华北平原和山区城市PM<sub>2.5</sub>和O<sub>3</sub>变化关系比较分析

摘要
图/表
参考文献
相关文章 (15)

全文: PDF (1834 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要利用2015~2019年环境监测数据，对比分析华北地区平原城市保定市和山区城市张家口市PM_2.5和O₃变化和相关关系.结果表明：保定市PM_2.5夏低冬高，O₃夏高冬低，日变化为午后单峰型，而张家口市PM_2.5浓度低，日变化幅度较弱，冬季O₃日变化为午后峰值和凌晨5：00左右弱峰值双峰型.张家口市冬季全天及春夏秋季夜间O₃浓度显著高于保定市，甚至夏季出现夜间O₃超标异常，最高浓度达到202μg/m³，反映了平原城市和清洁山区大气物理化学过程变化的影响.PM_2.5和O₃在4~9月为正相关，11~3月为负相关；保定市PM_2.5-O₃相关系数日变化呈单峰型，张家口市为双峰型变化，凌晨和午后各有一峰值，华北地区平原污染区和高山相对清洁区，大气复合污染物PM_2.5和O₃作用关系的日变化及季节特征具有明显差异.

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	罗悦函
	赵天良
	孟凯
	王宏
	龚康佳
	辛雨珊
	卢硕

关键词 ： PM_2.5, O₃, 大气复合污染, 相关性分析, 华北地区

Abstract：By using the environmental monitoring data from 2015 to 2019, This study presented a comparative analysis of PM_2.5 and O₃ changes and their relationships between the plain city Baoding (BD)and the mountainous city Zhangjiakou (ZJK) in North China. In BD, PM_2.5 concentrations were low in summer and high in winter, O₃ was high in summer and low in winter with a diurnal single-peak in afternoon, while in ZJK, the low PM_2.5 concentrations oscillated diurnally with a weaker amplitude. And the wintertime O₃ presented the bimodal peak in the afternoon and around 5:00 in the morning. The O₃ concentrations in ZJK in winter and during nighttime in spring, summer and autumn were significantly higher than those in BD. Even in summer, nighttime O₃ exceeded the air pollution standard, with the highest concentration reaching up to 202μg/m³, reflecting the distinct influence of changes in atmospheric physical and chemical processes in plain cities and clean mountains. PM_2.5 and O₃ were positively and negatively correlated respectively from April to September and from November to following March; the daily change of the correlation coefficient of PM_2.5-O₃ in BD is unimodal, and bimodal, each in the early morning and afternoon in ZJK The obvious differences were found in the diurnal and seasonal variations of the relationship between atmospheric compound pollutants PM_2.5 and O₃ in the plain polluted area and the relative clean mountainous area in North China.

Key words： PM_2.5 O₃ atmospheric compound pollution correlation analysis North China

收稿日期: 2021-02-18

PACS:

X51

基金资助:国家重点研发计划项目（2019YFC0214604）；国家自然科学基金项目（91744209）；河北省自然科学基金面上项目（D2020304038）

通讯作者: 赵天良,教授,tlzhao@nuist.edu.cn E-mail: tlzhao@nuist.edu.cn

作者简介: 罗悦函(1998-),女,河北保定人,硕士研究生,主要从事大气环境研究.

引用本文:

罗悦函, 赵天良, 孟凯, 王宏, 龚康佳, 辛雨珊, 卢硕. 华北平原和山区城市PM_2.5和O₃变化关系比较分析[J]. 中国环境科学, 2021, 41(9): 3981-3989. LUO Yue-han, ZHAO Tian-liang, MENG Kai, WANG Hong, GONG Kang-jia, XIN Yu-shan, LU Shuo. Comparative analysis of the relationship between PM_2.5 and O₃ in plain and mountainous cities in North China. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(9): 3981-3989.

链接本文:

