中国环境科学
 
 
中国环境科学  2017, Vol. 37 Issue (6): 2072-2079    DOI:
大气污染与控制 最新目录| 下期目录| 过刊浏览| 高级检索 |
天津临港某石化企业VOCs排放特征研究
郭凤艳1, 刘芯雨2, 程晓娟1, 杨文3, 王秀艳1
1. 南开大学环境科学与工程学院, 天津 300350;
2. 浙江大学光电科学与工程学院, 浙江 杭州 310027;
3. 中国环境科学研究院, 北京 100012
Study on VOCs emission characteristic of a petrochemical enterprise in Tianjin Lingang
GUO Feng-yan1, LIU Xin-yu2, CHENG Xiao-juan1, YANG Wen3, WANG Xiu-yan1
1. College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China;
2. College of Optical Science and Engineering, Zhejiang University, Hangzhou 310027, China;
3. Chinese Research Academy of Environmental Sciences, Beijing 100012, China

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摘要 

为量化石化行业各环节VOCs排放影响,在天津临港化工园区开展石化行业VOCs排放特征调查工作,以石化企业BS为例,对其有组织、无组织及厂界、敏感点排放的物质组分及其浓度进行定性定量分析,得到企业的分环节排放特征及排放清单.结果显示,有组织排放源、装置区、储罐区、集水池共检出25种物质,主要为烷类、烯烃类和醇类,其特征污染物为正癸烷、正壬烷、正辛烷及其异构体、正庚烷及其异构体、甲醇、丙烷;有组织排放源及装置区、储罐区、集水池4个环节排放量依次为8.70、268.42、120.04、0.0003t,以产品产量计,对应的排放因子分别为0.3631、0.1624、0.0118、4.06×10-7kg/t;通过相关性分析(p<0.01),装置区与企业厂界浓度水平显著相关,敏感点与BS企业储罐区浓度水平高度相关,可见无组织排放对环境影响显著.

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郭凤艳
刘芯雨
程晓娟
杨文
王秀艳
关键词 VOCs排放特征排放清单排放因子    
Abstract

In order to quantify the influences of volatile organic compounds (VOCs) emission from various sectors in petrochemical industry, an investigation of VOC emission characteristics was carried out in a petrochemical enterprise BS. The emitted VOC components and their corresponding concentrations were qualitatively and quantitatively analyzed in the organized and fugitive emission sources, factory boundary, as well as the sensitive sampling points. The emission characteristic and emission list were obtained at each sector of the enterprise. The results showed that a total of 25 substances were detected in the organized emission sources, production area, storage area and catchment pool, which were mainly alkanes, alkenes and alcohols. The featured pollutants were N-decane, N-nonane, N-octane isomers, N-heptane isomers, methanol and propane. Their emission were 8.70, 268.43, 120.04 and 0.0003 t, respectively. In terms of product output, their VOCs emission factors were 0.3631, 0.1624, 0.0118, and 4.06×10-7kg/t, respectively. Correlation analysis indicated that the concentration level of setting area was significantly correlated to the level of the factory boundary (p < 0.01), and the concentration level of sensitive point was highly correlated with the level of the storage area, which showed that fugitive emissions has significant impact on the environment.

Key wordsVOCs    emission characteristic    emission list    emission factor   
收稿日期: 2016-11-10     
PACS: X511  
基金资助:

国家环境保护公益行业科研专项(201409019);南开大学亚洲研究中心项目(AS1417);国家重大科学仪器研发项目(2013YQ090875)

通讯作者: 王秀艳,副教授,wangsy@nankai.edu.cn     E-mail: wangsy@nankai.edu.cn
作者简介: 郭凤艳(1991-),女,河南安阳人,南开大学硕士研究生,主要从事挥发性有机物测量及控制研究.
引用本文:   
郭凤艳, 刘芯雨, 程晓娟, 杨文, 王秀艳. 天津临港某石化企业VOCs排放特征研究[J]. 中国环境科学, 2017, 37(6): 2072-2079. GUO Feng-yan, LIU Xin-yu, CHENG Xiao-juan, YANG Wen, WANG Xiu-yan. Study on VOCs emission characteristic of a petrochemical enterprise in Tianjin Lingang. CHINA ENVIRONMENTAL SCIENCECE, 2017, 37(6): 2072-2079.
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