural Engineering, 2018,34(15):273-281.
[42]
刘巍,王涛,汪君,等.准东煤田露天矿区降尘、土壤重金属分布特征及生态风险评价[J].中国矿业, 2017,26(1):60-66.Liu W, Wang T, Wang J, et al.Distribution characteristics and ecological risk assessment of dust and soil heavy metals in open-pit mining area of Zhundong coalfield[J].China Mining Magazine, 2017, 26(1):60-66.
[43]
Zhang H W, Zhang F, Song J.Pollutant source, ecological and human health risks assessment of heavy metals in soils from coal mining areas in Xinjiang, China[J].Environmental Research, 2021,202:11702.
[44]
Liu P, Wu Q, Wang X, Hu W, et al.Spatiotemporal variation and sources of soil heavy metals along the lower reaches of Yangtze River, China[J].Chemosphere, 2022,291:132768.
[45]
邓霞,孙慧兰,杨余辉,等.伊宁市土壤中重金属污染评价及来源解析研究[J].环境污染与防治, 2020,42(2):223-226,237.Deng X, Sun H L, Yang Y H, et al.Pollution assessment and source apportionment of heavy metals in Yining City soil[J].Environmental Pollution & Control, 2020,42(2):223-226,237.
[46]
Lü J, Jiao W B, Qiu H Y, et al.Origin and spatial distribution of heavy metals and carcinogenic risk assessment in mining areas at You'xi County southeast China[J].Geoderma, 2018,310:99-106.
[47]
阿卜杜萨拉木·阿布都加帕尔,王宏卫,杨胜天,等.准东地区土壤重金属污染特征及来源分析[J].中国矿业, 2019,28(11):168-174.Abdulsalam A, Wang H W, Yang S T, et al.Pollution characteristics and source analysis of soil heavy metals in Zhundong area[J].China Mining Magazine, 2019,28(11):168-174.