http://www.zghjkx.com.cn/CN/ 或 http://www.zghjkx.com.cn/CN/Y2021/V41/I9/3981

[1]	Zhang Y H, Hu M, Zhong L J, et al. Regional integrated experiments on air quality over Pearl River Delta 2004(PRIDEPRD2004):Overview[J]. Atmospheric Environment, 2008,42:6157-6173.
[2]	中国大气臭氧污染防治蓝皮书[R]. 中国环境科学学会臭氧污染控制专业委员会, 2020.Blue Book of China's Atmospheric Ozone Pollution Prevention and Control[R]. Professional Committee of Ozone Pollution Control, Chinese Society of Environmental Sciences, 2020.
[3]	Shao M, Tang X, Zhang Y, et al. City clusters in China:Air and surface water pollution[J]. Frontiers in Ecology and the Environment, 2006, 4(7):353-361.
[4]	安俊琳,王跃思,孙扬,等.气象因素对北京臭氧的影响[J]. 生态环境学报, 2009,18(3):944-951.An J L, Wang Y S, Sun Y, et al. The influence of meteorological factors on ozone in Beijing[J]. Journal of Ecological Environment, 2009,18(3):944-951.
[5]	易睿,王亚林,张殷俊,等.长江三角洲地区城市臭氧污染特征与影响因素分析[J]. 环境科学学报, 2015,35(8):2370-2377.Yi R, Wang Y L, Zhang Y J, et al. Analysis of the characteristics and influencing factors of urban ozone pollution in the Yangtze River Delta[J]. Journal of Environmental Science, 2015,35(8):2370-2377.
[6]	刘建,吴兑,范绍佳,等.前体物与气象因子对珠江三角洲臭氧污染的影响[J]. 中国环境科学, 2017,37(3):813-820.Liu J, Wu D, Fan S J, et al. Effects of precursors and meteorological factors on ozone pollution in the Pearl River Delta[J]. China Environmental Science, 2017,37(3):813-820.
[7]	严茹莎,陈敏东,高庆先,等.北京夏季典型臭氧污染分布特征及影响因子[J]. 环境科学研究, 2013,26(1):43-49.Yan R S, Chen M D, Gao Q X, et al. Distribution characteristics and influencing factors of typical ozone pollution in summer in Beijing[J]. Environmental Science Research, 2013,26(1):43-49.
[8]	Saathoff H, Naumann K, Mohler O, et al. Temperature dependence of yields of secondary organic aerosols from the ozonolysis of pinene and limonene[J]. Atmospheric Chemistry and Physics, 2009,9(5):155-1577.
[9]	张宇静,赵天良,殷翀之,等.徐州市大气PM2.5与O3作用关系的季节变化[J]. 中国环境科学, 2019,39(6):2267-2272.Zhang Y J, Zhao T L, Yin C Z, et al. Seasonal changes in the relationship between atmospheric PM2.5 and O3 in Xuzhou City[J]. China Environmental Science, 2019,39(6):2267-2272.
[10]	毛卓成,许建明,杨丹丹,等.上海地区PM2.5-O3复合污染特征及气象成因分析[J]. 中国环境科学, 2019,39(7):2730-2738.Mao Z C, Xu J M, Yang D D, et al. Characteristics and meteorological causes analysis of PM2.5-O3 compound pollution in Shanghai area[J]. China Environmental Science, 2019,39(7):2730-2738.
[11]	Huang R J, Zhang Y, Bozzetti C, et al. High secondary aerosol contribution to particulate pollution during haze events in China[J]. Nature, 2014,514(7521):218-222.
[12]	李佳慧,刘红年,王学远.苏州城市颗粒物与臭氧相互作用的数值模拟研究[J]. 南京大学学报(自然科学), 2016,52(6):989-1000.Li J H, Liu H N, Wang X Y. Numerical simulation study on the interaction between urban particulate matter and ozone in Suzhou[J]. Journal of Nanjing University (Natural Science), 2016,52(6):989-1000.
[13]	Martin R V, Jacoh D J, Yantosca R M, et a1. Global and regional decreases in tropospheric oxidants from photochemical effects of aerosols[J]. Journal of Geophysical Research:Atmospheres, 2003, 108(D3).
[14]	孙金金,黄琳,龚康佳,等.2014~2019年北京和南京地区PM2.5和臭氧质量浓度相关性研究[J]. 南京信息工程大学学报(自然科学版), 2020,12(6):656-664.Sun J J, Huang L, Gong K J, et al. Research on the correlation between PM2.5 and ozone mass concentration in Beijing and Nanjing from 2014 to 2019[J]. Journal of Nanjing University of Information Technology (Natural Science Edition), 2020,12(6):656-664.
[15]	谢观雷,马永飞.淮安地区近地面臭氧与PM2.5等相关性[J]. 区域治理, 2019,(42):54-56.Xie G L, Ma Y F. The correlation between near-ground ozone and PM2.5 in Huaian area[J]. Regional Governance, 2019,(42):54-56.
