Spatial-temporal variation of ozone in Yangtze River Delta urban agglomeration in 2016
HUANG Xiao-gang1,2,3, ZHAO Jing-bo1,3
1. School of Geography and Tourism, Shaanxi Normal University, Xi'an 710119, China;
2. School of Geographical Sciences, Shanxi Normal University, Linfen 041004, China;
3. National Demonstration Center for Experimental Geography Education, Shaanxi Normal University, Xian 710119, China
Based on the air quality monitoring data collected in 40 cities in Yangtze River Delta urban agglomeration in 2016, this study presents the spatial-temporal variation of O3 concentration in Yangtze River Delta urban agglomeration in 2016 via spatial interpolation, spatial autocorrelation analysis, and hotspot analysis. It shows that:1) with an average O3 non-attainment rate of 8.8percent, O3 has become the second major source of pollutants following PM2.5; 2) the O3 concentration is decreasing from summer, spring, autumn to winter, the monthly changing of O3 concentration follows a pattern of "M", with two peaks in May and August respectively, and a valley in June due to the interruption of the plum rain season; 3) the O3 non-attainment mainly occurs from April to September, which contributes 98.1% to the O3 non-attainment days during the whole year with an average monthly rate of 17.3%; 4) the O3 concentration shows an a general decrease trend from the northeast to southwest, and the line connecting Hangzhou and Ma'anshan highlights the difference between the highly polluted area in the eastern side of the line, and the less polluted area in the western side of the line. The cities around the Taihu Lake suffer from severest pollution. In geologically speaking, the spatial distribution of O3 is approximately in accord with that of the economic development levels of Yangtze River Delta urban agglomeration; 5) the O3 concentration follows the spatial agglomeration law. Owing to the impact of southeast monsoon, the hotspots of O3 are primarily distributed in the eastern part of the Lake Cities from April to July, and later, move westward to Nanjing and its adjacent areas from August to September.
Fishman J, Crutzen P J. The origin of ozone in the troposphere[J]. Nature, 1978,274(5674):855-858.
[2]
Chen P, Quan J, Zhang Q, et al. Measurements of vertical and horizontal distributions of ozone over Beijing from 2007 to 2010[J]. Atmospheric Environment, 2013,74(2):37-44.
[3]
Ding A J, Wang T, Thouret V, et al. Tropospheric ozone climatology over Beijing:analysis of aircraft data from the MOZAIC program[J]. Atmospheric Chemistry & Physics, 2008,8(1):1-13.
[4]
Xu X, Lin W, Wang T, et al. Long-term trend of surface ozone at a regional background station in eastern China 1991-2006:enhanced variability[J]. Atmospheric Chemistry & Physics Discussions, 2008,8(1):2595-2607.
Jenkin M. Analysis of sources and partitioning of oxidant in the UK-Part 1:the NOx-dependence of annual mean concentrations of nitrogen dioxide and ozone[J]. Atmospheric Environment, 2004, 38(30):5117-5129.
[7]
Wang Y, Song Q, Frei M, et al. Effects of elevated ozone, carbon dioxide, and the combination of both on the grain quality of Chinese hybrid rice[J]. Environmental Pollution, 2014,189(12):9-17.
[8]
Stohl A, Forster C, Eckhardt S, et al. A backward modeling study of intercontinental pollution transport using aircraft measurements[J]. Journal of Geophysical Research, 2003,108(D12):ACH8-1-ACH8-18.
[9]
Lee J Y, Kim Y P. Source apportionment of the particulate PAHs at Seoul, Korea:impact of long range transport to a megacity[J]. Atmospheric Chemistry & Physics, 2007,7(13):3587-3596.
Minoura H. Some characteristics of surface ozone concentration observed in an urban atmosphere[J]. Atmospheric Research, 1999, 51(2):153-169.
[32]
Coleman L, Martin D, Varghese S, et al. Assessment of changing meteorology and emissions On air quality using a regional climate model:Impact on ozone[J]. Atmospheric Environment, 2013,69(69):198-210.
[33]
Finlayson B J, Pitts J N. Photochemistry of the Polluted Troposphere[J]. Science, 1976,192(4235):111-119.