Abstract:Based on the air pollution and meteorological observation data of 13cities in Jiangsu Province from 2013 to 2020, the distribution characteristics of PM2.5-O3 compound air pollutants and their relationship with meteorological conditions were analyzed. The results showed that the occurrence frequency of compound pollutants in Jiangsu were mainly composed of light pollution combinations, with more in the south, especially in the southeast. The compound air pollutants mainly appeared from April to October, with the highest concentration from afternoon to evening, and the average concentration of ozone during this period was higher than that of single ozone pollution; The average compound pollution days account for 15.7% of high ozone days, which was as high as 65.8% in 2014 and has significantly decreased since 2015. There was a positive correlation between PM2.5 and ozone concentrations in the warm season ozone pollution period, and a weak or negative correlation in the PM2.5 pollution period. The air temperature, relative humidity, wind speed and inversion conditions during the compound air pollution period are between single ozone pollution and PM2.5 pollution, mostly of them are below 4m/s and in the ENE-S wind direction range. Compared with the single ozone pollution, air temperature and wind speed are slightly lower, while relative humidity and inversion intensity are slightly higher during the compound air pollution. The main surface situations of compound pollution are the uniform pressure field and the front of low pressure (bottom), followed by the rear of high pressure into the sea and the bottom of high pressure. Through the backward trajectory cluster analysis, it is found that the compound pollution in Huaibei area mainly comes from the southeast coast to the local path, the central and southern cities mainly come from the surrounding areas and the southeast coastal area, and the southeastern cities mainly come from the short-distance transport and the Jiangsu-Anhui-Zhejiang border area.
严文莲, 刘端阳, 王磊, 李聪. 江苏PM2.5-O3复合污染特征及气象条件分析[J]. 中国环境科学, 2023, 43(10): 5098-5106.
YAN Wen-lian, LIU Duan-yang, WANG Lei, LI Cong. Analysis of characteristics and meteorological conditions of PM2.5-O3 compound pollution in Jiangsu province. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(10): 5098-5106.
张运江,雷若媛,崔世杰,等.2015~2020年我国主要城市PM2.5和O3污染时空变化趋势和影响因素[J]. 科学通报, 2022,67(18):2029-2042. Zhang Y J, Lei R Y, Cui S J, et al. Spatiotemporal trends and impact factors of PM2.5 and O3 pollution in major cities in China during 2015~2020[J]. Chinese Science Bulletin, 2022,67(18):2029-2042.
[2]
姜华,高健,李红,等.我国大气污染协同防控理论框架初探[J]. 环境科学研究, 2022,35(3):601-610. Jiang H, Gao J, Li H, et al. Preliminary Research on Theoretical Framework of Cooperative Control of Air Pollution in China[J]. Research of Environmental Sciences, 2022,35(3):601-610.
[3]
张鸿宇,王媛,卢亚灵,等.我国臭氧污染控制分区及其控制类型识别[J]. 中国环境科学, 2021,41(9):4051-4059. Zhang H Y, Wang Y, Lu Y L, et al. Identification of ozone pollution control zones and types in China[J]. China Environmental Science, 2021,41(9):4051-4059.
[4]
Ravishankara R A. Heterogeneous and multiphase chemistry in the troposphere[J]. Science, 1997,276(5315):1058-1065.
[5]
朱彤,尚静,赵德峰.大气复合污染及灰霾形成中非均相化学过程的作用[J]. 中国科学:化学, 2010,40(12):1731-1740. Zhu T, Shang J, Zhao D F. The roles of heterogeneous chemical processes in the formation of an air pollution complex and gray haze[J]. Science China Chemistry, 2010,40(12):1731-1740.
[6]
Kyung-Min Nam, Xu Zhang, Min Zhong, et al. Health effects of ozone and particulate matter pollution in China:a province-level CGE analysis[J]. The Annals of Regional Science, 2019,63(2):269-293.
[7]
牛笑笑,钟艳梅,杨璐,等.2015~2020年中国城市PM2.5-O3复合污染时空演变特征[J]. 环境科学, 2023,44(4):1830-1840. Niu X X, Zhong Y M, Yang L, et al. Spatiotemporal Evolution Characteristics of PM2.5-O3 Compound Pollution in Chinese Cities from 2015 to 2020[J]. Environmental Science, 2023,44(4):1830-1840.
[8]
花丛,江琪迟,茜元,等.我国中东部地区2015~2020年夏半年PM2.5和臭氧复合污染气象特征分析[J]. 环境科学研究, 2021, 35(3):650-658. Hua C, Jiang Q C, Qian Y, et al. Meteorological characteristics of PM2.5-O3 air combined pollution in central and eastern China in the summer half years of 2015~2020[J]. Research of Environmental Sciences, 2021,35(3):650-658.