[16]	Jia M W, Zhao T L, Cheng X H, et al. Inverse Relations of PM2.5 and O3 in Air Compound Pollution between Cold and Hot Seasons over an Urban Area of East China[J]. Atmosphere, 2017,8(3):59.
[17]	关清,郑有飞,赵辉,等.PM2.5及气象要素对乌鲁木齐市臭氧的影响[J]. 科学技术与工程, 2019,19(10):275-281.Guan Q, Zheng Y F, Zhao H, et al. The influence of PM2.5 and meteorological elements on ozone in Urumqi[J]. Science Technology and Engineering, 2019,19(10):275-281.
[18]	Meng K, Xu X, Xu X, et al. The causes of "vulnerable regions" to air pollution in winter in the Beijing-Tianjin-Hebei region:a topographic-meteorological impact model based on adaptive emission constraint technique[J]. Atmosphere-Basel. 2019,10(11):719.
[19]	孟捷,马倩,刘猛,等.保定市环境质量年报(2013年度)[R]. 保定:保定市环境保护局, 2014.Meng J, Ma Q, Liu M, et al. Baoding environmental quality annual report (2013)[R]. Baoding:Baoding Environmental Protection Bureau, 2014.
[20]	佟霁坤,陈海婴,张越.保定市臭氧污染时空变化特征研究分析[J]. 环境科学与管理, 2016,41(4):30-32.Tong J K, Chen H Y, Zhang Y. Research and analysis on the characteristics of temporal and spatial changes of ozone pollution in Baoding City[J]. Environmental Science and Management, 2016, 41(4):30-32.
[21]	孟凯,程兴宏,徐祥德,等.基于CMAQ源同化反演方法的京津冀局地污染源动态变化特征模拟研究[J]. 环境科学学报, 2017,37(1):52-60.Meng K, Cheng X H, Xu X D, et al. Simulation study on dynamic change characteristics of Beijing-Tianjin-Hebei local pollution sources based on CMAQ source assimilation inversion method[J]. Journal of Environmental Science. 2017,37(1):52-60.
[22]	Meng K, Xu X, Cheng X, et al. Spatio-temporal variations in SO2 and NO2 emissions caused by heating over the Beijing-Tianjin-Hebei region constrained by an adaptive nudging method with OMI data[J]. Science of The Total Environment. 2018,642:543-552.
[23]	王冠岚,薛建军,张建忠,等.2014年京津冀空气污染时空分布特征及主要成因分析[J]. 气象与环境科学, 2016,39(1):34-42.Wang G L, Xue J J, Zhang J Z, et al. Spatial and temporal distribution characteristics and main causes of air pollution in Beijing-Tianjin-Hebei in 2014[J]. Meteorological and Environmental Science, 2016, 39(1):34-42.
[24]	GB 3095-2012环境空气质量标准[S].GB 3095-2012 Ambient Air Quality Standard[S].
[25]	王彦超,蒋春来,贺晋瑜,等.京津冀大气污染传输通道城市燃煤大气污染减排潜力[J]. 中国环境科学, 2018,38(7):2401-2405.Wang Y C, Jiang C L, He J Y, et al. Beijing-Tianjin-Hebei air pollution transmission channel urban coal-burning air pollution reduction potential[J]. China Environmental Science, 2018,38(7):2401-2405.
[26]	刀谞,吉东生,张显,等.京津冀及周边地区采暖季PM2.5化学组分变化特征[J]. 环境科学研究, 2021,34(1):1-10.Dao D, Ji D S, Zhang X, et al. Variation characteristics of PM2.5 chemical composition during heating season in Beijing-Tianjin-Hebei and surrounding areas[J]. Environmental Science Research, 2021, 34(1):1-10.
[27]	孙丹丹,杨书运,王体健,等.长三角地区城市O3和PM2.5污染特征及影响因素分析[J]. 气象科学, 2019,39(2):164-177.Sun D D, Yang S Y, Wang T J, et al. Analysis of O3 and PM2.5 pollution characteristics and influencing factors in cities in the Yangtze River Delta[J]. Meteorological Science, 2019,39(2):164-177.
[28]	Li K, Chen L, Ying F, et al. Meteorological and chemical impacts on ozone formation:A case study in Hangzhou, China[J]. Atmospheric Research, 2017,196:40-52.
[29]	王闯,王帅,杨碧波,等.气象条件对沈阳市环境空气臭氧浓度影响研究[J]. 中国环境监测, 2015,31(3):32-37.Wang C, Wang S, Yang B B, et al. Study on the influence of meteorological conditions on the ozone concentration of ambient air in Shenyang[J]. China Environmental Monitoring, 2015,31(3):32-37.
