Abstract:We present a case from Liangshui River catchment to investigate and quantify the reasons for these changes. Results indicate that the groundwater with poor quality are limited at depths less than 100m. Shallow groundwater and river samples plot on the same meteoric water line, which indicates river seepage is one of the important controlling factors for groundwater quality. Meanwhile, the hydrogeologic structure of the study area indicates the groundwater is primarily recharged from river seepage in upper alluvial-proluvial plain, which should be considered an important protected region. Antropogenic contamination added about 435mg/L both in the river and shallow groundwater. Although groundwater pollution is observed at shallow depths, the trend is likely in stable state indicated by the steady TDS values over the most recent seven years. In order to mitigate groundwater pollution, limits on pumping phreatic aquifer water and channel anti-seepage treatment measures are put forward for consideration.
李捷, 姜颖, 刘玉莲, 姜亚, 滕彦国. 凉水河流域地下水水化学特征和时空变化规律[J]. 中国环境科学, 2022, 42(4): 1847-1853.
LI Jie, JIANG Ying, LIU Yu-lian, JIANG Ya, TENG Yan-guo. Hydrolochemical characteristics and spatial-temporal variations of groundwater in the Liangshui River basin, Beijing. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(4): 1847-1853.
de Graaf I E M, Gleeson T, (Rens) van Beek L P H, et al. Environmental flow limits to global groundwater pumping[J]. Nature, 2019,574:90-94.
[2]
Döll P, Schmied H M, Schuh C, et al. Global-scale assessment of groundwater depletion and related groundwater abstractions:Combining hydrological modeling with information from well observations and GRACE satellites[J]. Water Resources Research, 2014,50:5698-5720.
[3]
Mark R M. The urban transformation of the developing world[J]. Science, 2008,319:761-764.
[4]
北京市水务局.北京市水资源公报2015~2018[Z]. http://www.bjwater.gov.cn/pub/bjwater/gzhd/. Beijing Water Authority. Beijing water resources Bulletin 2015~2018[Z]. http://www.bjwater.gov.cn/pub/bjwater/gzhd/.
[5]
刘记来.北京应急地下水源地开采极限研究[D]. 北京:中国科学院地质与地球物理研究所, 2010. Liu J L. Research on the exploitation limit of emergency groundwater source in Beijing[D]. Beijing:Institute of Geology and Geophysics, Chinese Academy of Sciences, 2012.
[6]
Aji K, Tang C, Song X, et al. Characteristics of chemistry and stable isotopes in groundwater of Chaobai and Yongding River basin, North China Plain[J]. Hydrological Processes, 2008,22:63-72.
[7]
李文鹏,郑跃军,郝爱兵.北京平原区地下水位预警初步研究[J]. 地学前缘, 2010,17(6):166-173. Li W P, Zheng Y J, Hao A B. A preliminary study of groundwater level pre-warning in Beijing Plain[J]. Earth Science Frontiers, 2010,17(6):166-173.
[8]
张安京.北京地下水[M]. 北京:中国大地出版社, 2008 Zhang A J. Groundwater in Beijing[M]. Beijing:Geological Publishing House, 2008.
[9]
张景华,范久达,李世君.南水北调进京后怀柔应急水源地地下水资源涵养研究[J]. 城市地质, 2015,10(2):17-20. Zhang J H, Fan J D, Li S J. Research on the groundwater resources conservation of Huairou emergency water source after the south-to- north water transfer into Beijing[J]. Urban Geology, 2015,10(2):17-20.
[10]
张大胜,吴劲,张世伟,等.基于数值模拟的北京密怀顺地区地下水资源调蓄研究[J]. 北京师范大学学报(自然科学版), 2019,55(5):627-634. Zhang D S, Wu J, Zhang S W, et al. Groundwater resources storage in Mihuanshun area of Beijing:a numerical simulation[J]. Journal of Beijing Normal University (Natural Science), 2019,55(5):627-634.
[11]
何亚平,李世君,李阳,等.南水北调水对潮白河地区回补情况及水位影响分析[J]. 北京水务, 2019,(3):21-26. He Y P, Li S J, Li Y, et al. Effect of south-to-north water transfer project on recharge and water level in Chaobai river area[J]. Beijing Water Authority, 2019,(3):21-26.
[12]
Li J, Tao T, Pang Z, et al. Identification of different moisture sources through isotopic monitoring during a storm event[J]. Journal of Hydrometeorology, 2015,16(4):1918-1927.DOI:10.1175/JHM-D-15-0005.1
[13]
林学钰,王焰新,地下水科学[M]. 北京:中国科学出版社, 2018. Lin X Y, Wang Y X. Groundwater science[M]. Beijing:China Science Publishing, 2018.