[9]
Dai Huibin, Zhu Jia, Liao Hong, et al. Co-occurrence of ozone and PM2.5 pollution in the Yangtze River Delta over 2013~2019:Spatiotemporal distribution and meteorological conditions[J]. Atmospheric Research, 2021,249, https://doi.org/10.1016/j.atmosres. 2020.105363.
[10]
赵淑婷,王丽涛,齐孟姚,等.邯郸市PM2.5-O3复合污染特征及相互影响研究[J]. 环境科学学报, 2021,41(6):2250-2261. Zhao S T, Wang L T, Qi M Y, et al. Study on the characteristics and mutual influence of PM2.5-O3 complex pollution in Handan[J]. Acta Scientiae Circumstantiae, 2021,41(6):2250-2261.
[11]
刘南希,何成,刘晨曦,等.2015~2021年广州臭氧和PM2.5复合污染特征及天气分型研究[J]. 环境科学学报, 2023,43(1):42-53. Liu N X, He C, Liu C X, et al. Study on characteristics and weather classification of ozone and PM2.5 complex pollution in Guangzhou from 2015 to 2021[J]. Acta Scientiae Circumstantiae, 2023,43(1):42-53.
[12]
毛卓成,许建明,杨丹丹,等.上海地区PM2.5-O3复合污染特征及气象成因分析[J]. 中国环境科学, 2019,39(7):2730-2738. Mao Z C, Xu J M, Yang D D, et al. Analysis of characteristics and meteorological causes of PM2.5-O3 compound pollution in Shanghai[J]. China Environmental Science, 2019,39(7):2730-2738.
[13]
王占山,张大伟,李云婷,等.北京市夏季不同O3和PM2.5污染状况研究[J]. 环境科学, 2016,37(3):807-815. Wang Z S, Zhang D W, Li Y T, et al. Different Air Pollution Situations of O3 and PM2.5 During Summer in Beijing[J]. Environmental Science, 2016,37(3):807-815.
[14]
He Yuanping, Li Lei, Wang Haolin, et al. A cold front induced co-occurrence of O3 and PM2.5 pollution in a Pearl River Delta city:Temporal variation, vertical structure, and mechanism[J]. Environmental Pollution, 2022,306,DOI:10.1016/j.envpol.2022.119464.
[15]
赖安琪,陈晓阳,刘一鸣,等.珠江三角洲PM2.5和O3复合污染过程的数值模拟[J]. 中国环境科学, 2017,37(11):4022-4031. Lai A Q, Chen X Y, Liu Y M, et al. Numerical simulation of a complex pollution episode with high concentrations of PM2.5 and O3 over the Pearl River Delta region, China[J]. China Environmental Science, 2017,37(11):4022-4031.
[16]
刘可欣,卢苗苗,张裕芬,等.天津市夏秋季O3-PM2.5复合污染特征及气象成因分析[J]. 环境科学学报, 2021,41(9):3650-3662. Liu K X, Lu M M, Zhang Y F, et al. Analysis of characteristics and meteorological causes of O3-PM2.5 compound pollution in summer and autumn over Tianjin[J]. Acta Scientiae Circumstantiae, 2021, 41(9):3650-3662.
[17]
肖致美,徐虹,高璟贇,等.天津市PM2.5-O3复合污染特征及来源分析[J]. 环境科学, 2022,43(3):1140-1150. Xiao Z M, Xu H, Gao J Y, et al. Characteristics and Sources of PM2.5-O3 Compound Pollution in Tianjin[J]. Environmental Science, 2022,43(3):1140-1150.
[18]
卞锦婷,黄凌,李红丽,等.上海市PM2.5和臭氧复合污染期多路径减排效果评估[J]. 环境科学研究, 2023,36(2):314-324. Bian J T, Huang L, Li H L, et al. Evaluation of the effectiveness of multiple emission reduction pathways during a concurrent PM2.5 and ozone pollution in Shanghai[J]. Research of Environmental Sciences, 2023,36(2):314-324.
[19]
严文莲,刘端阳,康志明,等.江苏臭氧污染特征及其与气象因子的关系[J]. 气象科学, 2019,39(4):477-487. Yan W L, Liu D Y, Kang Z M, et al. The characteristics of ozone pollution and its relationship with meteorological factors in Jiangsu[J]. Journal of the Meteorological Sciences, 2019,39(4):477-487.
[20]
赵辉,郑友飞,吴晓云,等.江苏省大气复合污染特征与相关气象驱动[J]. 中国环境科学, 2018,38(8):2830-2839. Zhao H, Zhen Y F, Wu X Y, et al. Atmospheric compound pollution characteristics and the effects of meteorological factors in Jiangsu Province[J]. China Environmental Science, 2018,38(8):2830-2839.