[30]	王玫,郑有飞,柳艳菊,等.京津冀臭氧变化特征及与气象要素的关系[J]. 中国环境科学, 2019,39(7):2689-2698.Wang M, Zheng Y F, Liu Y J, et al. The characteristics of ozone changes in the Beijing-Tianjin-Hebei region and its relationship with meteorological elements[J]. China Environmental Science, 2019, 39(7):2689-2698.
[31]	梁丽思,靖娟利,王安娜,等.2014~2019年冬季京津冀地区PM2.5质量浓度时空分布特征[J]. 桂林理工大学学报, 2020,40(4):788-797.Liang L S, Jing J L, Wang A N, et al. Temporal and spatial distribution characteristics of PM2.5 mass concentration in the Beijing-Tianjin-Hebei region in the winter of 2014~2019[J]. Journal of Guilin University of Technology, 2020,40(4):788-797.
[32]	邵平,王莉莉,安俊琳,等.河北张家口市大气污染观测研究[J]. 环境科学, 2012,33(8):2538-2550.Shao P, Wang L L, An J L, et al. Air pollution observation and research in Zhangjiakou City, Hebei[J]. Environmental Science, 2012,33(8):2538-2550.
[33]	胡洛铭,李奕璇,施念邡,等.京津冀地区臭氧浓度时空变化特征[J]. 环境科学与技术, 2019,42(11):1-7.Hu L M, Li Y X, Shi N F, et al. Temporal and spatial variation characteristics of ozone concentration in the Beijing-Tianjin-Hebei region[J]. Environmental Science and Technology, 2019,42(11):1-7.
[34]	王占山,李云婷,陈添,等.北京城区臭氧日变化特征及与前体物的相关性分析[J]. 中国环境科学, 2014,34(12):3001-3008.Wang Z S, Li Y T, Chen T, et al. Characteristics of diurnal changes of ozone in Beijing urban area and correlation analysis with precursors[J]. China Environmental Science, 2014,34(12):3001-3008.
[35]	Cheung V T F, Wang T.Observational study of ozone pollution at a rural site in the Yangtze Delta of China[J]. Atmospheric Environment, 2001,35(29):4947-4958.
[36]	杨少波,曹念文,范广强,等.夜间近地表臭氧观测[J]. 中国环境科学, 2019,39(11):4494-4501.Yang S B, Cao N W, Fan G Q, et al. Observation of near-surface ozone at night[J]. China Environmental Science, 2019,39(11):4494-4501.
[37]	宋从波,李瑞芃,何建军,等.河北廊坊市区大气中NO、NO2和O3污染特征研究[J]. 中国环境科学, 2016,36(10):2903-2912.Song C B, Li R P, He J J, et al. Study on the pollution characteristics of NO, NO2 and O3 in the atmosphere in Langfang City, Hebei Province[J]. China Environmental Science, 2016,36(10):2903-2912.
[38]	杨俊益.京津冀区域本底大气污染物浓度的变化特征研究[D]. 南京:南京信息工程大学, 2012.Yang J Y. Research on the change characteristics of background air pollutant concentration in the Beijing-Tianjin-Hebei region[D]. Nanjing:Nanjing University of Information Science and Technology, 2012.
[39]	贾春晖,窦晶晶,苗世光,等.延庆-张家口地区复杂地形冬季山谷风特征分析[J]. 气象学报, 2019,77(3):475-488.Jia C H, Dou J J, Miao S G, et al. Analysis of winter valley wind characteristics of complex terrain in Yanqing-Zhangjiakou area[J]. Journal of Meteorology, 2019,77(3):475-488.
[40]	金祺,银燕,谭稳.黄山地区复杂地形下污染气体输送过程的数值模拟[J]. 大气科学学报, 2012,35(6):680-688.Jin Q, Yin Y, Tan W. Numerical simulation of polluted gas transportation process under complex terrain in Huangshan area[J]. Journal of Atmospheric Sciences, 2012,35(6):680-688.
[41]	张凯.四川盆地西部边缘地区大气边界层垂直结构及对大气污染影响研究[D]. 南京:南京信息工程大学, 2020.Zhang K. Research on the vertical structure of the atmospheric boundary layer and its influence on air pollution in the western marginal area of the Sichuan Basin[D]. Nanjing:Nanjing University of Information Science and Technology, 2020.
[42]	Lu K D, Guo S, Tan Z F, et al. Exploring atmospheric free-radical chemistry in China:the self-cleansing capacity and the formation of secondary air pollution[J]. National Science Review, 2019,6(3):579-594.
[43]	李红丽,王杨君,黄凌,等.中国典型城市臭氧与二次气溶胶的协同增长作用分析[J]. 环境科学学报, 2020,40(12):4368-4379.Li H L, Wang Y J, Huang L, et al. Analysis on the synergistic growth of ozone and secondary aerosols in typical cities in China[J]. Journal of Environmental Science, 2020,40(12):4368-4379.