[14]
Chen J Y, Tang C Y, Sakura Y, et al. Nitrate pollution from agriculture in different hydrogeological zones of the regional groundwater flow system in the North China Plain[J]. Hydrogeol J, 2015,13:481-492.
[15]
Derby N E, Casey F X M, Knighton R E. Long-term observations of vadose zone and groundwater nitrate concentrations underirrigated agriculture[J]. Vadose Zone J, 2009,8:290-300.
[16]
Zhai Y Z, Wang J S, Huan H, et al. Characterizing the groundwater renewability and evolution of the strongly exploited aquifers of the North China Plain by major ions and environmental tracers[J]. J. Radioanal Nucl. Chem., 2013,296:1263-1274.
[17]
Zhang W L, Tian Z X, Zhang N, et al. Nitrate pollution of groundwater in northern China[J]. Agr. Ecosyst. Environ., 1996,59:223-231.
[18]
张玉铭,胡春胜,毛任钊,等.华北太行山前平原农田生态系统中氮、磷、钾循环与平衡研究[J]. 应用生态学报, 2003,14.11:1863-1867. Zhang Y M, Hu C S, Mao R Z, et al. Nitrogen, phosphorus and potassium cycling and balance in farmland ecosystem at the piedmont of Taihang[J]. Chinese J. Appl. Ecol., 2003,14:1863-1867.
[19]
付玉芹,雷玉平,郑力,等.不同施氮水平下深层土壤硝态氮淋失特征研究[J]. 中国农学通报, 2006,(6):245-248. Fu Y Q, Lei Y P, Zheng L. Nitrate leaching characteristics in deep soil layer for different fertilization methods[J]. Chinese Agr. Sci. Bull., 2006,22(6):245-248.
[20]
Guo Y H, Xu G Q, Gao Z Y, et al. Nitrate in groundwater and the unsaturated zone, Shijiazhuang City, China. In:Application of isotopes to the assessment of pollutant behaviour in the unsaturated zone for groundwater protection[J]. IAEA-TECDOC-1618,IAEA, 2019:31- 66.
[21]
张兆吉,费宇红,陈宗宇,等.华北平原地下水可持续利用调查评价[M]. 北京:地质出版社, 2009. Zhang Z J, Fei Y H, Chen Z Y, et al. Investigation and assessment of sustainable utilization of groundwater resources in the North China Plain[M]. Beijing:Geological Publishing House, 2009:471.
[22]
Zhai Y Z, Wang J S, Zhang Y, et al. Hydrochemical and isotopic investigation of atmospheric precipitation in Beijing[J]. China Science of the Total Environment, 2013,456-457:202-211.
[23]
周福,潘安君,楼春华.北京市县域内水环境治理研究[J]. 中国水利, 2001,(5):46. Zhou F, Pan A J, Lou C H. Research on water environment management in the county area of Beijing[J]. China Water Resources, 2001,(5):46.
[24]
赵刚,史蓉,庞博,等.快速城市化对产汇流影响的研究:以凉水河流域为例[J]. 水力发电学报, 2016,35(5):10. Impact of rapid urbanization on rainfall-runoff processes in urban catchment:Case study for Liangshui River basin[J]. Journal of Hydroelectric Engineering, 2016,35(5):10.
[25]
生态补水影响区域地下水动态周报(第三十三期)[Z]. 2019-11-29.北京市水文总站. Weekly report on groundwater dynamics in areas affected by ecological water replenishment (issue 33)[Z]. 2019-11-29. Beijing Hydrological Station.
[26]
Cheng Z S, Zhang Y B, Su C, et al. Chemical and isotopic Response to intensive Groundwater abstraction and its implications on aquifer sustainability in Shijiazhuang, China[J]. Journal of Earth Science, 2017,28(3):523-534.
[27]
李炳华,孟庆义,黄俊雄,等.地下水回补污染风险防控及生态修复技术[M]. 北京:化学工业出版社, 2021. Li B H, Meng Q Y, Huang J X, et al. Groundwater recharge pollution risk prevention and control and ecological restoration technology[M]. Beijing:Chemical Industry Press, 2021.
[28]
朱金峰,刘悦忆,章树安,等.地表水与地下水相互作用研究进展[J]. 中国环境科学, 2017,37(8):3002-3010. Zhu J F, Liu Y Y, Zhang S A, et al. Review on the research of surface water and groundwater interactions[J]. China Environmental Science, 2017,37(8):3002-3010.