In this study, phosphoric acid was used as an activator to modify chaff-derived biochar for the obtainment of functional chaff-derived biochar(fCBC), which was rich in active functional groups. Then fCBC was utilized as a carrier material for manganese sulfide (MnS-fCBC), which could be applied to effectively remove cadmium(Cd) in aqueous solution. The effects of initial Cd concentration, initial pH value and dosage of MnS-fCBC on the adsorption capability were systematically evaluated. The MnS-fCBC showed an excellent adsorption performance of Cd. Under the condition of the intial Cd concentration was 200mg/L, solution pH value was 6, adsorbents dosage was 1g/L, the maximum adsorption capacity of MnS-fCBC came to 145.15mg/L. The adsorption reaction was significantly affected by the pH value, and a better removal performance could be obtained under weakly acidic conditions. To characterize the structure of MnS-fCBC, X-ray diffractometer (XRD) and Raman spectroscopy (Raman) was applied, and the removal mechanism of Cd was discussed by batch experiments and characterization results, showing that surface complexation and chemical precipitation were the main mechanisms of Cd removal. Recycle tests showed that the material still had significant Cd removal capability for five successive 24h adsorption-desorption cycles, which showed that MnS-fCBC had high reusability. Therefore, MnS-fCBC could be used as an effective Cd adsorbent for the treatment of Cd-containing wastewater.
熊伟,唐恒.改性花生壳对重金属镉吸附性能的研究[J]. 建材与装饰, 2016,0(25):145-146. Xiong W, Tang H. Study on adsorption properties of modified peanut shell to cadmium[J]. Construction material and decoration, 2016,0(25):145-146.
[2]
蔡键.富磷改性毛竹生物炭对水体中重金属镉的吸附研究[D]. 武汉:华中科技大学, 2018. Cai J. The study of adsorption of cadmium in aqueous solution by phosphate-modified bamboo biochar[D]. Wuhan:Huazhong university of science and technology, 2018.
[3]
Liu S, Li J, Xu S, et al. A modified method for enhancing adsorption capability of banana pseudostem biochar towards methylene blue at low temperature[J]. Bioresource Technology. 2019,282:48-55.
[4]
黄志平,王韶宾,周蕾,等.含镉废水处理方法研究[C]. 银川:中国化学会, 2015:141-145. Huang Z P, Wang S B, Zhou L, et al. Study on treatment of waterwater containing cadmium[C]. Yinchuan:Chinese chemical society, 2015:141-145.
[5]
Xie X L, Gao H L, Luo X, et al. Polyethyleneimine modified activated carbon for adsorption of Cd(II) in aqueous solution[J]. Journal of Environmental Chemical Engineering, 2019,7(3):103183.
[6]
Ren B, Wang K, Zhang B S, et al. Adsorption behavior of PAMAM dendrimers functionalized silica for Cd(II) from aqueous solution:Experimental and theoretical calculation[J]. Journal of the Taiwan Institute of Chemical Engineers, 2019,101:80-91.
[7]
Wu J W, Wang T, Zhang Y S, et al. The distribution of Pb(II)/Cd(II) adsorption mechanisms on biochars from aqueous solution:Considering the increased oxygen functional groups by HCl treatment[J]. Bioresource Technology, 2019,291:121859.
[8]
Li Y J, Yang Z M, Chen Y C, et al. Adsorption, recovery, and regeneration of Cd by magnetic phosphate nanoparticles.[J]. Environmental science and pollution research international, 2019, 26(17):17321-17332.
[9]
王靖宜,王丽,张文龙,等.生物炭基复合材料制备及其对水体特征污染物的吸附性能[J]. 化工进展, 2019,38(8):3838-3851. Wang J Y, Wang L, Zhang W L, et al. Preparation of biochar-based composites and their adsorption performances for characteristic in waterwater[J]. Chemical industry and engineering progress, 2019, 38(8):3838-3851.
[10]
肖琴,刘有才,曹占芳,等.生物炭吸附废水中重金属离子的研究进展[J]. 环境科技, 2019,32(1):68-73. Xiao Q, Liu Y C, Cao Z F, et al. Research progress on the adsorption of heavy metals from wasterwater by biochar[J]. Environmental science and technology, 2019,32(1):68-73.
[11]
Guo Y, Tang W, Huang Z Q, et al. Mechanism of Cu(II) adsorption inhibition on biochar by its aging process[J]. Journal of Environmental Sciences. 2014,26(10):2123-2130.
[12]
Liu N, Sun Z T, Wu Z C. Adsorption Characteristics of Ammonium Nitrogen by Biochar from Diverse Origins in Water[J]. Advanced materials research. 2013,2224:305-312.
[13]
Zhang Z, He S, Zhang Y L, et al. Spectroscopic investigation of Cu2+, Pb2+ and Cd2+ adsorption behaviors by chitosan-coated argillaceous limestone:Competition and mechanisms[J]. Environmental Pollution. 2019,254:112938.
