Abstract:Conventional permeable reactive barrier (PRB) for ground water remediation might be inapplicable for a wide pollution plume because constructing a large PRB underground might be too expensive, as the costs of excavation, remediation material and installation increase greatly with the scale. This investigation proposed a novel approach of convergent flow permeable reactive barrier (CF-PRB). In CF-PRB, some decompression wells were installed at the upstream of PRB to converge the groundwater flow to wells. As a result, the plume was converged to a relatively small scale. Partially penetrating decompression wells installed could also extract the deeply-bearing polluted water, making the PRB available to remediate deeper pollution. The convergent polluted ground water was conveyed to the PRB through water pipelines and distributed at the buffer slot in front of the PRB. The slot was distributed evenly the polluted water along the PRB so that the water could flow through the PRB homogeneously. CF-PRB could make the PRB design be determined primarily by flow rate and average pollutant concentrations, independent to the plume scale. Analytical solutions of well flow were used to calibrate the initial parameters in CF-PRB, and then MODFLOW numerical simulation was adopted for optimization. In MODFLOW simulation, parameters such as well radius, number of wells, spacings between wells and the distances from wells to PRB were tested to analyze their impacts on CF-PRB. Results showed that CF-PRB approach could make the upstream groundwater flow convergently to the decompression wells, resulting in the reduction of reactive barrier length by 50%. CF-PRB approach can significantly reduce the PRB scales and can therefore be used to remediate the polluted groundwater with a large plume width and depth.
罗兴申, 郑凯旋, 许芳铭, 王洪涛. 数值模拟减压集流式可渗透反应墙技术修复地下水[J]. 中国环境科学, 2021, 41(12): 5728-5735.
LUO Xing-shen, ZHENG Kai-xuan, XU Fang-ming, WANG Hong-tao. Numerical simulation for remediation of polluted ground water by a novel convergent flow permeable reactive barrier. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(12): 5728-5735.
Cunningham J A, Reinhard M. Injection-extraction treatment well pairs: an alternative to permeable reactive barriers[J]. Ground Water, 2002,40(6):599-607.
[4]
HJ 25.6-2019 污染地块地下水修复与风险管控技术导则[S]. HJ 25.6-2019 Technical guideline for groundwater remediation and risk control of contaminated sites[S].
[5]
Craig J R, Rabideau A J, Suribhatla R. Analytical expressions for the hydraulic design of continuous permeable reactive barriers[J]. Advances in Water Resources, 2006,29(1):99-111.
[6]
Powell R M, Blowes D W, Gillham R W, et al. Permeable reactive barrier technologies for contaminant remediation[R]. Washington, DC: EPA Office of Solid Waste and Emergency Responses, 1998.
[7]
王泓泉.污染地下水可渗透反应墙(PRB)技术研究进展[J]. 环境工程技术学报, 2020,10(2):251-259. Wang H Q. Study on permeable reactive barrier technology for the remediation of polluted groundwater[J]. Journal of Environmental Engineering Technology, 2020,10(2):251-259.
[8]
Alok K T, Meththika V, Diganta B D, et al. A review on design, material selection,mechanism, and modelling of permeable reactive barrier for community-scale groundwater treatment[J]. Environmental Technology & Innovation, 2020,19:1-20.
[9]
李志红,王广才,史浙明,等.渗透反应格栅技术综述:填充材料实验研究、修复技术实例和系统运行寿命[J]. 环境化学, 2017,36(2):316- 327. Li Z H, Wang G C, Shi Z M, et al. Review of permeable reactive barrier technology: The experimental study of filling materials,the example of remediation technology,and the longevity of the system[J]. Environmental Chemistry, 2017,36(2):316-327.
[10]
Obiri-Nyarko F, Grajales-Mesa S J, Malina G. An overview of permeable reactive barriers for in situ sustainable groundwater remediation[J]. Chemosphere, 2014,111:243-259.
[11]
Phillips D H, Nooten T V, Bastiaens L, et al. Ten year performance evaluation of a field-ccale zero-valent iron permeable reactive barrier installed to remediate trichloroethene contaminated groundwater[J]. Environmental Science & Technology, 2010,44(10):3861-3869.
[12]
Udayagee K, Ken K, Saito T, et al. Evaluation of applicability of filling materials in permeable reactive barrier(PRB) system to remediate groundwater contaminated with Cd and Pb at open solid waste dump sites[J]. Process Safety and Environmental Protection, 2018,120:118-127.
[13]
Fatemeh G, Hamid M, Mahmoud S, et al. Application of encapsulated magnesium peroxide(MgO2) nanoparticles in permeable reactive barrier (PRB) for naphthalene and toluene bioremediation from groundwater[J]. Science of the Total Environment, 2019,655:633- 640.
[14]
Huang Y J, Qiang Z, Liang H, et al. Column study of enhanced Cr(Ⅵ) removal and removal mechanisms by Sporosarcina saromensis W5assisted bio-permeable reactive barrier[J]. Journal of Hazardous Materials, 2021,405:1-11.
[15]
Saeideh T, Zahra R, Ali E, et al. Adsorption of cadmium using modified zeolite-supported nanoscale zero-valent iron composites as a reactive material for PRBs[J]. Science of the Total Environment, 2020,736:1-13.
[16]
Zhou H, Liu Z, Li X, et al. Remediation of lead(II)-contaminated soil using electrokinetics assisted by permeable reactive barrier with different filling materials[J]. Journal of Hazardous Materials, 2020, 408:1-9.
[17]
袁梦姣,王晓慧,赵芳,等.零价铁与微生物耦合修复地下水的研究进展[J]. 中国环境科学, 2021,41(3):1119-1131. Yuan M J, Wang X H, Zhao F, et al. Research progress of zero- valent-iron microbial coupled system in remediating contaminated groundwater[J]. China Environmental Science, 2021,41(3):1119-1131.