[21]
Zhujun Dai, Duanyang Liu, Kun Yu, et.al. Meteorological variables and synoptic patterns associated with air pollutions in Eastern China during 2013~2018[J]. Int. J. Environ. Res. Public Health 2020,17, 2528,http://dx.doi.org/10.3390/ijerph17072528.
[22]
Lei Wang, Duanyang Liu, Wenlian Yan, et al. Spatio-temporal distribution, transport characteristics and synoptic patterns of ozone pollution near surface in Jiangsu province, China[J]. Atmospheric Pollution Research, 2022,13(12), https://doi.org/10.1016/j.apr.2022. 101616.
[23]
Mengwei Jia, Tianliang Zhao, Xinghong Cheng, et al. Inverse relations of PM2.5 and O3 in air compound pollution between cold and hot seasons over an urban area of East China[J]. Atmosphere, 2017,8(3), 59:https://doi.org/10.3390/atmos8030059.
[24]
邵平,辛金元,安俊琳,等.长三角工业区夏季近地层臭氧和颗粒物污染相互关系研究[J]. 大气科学, 2017,(3):618-628. Shao P, Xin J Y, An J L, et al. An analysis on the relationship between ground-level ozone and particulate matter in an industrial area in the Yangtze River Delta during summer time[J]. Chinese Journal of Atmospheric Sciences, 2017,(3):618-628.
[25]
HJ 633-2012环境空气质量指数(AQI)技术规定(试行)[S]. HJ633-2012 Technical regulation on ambient air quality index (ontrial)[S].
[26]
GB 3095-2012环境空气质量标准[S]. GB 3095-2012 Ambient air quality standards[S].
[27]
李宗恺,潘云仙,孙润桥.空气污染气象学原理及应用[M]. 北京:气象出版社, 1985:171. Li Z K, Pan Y X, Sun R Q. Principles and applications of air pollution meteorology[M]. Beijing:china meteorological press, 1985:171.
[28]
康志明,刘端阳,严文莲,等,著.江苏大气环境观测与预报技术研究[M]. 北京:气象出版社, 2022:79-85. Kang Z M, Liu D Y, Yan W L, et al. Research on atmospheric environment observation and forecast technology in Jiangsu Province[M]. Beijing:China Meteorological Press, 2022:79-85.
[29]
杭鑫,李亚春,张明明,等.基于遥感的秸秆焚烧对江苏省气溶胶光学厚度时空分布的影响研究[J]. 生态环境学报, 2017,26(1):111-118. Hang X, LI Y C, Zhang M M, et al. Study on the spatial and temporal distribution of AOD in Jiangsu Province influenced by straw burning based on satellite remote sensing[J]. Ecology and Environmental Sciences, 2017,26(1):111-118.
[30]
Jun Hu, Yichen Li, Tianliang Zhao, et al. An important mechanism of regional O3transport for summer smog over the Yangtze River Delta in eastern China[J]. Atmos. Chem. Phys., 2018,18:16239-16251.
[31]
Jia Mao, Lili Wang, Chuhan Lu, et al. Meteorological mechanism for a large-scale persistent severe zone pollution event over eastern China in 2017[J]. Journal of Environmental Science, 2020,92,10.1016/j.jes.2020.02.019.
[32]
王芃,朱盛强,张梦媛,等.大气氧化性及其对二次污染物形成的贡献[J]. 科学通报, 2022,67(18):2069-2078. Peng W, Zhu S Q, Zhang M Y, et al. Atmospheric oxidation capacity and its contribution to secondary pollutants formation[J]. Chinese Science Bulletin, 2022,67(18):2069-2078.
[33]
张宇静,赵天良,殷翀之,等.徐州市大气PM2.5与O3作用关系的季节变化[J]. 中国环境科学, 2019,39(6):2267-2272. Zhang Y J, Zhao T L, Yin C Z, et al. Seasonal variation of the relationship between surface PM2.5 and O3 concentrations in Xuzhou[J]. China Environmental Science, 2019,39(6):2267-2272.
[34]
张小曳,徐祥德,丁一汇,等.2013~2017年气象条件变化对中国重点地区PM2.5质量浓度下降的影响[J]. 中国科学:地球科学, 2020, 50(4):483-500. Zhang X Y, Xu X D, Ding Y H et al. The impact of meteorological changes from 2013 to 2017 on PM2.5 mass reduction in key regions in China[J]. Scientia Sinica (Terrae), 2020,50(4):483-500.
[35]
Liu Duanyang, Wenlian Yan, Zhiming Kang, et al. Boundary-layer features and regional transport process of an extreme haze pollution event in Nanjing, China[J]. Atmospheric Pollution Research, 2018, 9(6):1088-1099.
[36]
Cheng Gong, Hong Liao, Lin Zhang, et al. Persistent ozone pollution episodes in North China exacerbated by regional transport[J]. Environmental Pollution, 2020,265,115056,doi:10.1016/j.envpol.2020. 115056.