[14]
Asadullah, Kaewsichan L, Tohdee K. Adsorption of hexavalent chromium onto alkali modified biochar derived from lepironia articulata:Kinetic, equilibrium and thermodynamic study[J]. Water environment research, 2019,91(11):1433-1446.
[15]
Shang L, Xu H, Huang S B, et al. Adsorption of Ammonium in Aqueous Solutions by the Modified Biochar and its Application as an Effective N-Fertilizer[J]. Water, air, & soil pollution, 2018,229(10):1-15.
[16]
赵天赐,周世真,马小龙,等.负载铁锰氧化物的玉米芯炭对Pb2+的吸附作用[J]. 环境科学学报, 2019,39(9):2997-3009. Zhao T C, Zhou S Z, Ma X L, et al. Study on the adsorption of Pb2+ by MnFeOx-loaded corncob biochar[J]. Acta scientiae circumstantiae, 2019,39(9):2997-3009.
[17]
陈坦,周泽宇,孟瑞红,等.改性污泥基生物炭的性质与重金属吸附效果[J]. 环境科学, 2019,40(4):1842-1848. Chen T, Zhou Z Y, Meng R H, et al. Characteristics and heavy metal adsorption performance of sewage sludge-derived biochar from co-pyrolysis with transition metals[J]. Environmental science, 2019, 40(4):1842-1848.
[18]
Ahmed M B, Johir M A H, Khourshed C, et al. Sorptive removal of dissolved organic matter in biologically-treated effluent by functionalized biochar and carbon nanotubes:Importance of sorbent functionality[J]. Bioresource Technology, 2018,269:9-17.
[19]
GB11906-89水质锰的测定-高锰酸钾分光光度法[S]. GB11906-89 Water quality-determination manganese-potassium periodate spectrophotometric method[S].
[20]
Martin D P, Seiter J M, Lafferty B J, et al. Exploring the ability of cations to facilitate binding between inorganic oxyanions and humic acid[J]. Chemosphere, 2017,166:192-196.
[21]
Zhu S S, Huang X C, Wang L, et al. Enhanced hexavalent chromium removal performance and stabilization by magnetic iron nanoparticles assisted biochar in aqueous solution:Mechanisms and application potential[J]. Chemosphere, 2018,207:50-59.
[22]
Wu J Z, Huang D, Liu X M, et al. Remediation of As(III) and Cd(II) co-contamination and its mechanism in aqueous systems by a novel calcium-based magnetic biochar[J]. Journal of Hazardous Materials, 2018,348:10-19.
[23]
Siswoyo E, Mihara Y, Tanaka S. Determination of key components and adsorption capacity of a low cost adsorbent based on sludge of drinking water treatment plant to adsorb cadmium ion in water[J]. Applied Clay Science, 2014,97-98:146-152.
[24]
Chen Z L, Zhang J Q, Huang L, et al. Removal of Cd and Pb with biochar made from dairy manure at low temperature[J]. Journal of Integrative Agriculture, 2019,18(1):201-210.
[25]
Eleonora S, Jan K. Comparison of adsorption of Cd(II) and Pb(II) ions on pure and chemically modified fly ashes[J]. Chemical & Process Engineering. 2016,37(2):215-234.
[26]
Wang H Y, Chen P, Zhu Y G, et al. Simultaneous adsorption and immobilization of As and Cd by birnessite-loaded biochar in water and soil.[J]. Environmental science and pollution research international, 2019,26(9):8575-8584.
[27]
Jing F Q, Sohi S P, Liu Y Y, et al. Insight into mechanism of aged biochar for adsorption of PAEs:Reciprocal effects of ageing and coexisting Cd2+[J]. Environmental Pollution, 2018,242:1098-1107.
[28]
Langmuir I. THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM.[J]. Journal of Chemical Physics, 2015,40(12):1361-1403.
[29]
Yin R L, Guo W Q, Wang H Z, et al. Singlet oxygen-dominated peroxydisulfate activation by sludge-derived biochar for sulfamethoxazole degradation through a nonradical oxidation pathway:Performance and mechanism[J]. Chemical Engineering Journal, 2019,357:589-599.
[30]
Zhang X, Lv L, Qin Y Z, et al. Removal of aqueous Cr(VI) by a magnetic biochar derived from Melia azedarach wood[J]. Bioresource Technology, 2018,256:1-10.
[31]
Wan Z H, Cho D W, Tsang D C.W, et al. Concurrent adsorption and micro-electrolysis of Cr(VI) by nanoscale zerovalent iron/biochar/Ca-alginate composite.[J]. Environmental pollution, 2019,247:410-420.
[32]
Yan W, Li Y M, Yong Z, et al. Effects of macromolecular humic/fulvic acid on Cd(II) adsorption onto reed-derived biochar as compared with tannic acid[J]. International Journal of Biological Macromolecules, 2019,134:43-55.
[33]
Chen Q, Zheng J W, Zheng L C, et al. Classical theory and electron-scale view of exceptional Cd(II) adsorption onto mesoporous cellulose biochar via experimental analysis coupled with DFT calculations[J]. Chemical Engineering Journal. 2018,350:1000-1009.