[18]
朱亚光,杜青青,夏雪莲,等.石墨烯类材料在水处理和地下水修复中的应用[J]. 中国环境科学, 2018,38(1):210-221. Zhu Y G, Du Q Q, Xia X L, et al. Application of graphene-based materials in water treatment and groundwater remediation[J]. China Environmental Science, 2018,38(1):210-221.
[19]
窦文龙,毛巧乐,梁丽萍.可渗透反应墙的研究与发展现状[J]. 四川环境, 2020,39(1):207-214. Dou W L, Mao Q L, Liang L P. Research and development status of permeable reactive barrier[J]. Sichuan Environment, 2020,39(1):207-214.
[20]
Dan Z, Yan L, Zhang Y, et al. Column test-based optimization of the permeable reactive barrier(PRB) technique for remediating groundwater contaminated by landfill leachates[J]. Journal of Contaminant Hydrology, 2014,168(11):1-16.
[21]
潘煜,孙力平,陈星宇,等.CMC改性纳米Fe/Cu双金属模拟PRB去除地下水中2,4-二氯苯酚[J]. 中国环境科学, 2019,39(9):3789- 3796. Pan Y, Sun L P, Chen X Y, et al. Removal of 2,4-dichlorophenol from groundwater by PRB simulated by CMC modified nanoscale Fe/Cu bimetal[J]. China Environmental Science, 2019,39(9):3789-3796.
[22]
Halim A A, Aziz H A, Johari M A M, et al. Comparison study of ammonia and COD adsorption on zeolite, activated carbon and composite materials in landfill leachate treatment[J]. Desalination, 2010,262(1-3):31-35.
[23]
江林.可渗透反应墙渗透性能变化分析与数值模拟及防治措施的研究[D]. 芜湖:安徽工程大学, 2015. Jiang L. Study on the analysis and numerical simulation of permeability quotient and preventable measures for blocking in permeable reactive barrier[D]. WuHu: Anhui Polytechnic University, 2015.
[24]
Grajales-Mesa S J, Malina G, Kret E, et al. Designing a permeable reactive barrier to treat TCE contaminated groundwater: numerical modelling[J]. Tecnologia y Ciencias del Agua, 2020,11(3):78-106.
[25]
马志飞,廉新颖,张进保,等.零价铁PRB修复2,4-DNT污染地下水模拟研究[J]. 中国环境科学, 2013,33(5):814-820. Ma Z F, Lian X Y, Zhang J B, et al. Simulation on remediation of 2,4-DNT in groundwater by zero-valent iron[J]. China Environmental Science, 2013,33(5):814-820.
[26]
邓红卫,贺威,胡建华,周科平.Fe~0-PRB修复地下水硝酸盐污染数值模拟[J]. 中国环境科学, 2015,35(8):2375-2381. Deng H W, He W, Hu J H, et al. Numerical simulation of Fe0-PRB in rehabilitating groundwater contaminated by nitrate[J]. China Environmental Science, 2015,35(8):2375-2381.
[27]
Medawela S,Indraratna B. Computational modelling to predict the longevity of a permeable reactive barrier in an acidic floodplain[J]. Computers and Geotechnics, 2020,124:1-17.
[28]
Obiri-Nyarko F, Kwiatkowska-Malina J, Malina G, et al. Geochemical modelling for predicting the long-term performance of zeolite-PRB to treat lead contaminated groundwater[J]. Journal of Contaminant Hydrology, 2015,177-178(6/7):76-84.
[29]
Indraratna B, Medawela S, Rowe R K, et al. Biogeochemical clogging of permeable reactive barriers in acid-sulfate soil floodplain[J]. Journal of Geotechnical and Geoenvironmental Engineering, 2020, 146(5):1-16.
[30]
Li S P, Li W P, Chen H H, et al. Effects of calcium ion and pH on the adsorption/regeneration process by activated carbon permeable reactive barriers[J]. Rsc Advances, 2018,8(30):16834-16841.
[31]
Falciglia P P, Gagliano E, Brancato V, et al. Microwave based regenerating permeable reactive barriers(MW-PRBs):Proof of concept and application for Cs removal[J]. Chemosphere, 2020,251:1-11.
[32]
薛禹群,吴吉春.地下水动力学[M]. 北京:地质出版社, 2010:94-96. Xue Y Q, Wu J C. Groundwater Hydraulics[M]. Beijing: Geological Publishing House, 2010:94-96.
[33]
王洪涛.多孔介质污染物迁移动力学[M]. 北京:高等教育出版社, 2008:140-145. Wang H T. Dynamics of fluid flow and contaminant transport in porous media[M]. Beijing: Higher Education Press, 2008:140-145.
[34]
夏强,王旭升,鲁林波.利用MODFLOW模拟井流的误差特征[J]. 工程勘察, 2007,(10):29-32,37. Xia Q, Wang X S, Lu L B. Characteristics of Error in Numerical Modeling of Well Flow with MODFLOW[J]. Geotechnical Investigation & Surveying, 2007,(10):29-32,37.
[35]
陈崇希,唐仲华.地下水流动问题数值方法[M]. 武汉:中国地质大学出版社, 1990:41-77. Chen C X, Tang Z H. Numerical method of groundwater flow[M]. Wuhan: China University of Geosciences Press, 1990:41-77.
[36]
吴持恭.水力学(第4版)[M]. 北京:高等教育出版社, 2008:148-150. Wu C G. Hydraulics(the 4th edition)[M]. Beijing: Higher Education Press, 2008:148-150.